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Allylic Alkylation and Ring-Closing Metathesis in Sequence: A Successful Cohabitation of Pd and Ru
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Section:Abstract
An allylic alkylation/ring-closing metathesis domino catalytic process, wherein a palladium and a ruthenium catalyst are concomitantly present in the reaction mixture from the outset of the reaction, is developed. Evidence for Grubbs' catalysts activity in allylic alkylation is also reported.
Citing Articles
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This article has been cited by 4 ACS Journal articles (4 most recent appear below).
Grubbs’ Ruthenium-Carbenes Beyond the Metathesis Reaction: Less Conventional Non-Metathetic Utility
Benito Alcaide, Pedro Almendros and Amparo LunaChemical Reviews2009 109 (8), 3817-3858Grubbs’ Ruthenium-Carbenes Beyond the Metathesis Reaction: Less Conventional Non-Metathetic Utility
Benito Alcaide, Pedro Almendros and Amparo LunaChemical Reviews2009 109 (8), 3817-3858
Ruthenium-Catalyzed Synthesis of Functionalized 1,3-Dienes
Mathieu Achard, Nolwenn Derrien, Hui-Jun Zhang, Bernard Demerseman and Christian BruneauOrganic Letters2009 11 (1), 185-188Ruthenium-Catalyzed Synthesis of Functionalized 1,3-Dienes
Mathieu Achard, Nolwenn Derrien, Hui-Jun Zhang, Bernard Demerseman and Christian BruneauOrganic Letters2009 11 (1), 185-188Functionalized 1,3-diene derivatives have been prepared by regioselective allylation of various nucleophiles with 1,3-dienic carbonates in the presence of a (N,O-carboxylate) allylruthenium precatalyst.
Intra/Intermolecular Direct Allylic Alkylation via Pd(II)-Catalyzed Allylic C−H Activation
Song Lin, Chun-Xiao Song, Gui-Xin Cai, Wen-Hua Wang and Zhang-Jie ShiJournal of the American Chemical Society2008 130 (39), 12901-12903Intra/Intermolecular Direct Allylic Alkylation via Pd(II)-Catalyzed Allylic C−H Activation
Song Lin, Chun-Xiao Song, Gui-Xin Cai, Wen-Hua Wang and Zhang-Jie ShiJournal of the American Chemical Society2008 130 (39), 12901-12903The first catalytic direct alkylation of allylic C−H bonds via Pd(II)-catalysis is described in the absence of base. Polysubstituted cyclic compounds can also be constructed by the intramolecular direct allylic alkylation.
New Picropodophyllin Analogs via Palladium-Catalyzed Allylic Alkylation−Hiyama Cross-Coupling Sequences
Maxime Vitale, Guillaume Prestat, David Lopes, David Madec, Claire Kammerer, Giovanni Poli and Leonard GirnitaThe Journal of Organic Chemistry2008 73 (15), 5795-5805New Picropodophyllin Analogs via Palladium-Catalyzed Allylic Alkylation−Hiyama Cross-Coupling Sequences
Maxime Vitale, Guillaume Prestat, David Lopes, David Madec, Claire Kammerer, Giovanni Poli and Leonard GirnitaThe Journal of Organic Chemistry2008 73 (15), 5795-5805Unsaturated malonyl esters underwent Pd-catalyzed intramolecular allylic alkylation to give 4-vinyl-substituted γ-lactones. In contrast to the formerly studied cyclization of malonamides, this reaction could be achieved only with a substrate ...
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History
- Published In Issue February 07, 2008
- Received November 6, 2007
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