Table of Contents

November 1997
Volume 9, Issue 11
Pages 2247-2646
For Selected Content:

Articles

Preface to the Special Issue:  Sol−Gel Derived Materials

Jackie Y. Ying, Guest Editor
pp 2247–2248
Publication Date (Web): November 18, 1997 (Editorial)
DOI: 10.1021/cm970999y
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Luminescent Si Nanoparticles in Sol−Gel Matrices Stabilized by Amino Acids

Libing Zhang and Jeffery L. CofferWei Xu and T. W. Zerda
pp 2249–2251
Publication Date (Web): November 18, 1997 (Communication)
DOI: 10.1021/cm970319r

Methyltrioxorhenium Encapsulated in Zeolite Y:  Tunable Olefin Metathesis Catalyst

Thomas Bein, Christian Huber, Karin Moller, Chun-Guey Wu, and Langqiu Xu
pp 2252–2254
Publication Date (Web): November 18, 1997 (Communication)
DOI: 10.1021/cm970332b

Simple Absorption Optical Fiber pH Sensor Based on Doped Sol−Gel Cladding Material

O. Ben-David, E. Shafir, I. Gilath, Y. Prior, and D. Avnir
pp 2255–2257
Publication Date (Web): November 18, 1997 (Communication)
DOI: 10.1021/cm9703334

An Efficient Sol−Gel Reactor for Antibody-Catalyzed Transformations

Doron Shabat, Flavio Grynszpan, Sigal Saphier, Avner Turniansky, David Avnir, and Ehud Keinan
pp 2258–2260
Publication Date (Web): November 18, 1997 (Communication)
DOI: 10.1021/cm970193y

Optical Biosensing of Gaseous Nitric Oxide Using Spin-Coated Sol−Gel Thin Films

Jonathan W. Aylott, David J. Richardson, and David A. Russell
pp 2261–2263
Publication Date (Web): November 18, 1997 (Communication)
DOI: 10.1021/cm970324v

Direct Formation of Aerogels by Sol−Gel Polymerizations of Alkoxysilanes in Supercritical Carbon Dioxide

Douglas A. Loy, Edward M. Russick, Stacey A. Yamanaka, and Brigitta M. BaugherKenneth J. Shea
pp 2264–2268
Publication Date (Web): November 18, 1997 (Communication)
DOI: 10.1021/cm970326f

In Situ Studies of the Sol−Gel Synthesis of Materials

Anthony K. Cheetham and Caroline F. Mellot
pp 2269–2279
Publication Date (Web): November 18, 1997 (Review)
DOI: 10.1021/cm970497k

Probes of Pore Environment and Molecule−Matrix Interactions in Sol−Gel Materials

Bruce Dunn and Jeffrey I. Zink
pp 2280–2291
Publication Date (Web): November 18, 1997 (Review)
DOI: 10.1021/cm970270p

Nonhydrolytic Sol−Gel Routes to Oxides

A. Vioux
pp 2292–2299
Publication Date (Web): November 18, 1997 (Review)
DOI: 10.1021/cm970322a

Sol−Gel Synthesis of Organized Matter

Stephen Mann, Sandra L. Burkett, Sean A. Davis, Christabel E. Fowler, Neil H. Mendelson, Stephen D. Sims, Dominic Walsh, and Nicola T. Whilton
pp 2300–2310
Publication Date (Web): November 18, 1997 (Review)
DOI: 10.1021/cm970274u

Titania−Silica:  A Model Binary Oxide Catalyst System

Robert J. Davis and Zhufang Liu
pp 2311–2324
Publication Date (Web): November 18, 1997 (Review)
DOI: 10.1021/cm970314u

Chemical Solution Deposition of Perovskite Thin Films

Robert W. Schwartz
pp 2325–2340
Publication Date (Web): November 18, 1997 (Review)
DOI: 10.1021/cm970286f

Light-Induced Charge Separation at Sensitized Sol−Gel Processed Semiconductors

Jeremy M. Stipkala, Felix N. Castellano, Todd A. Heimer, Craig A. Kelly, Kenneth J. T. Livi, and Gerald J. Meyer
pp 2341–2353
Publication Date (Web): November 18, 1997 (Review)
DOI: 10.1021/cm9703177

Sol−Gel Materials in Electrochemistry

O. Lev, Z. Wu, S. Bharathi, V. Glezer, A. Modestov, J. Gun, L. Rabinovich, and S. Sampath
pp 2354–2375
Publication Date (Web): November 18, 1997 (Review)
DOI: 10.1021/cm970367b

Probing the Dynamics of the Silica Nanostructure Formation and Growth by SAXS

Hacène Boukari, J. S. Lin, and M. T. Harris
pp 2376–2384
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm9702878

17O Solution NMR Characterization of the Preparation of Sol−Gel Derived SiO2/TiO2 and SiO2/ZrO2 Glasses

Laurent Delattre and Florence Babonneau
pp 2385–2394
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm970372f

Precursor Aluminum Effect in the Synthesis of Sol−Gel Si−Al Catalysts:  FTIR and NMR Characterization

M. May, M. Asomoza, T. Lopez, and R. Gomez
pp 2395–2399
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm970320q

Aero-Sol−Gel Synthesis of Nanostructured Silica Powders

Jingyu Hyeon-Lee, Gregory Beaucage, and Sotiris E. Pratsinis
pp 2400–2403
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm9703482

Preparation of Silica and Alumina Single Oxides from Commercial Preformed Sols

Steven J. Monaco and Edmond I. Ko
pp 2404–2417
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm970271h

Aqueous Synthesis of Water-Soluble Alumoxanes:  Environmentally Benign Precursors to Alumina and Aluminum-Based Ceramics

Rhonda L. Callender, C. Jeff Harlan, Noah M. Shapiro, Christopher D. Jones, Daniel L. Callahan, Mark R. Wiesner, D. Brent MacQueen, Ron Cook, and Andrew R. Barron
pp 2418–2433
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm9703684

Synthesis of Polycarbosilane/Siloxane Hybrid Polymers and Their Pyrolytic Conversion to Silicon Oxycarbide Ceramics

Q. Liu, W. Shi, F. Babonneau, and L. V. Interrante
pp 2434–2441
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm970316e

Effects of Dispersion and Aggregation of Silica in the Reinforcement of Poly(methyl acrylate) Elastomers

Zhengcai Pu and James E. MarkJagdish M. Jethmalani and Warren T. Ford
pp 2442–2447
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm970210j

Effect of Micropore Topology on the Structure and Properties of Zeolite Polymer Replicas

Stacy A. Johnson, Elaine S. Brigham, Patricia J. Ollivier, and Thomas E. Mallouk
pp 2448–2458
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm9703278

Fractal Analysis of Polymeric and Particulate Titania Aerogels by Adsorption

F. Meng, J. R. Schlup, and L. T. Fan
pp 2459–2463
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm9700662

Heat Treatment of Alumina Aerogels

Shani Keysar, Gennady E. Shter,* Yoram de Hazan, Yachin Cohen, and Gideon S. Grader
pp 2464–2467
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm970208s

Alkaline-Earth Oxide Nanoparticles Obtained by Aerogel Methods. Characterization and Rational for Unexpectedly High Surface Chemical Reactivities

Olga B. Koper, Isabelle Lagadic, Alexander Volodin, and Kenneth J. Klabunde
pp 2468–2480
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm970357a

Destructive Adsorption of Chlorinated Hydrocarbons on Ultrafine (Nanoscale) Particles of Calcium Oxide. 3. Chloroform, Trichloroethene, and Tetrachloroethene

Olga Koper and Kenneth J. Klabunde
pp 2481–2485
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm9703583

Effective Inorganic Hybrid Adsorbents of Water Vapor by the Sol−Gel Method

Julita Mrowiec-Białoń, Andrzej B. Jarzbski, Andrzej I. Lachowski, Janusz J. Malinowski, and Yuri I. Aristov
pp 2486–2490
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm9703280

Tailoring the Framework and Textural Mesopores of HMS Molecular Sieves through an Electrically Neutral (S°I°) Assembly Pathway

Wenzhong Zhang, Thomas R. Pauly, and Thomas J. Pinnavaia
pp 2491–2498
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm970354y

Characterization of Large-Pore MCM-41 Molecular Sieves Obtained via Hydrothermal Restructuring

A. Sayari and P. LiuM. Kruk and M. Jaroniec
pp 2499–2506
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm970128o

Mesoporous Silica Synthesized by Solvent Evaporation:  Spun Fibers and Spray-Dried Hollow Spheres

Paul J. Bruinsma, Anthony Y. Kim, Jun Liu, and Suresh Baskaran
pp 2507–2512
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm970282a

Mesostructured Vanadium Oxide Containing Dodecylamine

Ping Liu, Igor L. Moudrakovski, Jun Liu, and Abdelhamid Sayari
pp 2513–2520
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm970067u

Enhancement of Uranyl Adsorption Capacity and Selectivity on Silica Sol−Gel Glasses via Molecular Imprinting

Sheng Dai, Y. S. Shin, C. E. Barnes, and L. M. Toth
pp 2521–2525
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm970209k

Decomposition of Pinacyanol Chloride Dye Using Several Manganese Oxide Catalysts

Scott R. Segal and Steven L. SuibLafayette Foland
pp 2526–2532
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm9702934

Sol-Gel Derived Ormosil-Exfoliated Graphite−TiO2 Composite Floating Catalyst:  Photodeposition of Copper

Kumaran Ramanathan, David Avnir, Alexander Modestov, and Ovadia Lev
pp 2533–2540
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm960637a

Preparation and Characterization of CdS Films Synthesized in Situ in Zirconia Sol−Gel Matrix

M. Zelner, H. Minti, and R. ReisfeldH. Cohen and R. Tenne
pp 2541–2543
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm970245j

Sol−Gel Template Synthesis of Semiconductor Oxide Micro- and Nanostructures

Brinda B. Lakshmi, Charles J. Patrissi, and Charles R. Martin
pp 2544–2550
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm970268y

Metal Complexes in Inorganic Matrixes. 18.1 Phosphanyl-Substituted Titanium and Zirconium Alkoxides for Tethering Metal Complexes on Titania or Zirconia and the X-ray Structure Analysis of Polymeric Zr(OPr)(O3SMe)3

Anne Lorenz, Guido Kickelbick, and Ulrich Schubert
pp 2551–2560
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm9702575

Synthesis of Monophasic Hybrid Organic−Inorganic Solids Containing [η6-(Organosilyl)arene]chromium Tricarbonyl Moieties

Geneviève Cerveau, Robert J. P. Corriu, and Cédric Lepeytre
pp 2561–2566
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm9703233

Sol−Gel Synthesis and Characterization of Magnesium Silicate Thin Films

Steven A. Jones, Shan Wong, and James M. BurlitchSriram Viswanathan and David L. Kohlstedt
pp 2567–2576
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm970401m

Use of (Glycidoxypropyl)trimethoxysilane as a Binder in Colloidal Silica Coatings

L. Chu, M. W. Daniels, and L. F. Francis
pp 2577–2582
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm9702880

Design and Characterization of Interconnected, Microporous Hybrid Thin Films by a Sol−Gel Process

Yongan Yan, Yasukazu Hoshino, Zhibang Duan, S. Ray Chaudhuri, and Arnab Sarkar
pp 2583–2587
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm970503c

Luminescence Properties of Tris(2,2‘-bipyridine)ruthenium(II) in Sol−Gel Systems of SiO2

Kazunori Matsui and Fumitoshi Momose
pp 2588–2591
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm970186+

In Situ Dehydroxylation in Eu3+-Doped Sol−Gel Silica

Brandon T. Stone, Vilma C. Costa, and Kevin L. Bray
pp 2592–2598
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm970265l

Fabrication and Characterization of Uranium Oxide Doped Sol−Gel Planar Waveguides for Attenuated Total Reflectance Spectrometry

Paul L. Edmiston and S. Scott Saavedra
pp 2599–2603
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm970429y

Sol−Gel Replication of Microoptical Elements and Arrays

Y. Haruvy, I. Gilath, M. Maniewictz, and N. Eisenberg
pp 2604–2615
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm970229m

Effect of Copper Precursor on the Stabilization of Titania Phases, and the Optical Properties of Cu/TiO2 Prepared with the Sol−Gel Technique

X. Bokhimi, A. Morales, and O. NovaroT. López, O. Chimal, M. Asomoza, and R. Gómez
pp 2616–2620
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm970279r

Electrochemically Assisted Sol−Gel Process for the Synthesis of Polysiloxane Films Incorporating Phenothiazine Dyes Analogous to Methylene Blue. Structure and Ion-Transport Properties of the Films via Spectroscopic and Electrochemical Characterization

Nicholas Leventis and Muguo Chen
pp 2621–2631
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm970261g

Sol−Gel Matrixes Doped with Atrazine Antibodies:  Atrazine Binding Properties

Alisa Bronshtein, Nadav Aharonson, David Avnir, Avner Turniansky, and Miriam Altstein
pp 2632–2639
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm970330r

Optimization of the Selectivity of Pyrene Immunoaffinity Columns Prepared by the Sol−Gel Method

Margit Cichna and Peter MarklDietmar Knopp and Reinhard Niessner
pp 2640–2646
Publication Date (Web): November 18, 1997 (Article)
DOI: 10.1021/cm970248w
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