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Volume Profile Analysis of Oxidative Addition to Palladium(II) and Reductive Elimination from Palladium(IV)
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This article has been cited by 19 ACS Journal articles (5 most recent appear below).
Mechanistic and Computational Studies of Oxidatively-Induced Aryl−CF3 Bond-Formation at Pd: Rational Design of Room Temperature Aryl Trifluoromethylation
Nicholas D. Ball, J. Brannon Gary, Yingda Ye, and Melanie S. SanfordJournal of the American Chemical Society2011 Article ASAPMechanistic and Computational Studies of Oxidatively-Induced Aryl−CF3 Bond-Formation at Pd: Rational Design of Room Temperature Aryl Trifluoromethylation
Nicholas D. Ball, J. Brannon Gary, Yingda Ye, and Melanie S. SanfordJournal of the American Chemical Society2011 Article ASAPThis article describes the rational design of first generation systems for oxidatively induced Aryl−CF3 bond-forming reductive elimination from PdII. Treatment of (dtbpy)PdII(Aryl)(CF3) (dtbpy = di-tert-butylbipyridine) with NFTPT (N-fluoro-1,3,5-...
Oxidation of a Cyclometalated Pd(II) Dimer with “CF3+”: Formation and Reactivity of a Catalytically Competent Monomeric Pd(IV) Aquo Complex
Yingda Ye, Nicholas D. Ball, Jeff W. Kampf, and Melanie S. SanfordJournal of the American Chemical Society2010 132 (41), 14682-14687Oxidation of a Cyclometalated Pd(II) Dimer with “CF3+”: Formation and Reactivity of a Catalytically Competent Monomeric Pd(IV) Aquo Complex
Yingda Ye, Nicholas D. Ball, Jeff W. Kampf, and Melanie S. SanfordJournal of the American Chemical Society2010 132 (41), 14682-14687The reaction of [(bzq)Pd(OAc)]2 (bzq = benzo[h]quinoline) with “CF3+” reagents to afford the monomeric PdIV aquo complex (bzq)Pd(CF3)(OAc)2(OH2) is demonstrated. Heating this PdIV adduct at 60 °C for 12 h leads to highly chemoselective aryl−CF3 bond-...
Emergence of Palladium(IV) Chemistry in Synthesis and Catalysis
Petr Sehnal, Richard J. K. Taylor and Ian J. S. FairlambChemical Reviews2010 110 (2), 824-889Emergence of Palladium(IV) Chemistry in Synthesis and Catalysis
Petr Sehnal, Richard J. K. Taylor and Ian J. S. FairlambChemical Reviews2010 110 (2), 824-889
Oxidatively Induced Reductive Elimination from (tBu2bpy)Pd(Me)2: Palladium(IV) Intermediates in a One-Electron Oxidation Reaction
Michael P. Lanci, Matthew S. Remy, Werner Kaminsky, James M. Mayer and Melanie S. SanfordJournal of the American Chemical Society2009 131 (43), 15618-15620Oxidatively Induced Reductive Elimination from (tBu2bpy)Pd(Me)2: Palladium(IV) Intermediates in a One-Electron Oxidation Reaction
Michael P. Lanci, Matthew S. Remy, Werner Kaminsky, James M. Mayer and Melanie S. SanfordJournal of the American Chemical Society2009 131 (43), 15618-15620This communication describes studies of oxidatively induced C−C bond-forming reductive elimination from (tBu2bpy)PdII(Me)2. With the outer-sphere oxidant ferrocenium, the data are consistent with a mechanism involving PdIII and PdIV intermediates, with C−...
Kinetico-Mechanistic Insight into the Platinum-Mediated C−C Coupling of Fluorinated Arenes
Teresa Calvet, Margarita Crespo, Mercè Font-Bardia, Kerman Gómez, Gabriel González and Manuel MartínezOrganometallics2009 28 (17), 5096-5106Kinetico-Mechanistic Insight into the Platinum-Mediated C−C Coupling of Fluorinated Arenes
Teresa Calvet, Margarita Crespo, Mercè Font-Bardia, Kerman Gómez, Gabriel González and Manuel MartínezOrganometallics2009 28 (17), 5096-5106The reaction of compound cis-[Pt(C6F5)2(SEt2)2] with the imine ligands ArCH═NCH2CH2NMe2 (Ar = 2-BrC6H4 (1a) or 2,6-Cl2C6H3 (1b)) in toluene produces coordination compounds cis-[Pt(C6F5)2(ArCH═NCH2CH2NMe2)] (2a, 2b) containing a bidentate [N,N′] ligand. No ...
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- Published In Issue June, 1994
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