Table of Contents

February 2004
Volume 104, Issue 2
Pages 347-1200
For Selected Content:

Biomimetic Inorganic Chemistry
Richard H. Holm and Edward I. Solomon, Guest Editors

Preface:  Biomimetic Inorganic Chemistry

Richard H. HolmEdward I. Solomon
pp 347–348
Publication Date (Web): February 11, 2004 (Editorial)
DOI: 10.1021/cr0206364
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Concepts

Principles of Mononucleating and Binucleating Ligand Design

Anna L. Gavrilova and Brice Bosnich
pp 349–384
Publication Date (Web): January 20, 2004 (Article)
DOI: 10.1021/cr020604g

Dinitrogen Coordination Chemistry:  On the Biomimetic Borderlands

Bruce A. MacKay and Michael D. Fryzuk
pp 385–402
Publication Date (Web): January 17, 2004 (Article)
DOI: 10.1021/cr020610c

Chemistry of Nitric Oxide Relevant to Biology

J. A. McCleverty
pp 403–418
Publication Date (Web): January 21, 2004 (Article)
DOI: 10.1021/cr020623q

Electronic Structures of Metal Sites in Proteins and Models:  Contributions to Function in Blue Copper Proteins

Edward I. Solomon, Robert K. Szilagyi, Serena DeBeer George, and Lipika Basumallick
pp 419–458
Publication Date (Web): January 10, 2004 (Article)
DOI: 10.1021/cr0206317

Quantum Chemical Studies of Intermediates and Reaction Pathways in Selected Enzymes and Catalytic Synthetic Systems

Louis Noodleman, Timothy Lovell, Wen-Ge Han, Jian Li, and Fahmi Himo
pp 459–508
Publication Date (Web): January 27, 2004 (Article)
DOI: 10.1021/cr020625a

Biosynthesis of Metal Sites

Jason Kuchar and Robert P. Hausinger
pp 509–526
Publication Date (Web): December 16, 2003 (Article)
DOI: 10.1021/cr020613p

Classic Systems

Synthetic Analogues of the Active Sites of Iron−Sulfur Proteins

P. Venkateswara Rao and R. H. Holm
pp 527–560
Publication Date (Web): October 30, 2003 (Article)
DOI: 10.1021/cr020615+

Functional Analogues of Cytochrome c Oxidase, Myoglobin, and Hemoglobin

James P. Collman, Roman Boulatov, Christopher J. Sunderland, and Lei Fu
pp 561–588
Publication Date (Web): December 16, 2003 (Article)
DOI: 10.1021/cr0206059

Electron Transfer Centers

Models of the Bis-Histidine-Ligated Electron-Transferring Cytochromes. Comparative Geometric and Electronic Structure of Low-Spin Ferro- and Ferrihemes

F. Ann Walker
pp 589–616
Publication Date (Web): January 07, 2004 (Article)
DOI: 10.1021/cr020634j

Heme Protein Assemblies

Charles J. Reedy and Brian R. Gibney
pp 617–650
Publication Date (Web): January 24, 2004 (Article)
DOI: 10.1021/cr0206115

Electron Transfer by Copper Centers

David B. Rorabacher
pp 651–698
Publication Date (Web): January 22, 2004 (Article)
DOI: 10.1021/cr020630e

Non-Redox Sites

Synthetic Analogues Relevant to the Structure and Function of Zinc Enzymes

Gerard Parkin
pp 699–768
Publication Date (Web): January 24, 2004 (Article)
DOI: 10.1021/cr0206263

Zinc−Nucleic Acid Interaction

Shin AokiEiichi Kimura
pp 769–788
Publication Date (Web): January 27, 2004 (Article)
DOI: 10.1021/cr020617u

The Design of Functional DNA-Binding Proteins Based on Zinc Finger Domains

Derek Jantz, Barbara T. Amann, Gregory J. Gatto, Jr., and Jeremy M. Berg
pp 789–800
Publication Date (Web): December 09, 2003 (Article)
DOI: 10.1021/cr020603o

Metallothioneins:  Zinc, Cadmium, Mercury, and Copper Thiolates and Selenolates Mimicking Protein Active Site Features − Structural Aspects and Biological Implications

Gerald Henkel and Bernt Krebs
pp 801–824
Publication Date (Web): January 28, 2004 (Article)
DOI: 10.1021/cr020620d

Synthetic Analogues of Cysteinate-Ligated Non-Heme Iron and Non-Corrinoid Cobalt Enzymes

Julie A. Kovacs
pp 825–848
Publication Date (Web): January 27, 2004 (Article)
DOI: 10.1021/cr020619e

Redox Sites

The Chemistry and Biochemistry of Vanadium and the Biological Activities Exerted by Vanadium Compounds

Debbie C. Crans, Jason J. Smee, Ernestas Gaidamauskas, and Luqin Yang
pp 849–902
Publication Date (Web): January 29, 2004 (Article)
DOI: 10.1021/cr020607t

Structural, Spectroscopic, and Reactivity Models for the Manganese Catalases

Amy J. Wu, James E. Penner-Hahn, and Vincent L. Pecoraro
pp 903–938
Publication Date (Web): January 03, 2004 (Article)
DOI: 10.1021/cr020627v

Dioxygen Activation at Mononuclear Nonheme Iron Active Sites:  Enzymes, Models, and Intermediates

Miquel Costas, Mark P. Mehn, Michael P. Jensen, and Lawrence Que, Jr.
pp 939–986
Publication Date (Web): January 28, 2004 (Article)
DOI: 10.1021/cr020628n

Synthetic Models for Non-Heme Carboxylate-Bridged Diiron Metalloproteins:  Strategies and Tactics

Edit Y. Tshuva and Stephen J. Lippard
pp 987–1012
Publication Date (Web): January 21, 2004 (Article)
DOI: 10.1021/cr020622y

Structure and Spectroscopy of Copper−Dioxygen Complexes

Liviu M. Mirica, Xavier Ottenwaelder, and T. Daniel P. Stack
pp 1013–1046
Publication Date (Web): January 29, 2004 (Article)
DOI: 10.1021/cr020632z

Reactivity of Dioxygen−Copper Systems

Elizabeth A. Lewis and William B. Tolman
pp 1047–1076
Publication Date (Web): January 13, 2004 (Article)
DOI: 10.1021/cr020633r

Synthetic Models for Heme−Copper Oxidases

Eunsuk Kim, Eduardo E. Chufán, Kaliappan Kamaraj, and Kenneth D. Karlin
pp 1077–1134
Publication Date (Web): January 28, 2004 (Article)
DOI: 10.1021/cr0206162

The Clusters of Nitrogenase:  Synthetic Methodology in the Construction of Weak-Field Clusters

Sonny C. Lee and R. H. Holm
pp 1135–1158
Publication Date (Web): November 06, 2003 (Article)
DOI: 10.1021/cr0206216

Formation and Insertion of the Nitrogenase Iron−Molybdenum Cofactor

Patricia C. Dos Santos, Dennis R. Dean, Yilin Hu, and Markus W. Ribbe
pp 1159–1174
Publication Date (Web): December 12, 2003 (Article)
DOI: 10.1021/cr020608l

Synthetic Analogues and Reaction Systems Relevant to the Molybdenum and Tungsten Oxotransferases

John H. Enemark and J. Jon A. CooneyJun-Jieh Wang and R. H. Holm
pp 1175–1200
Publication Date (Web): December 09, 2003 (Article)
DOI: 10.1021/cr020609d
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