Cart
Communication
Facile Two-Step Construction of a Novel Tetrathiamacrotricycle
Full Text HTML
Hi-Res PDFPurchase the full-text
- PDF/HTML,
figures/images,
references and tables,
(where available)
Abstract
The reactions of [Os(CO)(CA)(PPh3)3] (A = O, S) with 4,7,10-trithiatrideca-2,11-diyne provide cyclopentadienone and cyclopentadienethione complexes, the latter affording a novel polythioether macrotricyclic ligand on subsequent treatment with dimethylacetylenedicarboxylate.
Citing Articles
Citation data is made available by participants in CrossRef's Cited-by Linking service. For a more comprehensive list of citations to this article, users are encouraged to perform a search in SciFinder.
This article has been cited by 10 ACS Journal articles (5 most recent appear below).
Organometallic Macrocyclic Chemistry. 8. An Unusual Metallacycle Derived from Phosphine−Alkynyl Thioether Coupling
Anthony F. Hill, Barbara Niess, Madeleine Schultz, Andrew J. P. White, and David J. WilliamsOrganometallics2010 29 (23), 6488-6492Organometallic Macrocyclic Chemistry. 8.(1) An Unusual Metallacycle Derived from Phosphine−Alkynyl Thioether Coupling
Anthony F. Hill, Barbara Niess, Madeleine Schultz, Andrew J. P. White, and David J. WilliamsOrganometallics2010 29 (23), 6488-6492The α,ω-diyne 4,7,10-trithiatrideca-2,11-diyne reacts with [RuCl2(PPh3)3] and KPF6 to form the phosphonio-substituted metallatricyclic salt [RuCl(PPh3){κ4C,S,S′,S′′-S(C≡CMe)C2H4SC2H4SC(PPh3)CMe}]PF6 arising from the activation of one alkynyl group toward ...
A Bridging Selenoacyl Complex via Alkynylselenolatoalkylidyne Rearrangement
Lorraine M. Caldwell, Richard L. Cordiner, Anthony F. Hill and Jörg WaglerOrganometallics2010 29 (7), 1526-1529A Bridging Selenoacyl Complex via Alkynylselenolatoalkylidyne Rearrangement
Lorraine M. Caldwell, Richard L. Cordiner, Anthony F. Hill and Jörg WaglerOrganometallics2010 29 (7), 1526-1529The alkynylselenolatoalkylidyne complex [Mo(≡C−Se−C≡CSiMe3)(CO)2{HB(pzMe2)3}] (pz = pyrazol-1-yl) reacts with [RhCl(PPh3)3] via an unusual C−Se bond cleavage/formation sequence to provide the heterodinuclear bridging selenoacyl complex [MoRh(μ
-SeCC≡CSiMe...
Chelation-Assisted Reactions of Phosphine- and Olefin-Tethered Imidazolium Derivatives and Their Affiliated N-Heterocyclic Carbenes with Roper’s Complex Ru(CO)2(PPh3)3
Laure Benhamou, Joffrey Wolf, Vincent César, Agnès Labande, Rinaldo Poli, Noël Lugan and Guy LavigneOrganometallics2009 28 (24), 6981-6993Chelation-Assisted Reactions of Phosphine- and Olefin-Tethered Imidazolium Derivatives and Their Affiliated N-Heterocyclic Carbenes with Roper’s Complex Ru(CO)2(PPh3)3
Laure Benhamou, Joffrey Wolf, Vincent César, Agnès Labande, Rinaldo Poli, Noël Lugan and Guy LavigneOrganometallics2009 28 (24), 6981-6993Complex Ru(CO)2(PPh3)3, 1, is a suitable starting compound for the generation of N-heterocyclic carbene complexes of Ru(0). Although monodentate NHCs are totally unreactive toward 1, phosphine- or olefin-functionalized N-heterocyclic carbenes, as well as ...
Reactions of [Ru(CO)2(PPh3)3] with Alkynylphosphonium Salts: A Phosphinoallene Complex
Wee Han Ang, Richard L. Cordiner, Anthony F. Hill, Tamara L Perry and Jörg WaglerOrganometallics2009 28 (18), 5568-5574Reactions of [Ru(CO)2(PPh3)3] with Alkynylphosphonium Salts: A Phosphinoallene Complex
Wee Han Ang, Richard L. Cordiner, Anthony F. Hill, Tamara L Perry and Jörg WaglerOrganometallics2009 28 (18), 5568-5574[Ru(CO)2(PPh3)3] reacts with either HC≡CCH2Br or [HC≡CCH2SMe2]Br to provide the σ-allenyl complex [Ru(CH═C═CH2)Br(CO)2(PPh3)2]; however, with [HC≡CCH2PPh3]Br, the salt [Ru(η2-H2C═C═CHPPh3)(CO)2(PPh3)2]Br is obtained, which may be described as a complex of ...
Reactions of [Ru(CO)2(PPh3)3] with Alkynylphosphonium Salts: Phosphaallenylidene vs Phosphonioacetylide Coordination
Richard L. Cordiner, Anthony F. Hill and Jörg WaglerOrganometallics2009 28 (16), 4880-4885Reactions of [Ru(CO)2(PPh3)3] with Alkynylphosphonium Salts: Phosphaallenylidene vs Phosphonioacetylide Coordination
Richard L. Cordiner, Anthony F. Hill and Jörg WaglerOrganometallics2009 28 (16), 4880-4885[Ru(CO)2(PPh3)3] reacts with [Me3SiC≡CPPh3]OTf in the presence of moist [nBu4N]F to provide the C−H activation product [RuH(C≡CPPh3)(CO)2(PPh3)2]OTf, spectroscopic and structural data for which are used to assess the previously proposed analogy between ...
Tools
-
Add to Favorites
-
Download Citation
-
Email a Colleague -
Permalink
Order Reprints
Rights & Permissions
Citation Alerts
History
- Published In Issue April 25, 2005
- Received October 13, 2004
ACS
Network
Facebook
Tweet This
CiteULike
Newsvine
Digg This
Delicious
CPh)2] (x = 0, 1)
