FeCl₃-Catalyzed Alkenylation of Simple Arenes with Aryl-Substituted Alkynes

• Abstract
• Full Text HTML
• Hi-Res PDF[86 KB]
• PDF w/ Links[167 KB]

• Supporting Info
• Figures
• Citing Articles

Your current credentials do not allow retrieval of the full text.

Purchase the full-text

• PDF/HTML,
  figures/images,
  references and tables,
  (where available)

Abstract

An addition of electron-rich arenes to aryl-substituted alkynes to form 1,1-diaryl alkenes is carried out in the presence of FeCl₃ as catalyst under mild conditions.

Citing Articles

View all 41 citing articles

Citation data is made available by participants in CrossRef's Cited-by Linking service. For a more comprehensive list of citations to this article, users are encouraged to perform a search in SciFinder.

This article has been cited by 10 ACS Journal articles (5 most recent appear below).

• 

  Iron-Containing Mesoporous Aluminosilicate: A Highly Active and Reusable Heterogeneous Catalyst for Hydroarylation of Styrenes

  Satyajit Haldar and Subratanath Koner
  The Journal of Organic Chemistry2010 75 (17), 6005-6008

  • Iron-Containing Mesoporous Aluminosilicate: A Highly Active and Reusable Heterogeneous Catalyst for Hydroarylation of Styrenes

    Satyajit Haldar and Subratanath Koner
    The Journal of Organic Chemistry2010 75 (17), 6005-6008

    Hydroarylation of various styrene derivatives has been successfully carried out in excellent yield using Fe−Al-MCM-41 catalyst. The C−H functionalization using solid heterogeneous catalyst provides a straightforward access to a series of important 1,1-...

    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
• 

  Switching from Dimerization to Cyclotrimerization Selectivity by FeCl₃ in the Y[N(TMS)₂]₃-Catalyzed Transformation of Terminal Alkynes: A New Strategy for Controlling the Selectivity of Organolanthanide-Based Catalysis

  Xiuli Bu, Zhengxing Zhang and Xigeng Zhou
  Organometallics2010 29 (16), 3530-3534

  • Switching from Dimerization to Cyclotrimerization Selectivity by FeCl₃ in the Y[N(TMS)₂]₃-Catalyzed Transformation of Terminal Alkynes: A New Strategy for Controlling the Selectivity of Organolanthanide-Based Catalysis

    Xiuli Bu, Zhengxing Zhang and Xigeng Zhou
    Organometallics2010 29 (16), 3530-3534

    Y[N(TMS)2]3/FeCl3 has been found to be an efficient bimetallic catalyst system for the cyclotrimerization of terminal alkynes, which cannot be achieved by either trivalent iron or trivalent lanthanide catalysts. Furthermore, this reaction also occurs ...

    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
• 

  Friedel−Crafts Arylation Reactions of N-Sulfonyl Aldimines or Sulfonamidesulfones with Electron-Rich Arenes Catalyzed by FeCl₃·6H₂O: Synthesis of Triarylmethanes and Bis-heteroarylarylmethanes

  Ponnaboina Thirupathi and Sung Soo Kim
  The Journal of Organic Chemistry2010 75 (15), 5240-5249

  • Friedel−Crafts Arylation Reactions of N-Sulfonyl Aldimines or Sulfonamidesulfones with Electron-Rich Arenes Catalyzed by FeCl₃·6H₂O: Synthesis of Triarylmethanes and Bis-heteroarylarylmethanes

    Ponnaboina Thirupathi and Sung Soo Kim
    The Journal of Organic Chemistry2010 75 (15), 5240-5249

    The FeCl3·6H2O-catalyzed Friedel−Crafts arylation reactions of N-sulfonyl aldimines or sulfonamidesulfones with electron-rich arenes and heteroarenes, which lead to the formation of triarylmethanes and bis-heteroarylarylmethanes, are developed. The use of ...

    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
• 

  Iron-Catalyzed Domino Process for the Synthesis of α-Carbonyl Furan Derivatives via One-Pot Cyclization Reaction

  Huanfeng Jiang, Wenjuan Yao, Hua Cao, Huawen Huang and Derong Cao
  The Journal of Organic Chemistry2010 75 (15), 5347-5350

  • Iron-Catalyzed Domino Process for the Synthesis of α-Carbonyl Furan Derivatives via One-Pot Cyclization Reaction

    Huanfeng Jiang, Wenjuan Yao, Hua Cao, Huawen Huang and Derong Cao
    The Journal of Organic Chemistry2010 75 (15), 5347-5350

    The Fe(ClO4)3-catalyzed intramolecular rearrangement/cyclization/oxidation reaction sequence for the synthesis of α-carbonyl furan derivatives from electron-deficient alkynes and 2-yn-1-ols is reported.

    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
• 

  Palladium-Catalyzed Intramolecular 5-exo-dig Hydroarylations of N-Arylpropiolamides: Thermodynamics-Controlled Stereoselective Synthesis of 3-Methyleneoxindoles

  Tao-Shan Jiang, Ri-Yuan Tang, Xing-Guo Zhang, Xin-Hua Li and Jin-Heng Li
  The Journal of Organic Chemistry2009 74 (22), 8834-8837

  • Palladium-Catalyzed Intramolecular 5-exo-dig Hydroarylations of N-Arylpropiolamides: Thermodynamics-Controlled Stereoselective Synthesis of 3-Methyleneoxindoles

    Tao-Shan Jiang, Ri-Yuan Tang, Xing-Guo Zhang, Xin-Hua Li and Jin-Heng Li
    The Journal of Organic Chemistry2009 74 (22), 8834-8837

    Palladium-catalyzed intramolecular hydroarylation of N-arylpropiolamides has been developed for the stereoselective synthesis of 3-(monosubstituted methylene)oxindoles. In the presence of Pd(OAc)2 and dppf, a variety of N-arylpropiolamides successfully ...

    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links

SciFinder Links

• Get Reference Detail
• Get Substances
• Get Reactions
• Get Cited
• Get Citing