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Efficient Synthetic Method of Multisubstituted Allenes from the Reactions of Allylindium Reagents with 3°-Propargyl Alcohols
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Section:Abstract
An efficient synthetic method of tri- and tetra-substituted allenes having an allyl and methallyl group was developed by the reactions of allylindium reagents generated in situ from indium and allyl bromides with 3°-propargyl alcohols.
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This article has been cited by 3 ACS Journal articles (3 most recent appear below).
Making and Breaking of Sn−C and In−C Bonds in Situ: The Cases of Allyltins and Allylindiums
Ujjal Kanti Roy and Sujit RoyChemical Reviews2010 110 (4), 2472-2535Making and Breaking of Sn−C and In−C Bonds in Situ: The Cases of Allyltins and Allylindiums
Ujjal Kanti Roy and Sujit RoyChemical Reviews2010 110 (4), 2472-2535
Stereoselective DABCO-Catalyzed Synthesis of (E)-α-Ethynyl-α,β-Unsaturated Esters from Allenyl Acetates
Yongsik Choe and Phil Ho LeeOrganic Letters2009 11 (6), 1445-1448Stereoselective DABCO-Catalyzed Synthesis of (E)-α-Ethynyl-α,β-Unsaturated Esters from Allenyl Acetates
Yongsik Choe and Phil Ho LeeOrganic Letters2009 11 (6), 1445-1448(E)-α-Ethynyl-α,β-unsaturated esters were exclusively prepared in good to excellent yields from treatment of allenyl acetates with 10 mol % DABCO in DMF at room temperature.
Palladium-Catalyzed Regioselective Cyclopropanating Allenylation of (2,3-Butadienyl)malonates with Propargylic Carbonates and Their Application to Synthesize Cyclopentenones
Wei Shu, Guochen Jia and Shengming MaOrganic Letters2009 11 (1), 117-120Palladium-Catalyzed Regioselective Cyclopropanating Allenylation of (2,3-Butadienyl)malonates with Propargylic Carbonates and Their Application to Synthesize Cyclopentenones
Wei Shu, Guochen Jia and Shengming MaOrganic Letters2009 11 (1), 117-120An efficient and highly regioselective route to synthesize polysubstituted 1,3,4-alkatrien-2-yl cyclopropane derivatives via Pd(0)-catalyzed highly regioselective coupling cyclization of (2,3-butadienyl)malonate or bis(phenylsulfonyl)methane with ...
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History
- Published In Issue June 19, 2008
- Article ASAPMay 14, 2008
- Received: March 31, 2008
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