Synthesis and Study of the First N-Aryl Acyclic Diaminocarbene and Its Transition-Metal Complexes

Related Content

• Quinone-Annulated N-Heterocyclic Carbene−Transition-Metal Complexes:  Observation of π-Backbonding Using FT-IR Spectroscopy and Cyclic Voltammetry Quinone-Annulated N-Heterocyclic Carbene−Transition-Metal Complexes:  Observation of π-Backbonding Using FT-IR Spectroscopy and Cyclic VoltammetryJournal of the American Chemical Society

  • Quinone-Annulated N-Heterocyclic Carbene−Transition-Metal Complexes:  Observation of π-Backbonding Using FT-IR Spectroscopy and Cyclic Voltammetry Quinone-Annulated N-Heterocyclic Carbene−Transition-Metal Complexes:  Observation of π-Backbonding Using FT-IR Spectroscopy and Cyclic Voltammetry

    Matthew D. Sanderson, Justin W. Kamplain, and Christopher W. Bielawski
    Journal of the American Chemical Society 2006 128 (51), pp 16514–16515

    Abstract: A new N-heterocyclic carbene architecture comprising a 1,4-naphthoquinone annulated to 1,3-dimesitylimidazolylidene (NpQ−NHC) was synthesized in two high yielding steps from commercially available starting materials. The free NpQ−NHC was characterized (...

    Abstract | Full Text HTML | Hi-Res PDF
• A Modular Approach to Main-Chain Organometallic PolymersJournal of the American Chemical Society

  • A Modular Approach to Main-Chain Organometallic Polymers

    Andrew J. Boydston, Kyle A. Williams, and Christopher W. Bielawski
    Journal of the American Chemical Society 2005 127 (36), pp 12496–12497

    Abstract: A highly efficient route to a new class of organometallic polymers containing difunctional N-heterocyclic carbenes has been developed. Bis(imidazolium) halides and divalent group X metals were copolymerized to afford organometallic polymers in up to ...

    Abstract | Full Text HTML | Hi-Res PDF
• Phase-Tunable Fluorophores Based upon Benzobis(imidazolium) SaltsJournal of the American Chemical Society

  • Phase-Tunable Fluorophores Based upon Benzobis(imidazolium) Salts

    Andrew J. Boydston, Cory S. Pecinovsky, Steven T. Chao, and Christopher W. Bielawski
    Journal of the American Chemical Society 2007 129 (47), pp 14550–14551

    Abstract: A new series of highly photoluminescent benzobis(imidazolium) salts with tunable electronic and physical properties is described. Systematic structural manipulations provided a set of materials that were not only fluorescent in the condensed state but ...

    Abstract | Full Text HTML | Hi-Res PDF

Other ACS content by these authors:

• Evelyn L. Rosen
• Matthew D. Sanderson
• Shanmuganathan Saravanakumar
• Christopher W. Bielawski