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Letter

A Method for Constructing the C44−C51 Side Chain of Altohyrtin C

Supporting Info

Gregory R. Ott and Clayton H. Heathcock*

Department of Chemistry, University of California, Berkeley, California 94720

Org. Lett., 1999, 1 (9), pp 1475–1478

DOI: 10.1021/ol990281j

Publication Date (Web): September 28, 1999

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

, chh@steroid.cchem.berkeley.edu

Abstract

A method to construct the C44−C51 side chain of altohyrtin C has been developed and applied to a model aldehyde derived from d-glucose. The approach relies on a Wittig reaction to couple the side chain to an aldehyde and utilizes an allylic diazene rearrangement to place the C45 double bond in the correct position.

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Published In Issue November 04, 1999
Received September 13, 1999

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Letter

A Method for Constructing the C44−C51 Side Chain of Altohyrtin C

Abstract

Tools

SciFinder Links

History

Recommend & Share

Related Content

Total Synthesis of (−)-Penifulvin A, an Insecticide with a Dioxafenestrane Skeleton

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Inspirations, Discoveries, and Future Perspectives in Total Synthesis

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