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Communication

Carbon−Carbon Bond Formation on a Bis(oxazolinyl)phenyl−Rhodium Complex in a Reduction and Oxidative Addition Sequence

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Jun-ichi Ito, Takeshi Miyakawa, and Hisao Nishiyama*

Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Chikusa, Nagoya 464-8603, Japan

Organometallics, 2006, 25 (22), pp 5216–5218

DOI: 10.1021/om0607595

Publication Date (Web): September 26, 2006

To whom correspondence should be addressed. E-mail: hnishi@ apchem.nagoya-u.ac.jp.

Abstract

The unique C−C bond formation reaction between diisopropylamine and CH₂Cl₂ proceeding on a bis(oxazolinyl)phenyl rhodium complex (tBu-Phebox-dm)RhCl₂(H₂O) (1) was discovered. The intermediary chloromethyl complex, (tBu-Phebox-dm)Rh(CH₂Cl)Cl(NEt₃), which was obtained by reaction of 1 with CH₂Cl₂ in the presence of amine, underwent C−C bond formation with imine to give an azarhodacyclopentene complex, 2.

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Published In Issue October 23, 2006
Received August 22, 2006

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Communication

Carbon−Carbon Bond Formation on a Bis(oxazolinyl)phenyl−Rhodium Complex in a Reduction and Oxidative Addition Sequence

Abstract

Tools

SciFinder Links

History

Recommend & Share

Related Content

Amide Synthesis from Alcohols and Amines by the Extrusion of Dihydrogen

New Bis(oxazolinyl)phenyl−Ruthenium(II) Complexes and Their Catalytic Activity for Enantioselective Hydrogenation and Transfer Hydrogenation of Ketones

Versatile Pd(II)-Catalyzed C−H Activation/Aryl−Aryl Coupling of Benzoic and Phenyl Acetic Acids

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