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Use of Polyanions for Alkylation of Hydrazine Derivatives

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Aleksei Bredihhin and Uno Mäeorg*

Institute of Organic and Bioorganic Chemistry, University of Tartu, Jakobi 2, 51014 Tartu, Estonia

Org. Lett., 2007, 9 (24), pp 4975–4977

DOI: 10.1021/ol702234s

Publication Date (Web): November 3, 2007

Section:

Aliphatic Compounds

Abstract

Alkylation of hydrazine and its derivatives still remains a quite complicated task. The novel method utilizing the polyanion strategy is reported. Formation and use of trianion for alkylation of hydrazine derivatives is first reported. Described method provides fast and convenient access to multialkylated derivatives. Scope and limitations of new method are also investigated.

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This article has been cited by 1 ACS Journal articles (1 most recent appear below).

Fast Synthesis of Hydrazine and Azo Derivatives by Oxidation of Rare-Earth-Metal−Nitrogen Bonds
Lijun Zhang, Jing Xia, Qinghai Li, Xihong Li, and Shaowu Wang
Organometallics2011 30 (3), 375-378
- Fast Synthesis of Hydrazine and Azo Derivatives by Oxidation of Rare-Earth-Metal−Nitrogen Bonds
  Lijun Zhang, Jing Xia, Qinghai Li, Xihong Li, and Shaowu Wang
  Organometallics2011 30 (3), 375-378
  A novel N−N coupling reaction was developed through the oxidation of rare-earth-metal−nitrogen bonds produced by treatment of the easily available rare-earth-metal amides [(Me3Si)2N]3RE(μ-Cl)Li(THF)3 with aromatic primary or secondary amines. The reaction ...
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