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AuCl-Catalyzed Synthesis of Benzyl-Protected Substituted Phenols: A Formal [3+3] Approach
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Abstract
A AuCl-catalyzed synthesis of highly substituted, benzyl-protected phenols is developed. This reaction unites enal/enones and benzyl allenyl ether in a [3+3] fashion in two steps, allowing flexibility in phenol synthesis and excellent control of substitution at the benzene ring.
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This article has been cited by 6 ACS Journal articles (5 most recent appear below).
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Mechanistic Insights into the Gold-Catalyzed Cycloisomerization of Bromoallenyl Ketones: Ligand-Controlled Regioselectivity
Yuanzhi Xia, Alexander S. Dudnik, Vladimir Gevorgyan and Yahong LiJournal of the American Chemical Society2008 130 (22), 6940-6941Mechanistic Insights into the Gold-Catalyzed Cycloisomerization of Bromoallenyl Ketones: Ligand-Controlled Regioselectivity
Yuanzhi Xia, Alexander S. Dudnik, Vladimir Gevorgyan and Yahong LiJournal of the American Chemical Society2008 130 (22), 6940-6941Through computational and experimental studies, the mechanisms of gold-catalyzed cycloisomerization of bromoallenyl ketones in toluene have been elucidated. The divergent 1,2-migrations for the Au(I)- and Au(III)-catalyzed reactions have been investigated,...
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History
- Published In Issue October 25, 2007
- Received August 31, 2007
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