Direct Lactone Formation by Using Hypervalent Iodine(III) Reagents with KBr via Selective C−H Abstraction Protocol

Related Content

• Total Synthesis and Structural Revision of the Piperarborenines via Sequential Cyclobutane C–H ArylationJournal of the American Chemical Society

  • Total Synthesis and Structural Revision of the Piperarborenines via Sequential Cyclobutane C–H Arylation

    Will R. Gutekunst and Phil S. Baran
    Journal of the American Chemical Society 2011 133 (47), pp 19076–19079

    Abstract: A strategy for the construction of unsymmetrical cyclobutanes using C–H functionalization logic is demonstrated in the total synthesis of piperarborenine B and piperarborenine D (reported structure). These syntheses feature a new preparation of cis-...

    Abstract | Full Text HTML | PDF w/ Links | Hi-Res PDF
• Rh Catalyzed C–H Activation and Oxidative Olefination without Chelate Assistance: On the Reactivity of BromoarenesOrganic Letters

  • Rh Catalyzed C–H Activation and Oxidative Olefination without Chelate Assistance: On the Reactivity of Bromoarenes

    Frederic W. Patureau, Corinna Nimphius, and Frank Glorius
    Organic Letters 2011 13 (24), pp 6346–6349

    Abstract: A Rh catalyzed, no-chelate-assisted C–H activation/oxidative olefination reaction of bromoarenes has been discovered, in which the latter ones seem to act as a substrate, terminal oxidant, and catalyst modifier.

    Abstract | Full Text HTML | PDF w/ Links | Hi-Res PDF
• Metal-Free Intermolecular Oxidative C–N Bond Formation via Tandem C–H and N–H Bond FunctionalizationJournal of the American Chemical Society

  • Metal-Free Intermolecular Oxidative C–N Bond Formation via Tandem C–H and N–H Bond Functionalization

    Abhishek A. Kantak, Shathaverdhan Potavathri, Rose A. Barham, Kaitlyn M. Romano, and Brenton DeBoef
    Journal of the American Chemical Society 2011 133 (49), pp 19960–19965

    Abstract: The development of a novel intermolecular oxidative amination reaction, a synthetic transformation that involves the simultaneous functionalization of both a N–H and C–H bond, is described. The process, which is mediated by an I(III) oxidant and contains ...

    Abstract | Full Text HTML | PDF w/ Links | Hi-Res PDF

Other ACS content by these authors:

• Toshifumi Dohi
• Naoko Takenaga
• Akihiro Goto
• Akinobu Maruyama
• Yasuyuki Kita