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Brief reports of significant research concerning organic chemistry, including organic synthesis, organometallic, natural product, physical organic, bioorganic, and medicinal chemistry.

Editors: Amos B. Smith, III & Associate Editors
Volume: 10, 24 issues

Articles ASAP (As Soon As Publishable)

The Most Recently Published Research

The following list of Articles ASAP is limited to the latest 20 articles. Visit the All Articles ASAP page for the complete listing.

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Web Release Date: September 5, 2008
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Palladium-Catalyzed Disilylation of o-Quinodimethanes: Synthesis of 9- and 10-Membered Disilacarbocycles
Hiroto Yoshida, Saori Nakano, Masashi Mukae, and Joji Ohshita
Web Release Date: 05-Sep-2008; (Letter) DOI:
10.1021/ol801788t
Abstract   Full:  HTML /  PDF (165K)  Supporting Info 
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Two Novel Triterpenoids from Dysoxylum hainanense
Xiu-Feng He, Xiao-Ning Wang, Li-She Gan, Sheng Yin, Lei Dong, and Jian-Min Yue
Web Release Date: 05-Sep-2008; (Letter) DOI:
10.1021/ol801834y
Abstract   Full:  HTML /  PDF (265K)  Supporting Info 
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Simple Chiral Diene Ligands Provide High Enantioselectivities in Transition-Metal-Catalyzed Conjugate Addition Reactions
Kazuhiro Okamoto, Tamio Hayashi, and Viresh H. Rawal
Web Release Date: 05-Sep-2008; (Letter) DOI:
10.1021/ol801931v
Abstract   Full:  HTML /  PDF (215K)  Supporting Info 
Web Release Date: September 4, 2008
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Catalytic Asymmetric Conjugate Addition of Grignard Reagents to α,β-Unsaturated Sulfones
Pieter H. Bos, Adriaan J. Minnaard, and Ben L. Feringa
Web Release Date: 04-Sep-2008; (Letter) DOI:
10.1021/ol801566n
Abstract   Full:  HTML /  PDF (93K)  Supporting Info 
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Structure of Membrane-Bound Amphidinol 3 in Isotropic Small Bicelles
Toshihiro Houdai, Nobuaki Matsumori, and Michio Murata
Web Release Date: 04-Sep-2008; (Letter) DOI:
10.1021/ol8016337
Abstract   Full:  HTML /  PDF (456K)  Supporting Info 
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A Samarium(II)-Mediated, Stereoselective Cyclization for the Synthesis of Azaspirocycles
Giuditta Guazzelli, Lorna A. Duffy, and David J. Procter
Web Release Date: 04-Sep-2008; (Letter) DOI:
10.1021/ol8017209
Abstract   Full:  HTML /  PDF (226K)  Supporting Info 
Web Release Date: September 3, 2008
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Exploring Electronically Polarized Pentacenes
Dan Lehnherr, Robert McDonald, and Rik R. Tykwinski
Web Release Date: 03-Sep-2008; (Letter) DOI:
10.1021/ol801464k
Abstract   Full:  HTML /  PDF (358K)  Supporting Info 
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Synthesis of CH2-Linked α(2,3)Sialylgalactose Analogue: On the Stereoselectivity of the Key Ireland-Claisen Rearrangement
Toru Watanabe, Go Hirai, Marie Kato, Daisuke Hashizume, Taeko Miyagi, and Mikiko Sodeoka
Web Release Date: 03-Sep-2008; (Letter) DOI:
10.1021/ol801519j
Abstract   Full:  HTML /  PDF (735K)  Supporting Info 
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Scandium-Catalyzed Carbon−Carbon Bond-Forming Reactions of 3-Sulfanyl- and 3-Selanylpropargyl Alcohols
Mitsuhiro Yoshimatsu, Tokutaro Otani, Saki Matsuda, Teruhisa Yamamoto, and Arisa Sawa
Web Release Date: 03-Sep-2008; (Letter) DOI:
10.1021/ol801533p
Abstract   Full:  HTML /  PDF (145K)  Supporting Info 
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Structural Determination of Montanacin D by Total Synthesis
Shunya Takahashi, Yayoi Hongo, Yuki Tsukagoshi, and Hiroyuki Koshino
Web Release Date: 03-Sep-2008; (Letter) DOI:
10.1021/ol801576z
Abstract   Full:  HTML /  PDF (132K)  Supporting Info 
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7-Hydroxycoumarin−Hemicyanine Hybrids: A New Class of Far-Red Emitting Fluorogenic Dyes
Jean-Alexandre Richard, Marc Massonneau, Pierre-Yves Renard, and Anthony Romieu
Web Release Date: 03-Sep-2008; (Letter) DOI:
10.1021/ol801582w
Abstract   Full:  HTML /  PDF (232K)  Supporting Info 
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Synthetic Studies Toward Pectenotoxin 2. Part II. Synthesis of the CDE and CDEF Ring Systems
Hannes Helmboldt, Jatta E. Aho, and Petri M. Pihko
Web Release Date: 03-Sep-2008; (Letter) DOI:
10.1021/ol801585j
Abstract   Full:  HTML /  PDF (474K)  Supporting Info 
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Synthetic Studies Toward Pectenotoxin 2. Part I. Stereocontrolled Access to the C10−C22 Fragment
Jatta E. Aho, Elina Salomäki, Kari Rissanen, and Petri M. Pihko
Web Release Date: 03-Sep-2008; (Letter) DOI:
10.1021/ol8015868
Abstract   Full:  HTML /  PDF (258K)  Supporting Info 
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Total Synthesis of (−)-Histrionicotoxin 285A and (−)-Perhydrohistrionicotoxin
James M. Macdonald, Helen T. Horsley, John H. Ryan, Simon Saubern, and Andrew B. Holmes
Web Release Date: 03-Sep-2008; (Letter) DOI:
10.1021/ol801604z
Abstract   Full:  HTML /  PDF (111K)  Supporting Info 
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Cu(I)-Catalyzed Asymmetric Diamination of Conjugated Dienes
Haifeng Du, Baoguo Zhao, Weicheng Yuan, and Yian Shi
Web Release Date: 03-Sep-2008; (Letter) DOI:
10.1021/ol801605w
Abstract   Full:  HTML /  PDF (122K)  Supporting Info 
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Total Synthesis of Salinosporamide A
Takeo Fukuda, Kouhei Sugiyama, Shiho Arima, Yoshihiro Harigaya, Tohru Nagamitsu, and Satoshi O̅mura
Web Release Date: 03-Sep-2008; (Letter) DOI:
10.1021/ol8016066
Abstract   Full:  HTML /  PDF (143K)  Supporting Info 
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A Concise Entry into Nonsymmetrical Alkyl Polyamines
Tracey Pirali, Grazia Callipari, Emanuela Ercolano, Armando A. Genazzani, Giovanni Battista Giovenzana, and Gian Cesare Tron
Web Release Date: 03-Sep-2008; (Letter) DOI:
10.1021/ol801612r
Abstract   Full:  HTML /  PDF (138K)  Supporting Info 
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Palladium-Catalyzed C-Allylation of Benzoins and an NHC-Catalyzed Three Component Coupling Derived Thereof: Compatibility of NHC- and Pd-Catalysts
Raphaël Lebeuf, Keiichi Hirano, and Frank Glorius
Web Release Date: 03-Sep-2008; (Letter) DOI:
10.1021/ol801644f
Abstract   Full:  HTML /  PDF (126K)  Supporting Info 
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Cyclic Imine Nitro-Mannich/Lactamization Cascades: A Direct Stereoselective Synthesis of Multicyclic Piperidinone Derivatives
Pavol Jakubec, Madeleine Helliwell, and Darren J. Dixon
Web Release Date: 03-Sep-2008; (Letter) DOI:
10.1021/ol801666w
Abstract   Full:  HTML /  PDF (239K)  Supporting Info 
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Rearrangement of Biaryl Monoaminocarbenes via Concerted Asynchronous Insertion into Aromatic C−H Bonds
Joan Vignolle, Matthew Asay, Karinne Miqueu, Didier Bourissou, and Guy Bertrand
Web Release Date: 03-Sep-2008; (Letter) DOI:
10.1021/ol801670z
Abstract   Full:  HTML /  PDF (451K)  Supporting Info 
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