Log In Register
Cart
Advanced Search
x
Select a CAS section from the 5 main topical divisions below:

Letter

Previous Article
Table of Contents

F8BINOL, an Electronically Perturbed Version of BINOL with Remarkable Configurational Stability

Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario M5S 3H6, Canada
Org. Lett., 2000, 2 (1), pp 41–44
DOI: 10.1021/ol991244v
Publication Date (Web): December 18, 1999
Copyright © 2000 American Chemical Society

Abstract

Abstract Image

Substitution of hydrogens by fluorines at the 5, 5‘, 6, 6‘, 7, 7‘, 8, and 8‘ positions of BINOL strongly affects distribution of electron density within the biaryl skeleton but has a very small influence on the torsion angle. The most important consequence of this structural alteration is the dramatic increase in configurational stability of homochiral F8BINOL.

View: PDF | PDF w/ Links | Full Text HTML

Citation data is made available by participants in CrossRef's Cited-by Linking service. For a more comprehensive list of citations to this article, users are encouraged to perform a search in SciFinder.

Add to ACS ChemWorx

Metrics

Article Views: 840 Times
Received 11 November 1999
Published online 18 December 1999
Published in print 1 January 2000
Learn more about these metrics Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.
+
More Article Metrics
Explore by: