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Complete Conversion of Hydrous Hydrazine to Hydrogen at Room Temperature for Chemical Hydrogen Storage
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Section:Abstract
A synergic effect of Rh and Ni in the bimetallic Rh4Ni nanocatalyst (Rh/Ni ratio = 4:1) makes it possible to achieve a 100% selectivity for hydrogen generation by complete decomposition of hydrous hydrazine at room temperature. The Rh4Ni nanocatalysts with a particle size of 
3 nm were prepared by alloying Rh and Ni using a coreduction process in the presence of hexadecyltrimethyl ammonium bromide (CTAB).
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This article has been cited by 4 ACS Journal articles (4 most recent appear below).
Noble-Metal-Free Bimetallic Nanoparticle-Catalyzed Selective Hydrogen Generation from Hydrous Hydrazine for Chemical Hydrogen Storage
Sanjay Kumar Singh, Ashish Kumar Singh, Kengo Aranishi, and Qiang XuJournal of the American Chemical Society2011 133 (49), 19638-19641Noble-Metal-Free Bimetallic Nanoparticle-Catalyzed Selective Hydrogen Generation from Hydrous Hydrazine for Chemical Hydrogen Storage
Sanjay Kumar Singh, Ashish Kumar Singh, Kengo Aranishi, and Qiang XuJournal of the American Chemical Society2011 133 (49), 19638-19641Noble-metal-free nickel–iron alloy nanoparticles exhibit excellent catalytic performance for the complete decomposition of hydrous hydrazine, for which the NiFe nanocatalyst, with equimolar compositions of Ni and Fe, shows 100% hydrogen selectivity in ...
A Single-Component Liquid-Phase Hydrogen Storage Material
Wei Luo, Patrick G. Campbell, Lev N. Zakharov, and Shih-Yuan LiuJournal of the American Chemical Society2011 133 (48), 19326-19329A Single-Component Liquid-Phase Hydrogen Storage Material
Wei Luo, Patrick G. Campbell, Lev N. Zakharov, and Shih-Yuan LiuJournal of the American Chemical Society2011 133 (48), 19326-19329The current state-of-the-art for hydrogen storage is compressed H2 at 700 bar. The development of a liquid-phase hydrogen storage material has the potential to take advantage of the existing liquid-based distribution infrastructure. We describe a liquid-...
Synergistic Catalysis of Metal–Organic Framework-Immobilized Au–Pd Nanoparticles in Dehydrogenation of Formic Acid for Chemical Hydrogen Storage
Xiaojun Gu , Zhang-Hui Lu , Hai-Long Jiang , Tomoki Akita , and Qiang XuJournal of the American Chemical Society 0 (ja),Synergistic Catalysis of Metal–Organic Framework-Immobilized Au–Pd Nanoparticles in Dehydrogenation of Formic Acid for Chemical Hydrogen Storage
Xiaojun Gu , Zhang-Hui Lu , Hai-Long Jiang , Tomoki Akita , and Qiang XuJournal of the American Chemical Society 0 (ja),Bimetallic Au–Pd nanoparticles (NPs) were successfully immobilized by a metal–organic framework (MOF) MIL-101 and ethylenediamine (ED)-grafted MIL-101 (ED-MIL-101) using a simple liquid impregnation method. The resulting composites, Au–Pd/MIL-101 and Au–...
Bimetallic Ni−Pt Nanocatalysts for Selective Decomposition of Hydrazine in Aqueous Solution to Hydrogen at Room Temperature for Chemical Hydrogen Storage
Sanjay K. Singh and Qiang XuInorganic Chemistry2010 49 (13), 6148-6152Bimetallic Ni−Pt Nanocatalysts for Selective Decomposition of Hydrazine in Aqueous Solution to Hydrogen at Room Temperature for Chemical Hydrogen Storage
Sanjay K. Singh and Qiang XuInorganic Chemistry2010 49 (13), 6148-6152The design and development of alloy catalysts has been a focus of intense interest because suitable selection and control over the composition of alloy catalysts can result in greatly improved activity and selectivity, while it is unusual that the ...
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History
- Published In Issue December 23, 2009
- Article ASAPNovember 24, 2009
- Received: September 21, 2009
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