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Letter

Total Synthesis of (3R,9R,10R)-Panaxytriol via Tandem Metathesis and Metallotropic [1,3]-Shift as a Key Step

Supporting Info

Eun Jin Cho^† and Daesung Lee*

Department of Chemistry, University of Illinois at Chicago, 845 West Taylor Street, Chicago, Illinois 60607

Org. Lett., 2008, 10 (2), pp 257–259

DOI: 10.1021/ol702651s

Publication Date (Web): December 13, 2007

†

University of WisconsinMadison.

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

, dsunglee@uic.edu

Abstract

Enyne metathesis is unique for its capacity to carry out multiple bond formation in tandem fashion. Its combined use with metallotropic [1,3]-shift allowed for the development of a novel strategy for the total synthesis of a conjugated 1,3-diyne-containing natural product (3R,9R,10R)-panaxytriol.

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Published In Issue January 17, 2008
Received November 1, 2007

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Letter

Total Synthesis of (3R,9R,10R)-Panaxytriol via Tandem Metathesis and Metallotropic [1,3]-Shift as a Key Step

Abstract

Tools

SciFinder Links

History

Recommend & Share

Related Content

Total Synthesis of (−)-Acutumine

Tandem Enyne Metathesis−Metallotropic [1,3]-Shift for a Concise Total Syntheses of (+)-Asperpentyn, (−)-Harveynone, and (−)-Tricholomenyn A

Enantiospecific Total Syntheses of Kapakahines B and F

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