Articles ASAP (As Soon As Publishable)

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November 20, 2009

Structural and Spectroscopic Studies of the PCP-Bridged Heavy Chalcogen-Centered Monoanions [HC(PPh2E)(PPh2)]− (E = Se, Te) and [HC(PR2E)2]− (E = Se, Te, R = Ph; E = Se, R = iPr): Homoleptic Group 12 Complexes and One-Electron Oxidation of [HC(PR2Se)2]−

Jari Konu, Heikki M. Tuononen and Tristram Chivers
Publication Date (Web): November 20, 2009 (Article)
DOI: 10.1021/ic901878h

New Strategy for Synthesis of Mercaptoundecahydrododecaborate Derivatives via Click Chemistry: Possible Boron Carriers and Visualization in Cells for Neutron Capture Therapy

Mohamed E. El-Zaria and Hiroyuki Nakamura
Publication Date (Web): November 20, 2009 (Article)
DOI: 10.1021/ic902033c

Formation of a 3-D Porous Ferric Arsenate Containing Novel Cubane-like Fe4F4 Building Units

Zhihui Yi, Chao Yang, Wujiong Xia, Xianzhu Xu and Xiao Zhang
Publication Date (Web): November 20, 2009 (Addition/Correction)
DOI: 10.1021/ic902137b

Photochemical Stereospecific Hydrogenation of a Ru Complex with an NAD+/NADH-Type Ligand

Takashi Fukushima, Etsuko Fujita, James T. Muckerman, Dmitry E. Polyansky, Tohru Wada and Koji Tanaka
Publication Date (Web): November 20, 2009 (Communication)
DOI: 10.1021/ic901935u

Luminescence Properties and Energy Transfer of Site-Sensitive Ca6−x−yMgx−z(PO4)4:Euy2+,Mnz2+ Phosphors and Their Application to Near-UV LED-Based White LEDs

Ki Hyuk Kwon, Won Bin Im, Ho Seong Jang, Hyoung Sun Yoo and Duk Young Jeon
Publication Date (Web): November 20, 2009 (Article)
DOI: 10.1021/ic900809b

November 19, 2009

A Selective Redox and Chromogenic Probe for Hg(II) in Aqueous Environment Based on a Ferrocene−Azaquinoxaline Dyad

Fabiola Zapata, Antonio Caballero, Arturo Espinosa, Alberto Trraga and Pedro Molina
Publication Date (Web): November 19, 2009 (Article)
DOI: 10.1021/ic901234d

Cubes, Squares, and Books: A Simple Transition Metal/Bridging Ligand Combination Can Lead to a Surprising Range of Structural Types with the Same Metal/Ligand Proportions

Adel M. Najar, Ian S. Tidmarsh, Harry Adams and Michael D. Ward
Publication Date (Web): November 19, 2009 (Article)
DOI: 10.1021/ic901892y

November 18, 2009

Tridentate Assembling Ligands Based on Oxazoline and Phosphorus Donors in Dinuclear Pd(I)−Pd(I) Complexes

Jing Zhang, Roberto Pattacini and Pierre Braunstein
Publication Date (Web): November 18, 2009 (Article)
DOI: 10.1021/ic9018579

Efficient Transfer of Either One or Two Dithiolene Ligands from Nickel to Ruthenium: Synthesis and Crystal Structures of [Ru(SCR═CPhS)2(PPh3)] and [RuCl2(SCR═CPhS)(PPh3)2] (R = Ph, H)

Harry Adams, Anna M. Coffey, Michael J. Morris and Sarah A. Morris
Publication Date (Web): November 18, 2009 (Article)

Hydration and Hydrolysis of Thorium(IV) in Aqueous Solution and the Structures of Two Crystalline Thorium(IV) Hydrates

Natallia Torapava, Ingmar Persson, Lars Eriksson and Daniel Lundberg
Publication Date (Web): November 18, 2009 (Article)
DOI: 10.1021/ic901763s

First-Principle Calculation-Assisted Structural Study on the Nanoscale Phase Transition of Si for Li-Ion Secondary Batteries

Yong-Mook Kang, Seung-Bum Suh and Yang-Soo Kim
Publication Date (Web): November 18, 2009 (Article)
DOI: 10.1021/ic901674s

Structure of Bayerite-Based Lithium−Aluminum Layered Double Hydroxides (LDHs): Observation of Monoclinic Symmetry

Sylvia Britto and P. Vishnu Kamath
Publication Date (Web): November 18, 2009 (Article)
DOI: 10.1021/ic9016728

Oxidation Chemistry of Axially Protected Mo2 and W2 Quadruply Bonded Compounds

Michael Nippe, Eric Victor and John F. Berry
Publication Date (Web): November 18, 2009 (Article)
DOI: 10.1021/ic901965b

November 17, 2009

Asymmetric Twisting and Chirality Probing Properties of Quadruple-Stranded Helicates: Coordination Versatility and Chirality Response of Na+, Ca2+, and La3+ Complexes with Octadentate Cyclen Ligand

Hitomi Misaki, Hiroyuki Miyake, Satoshi Shinoda and Hiroshi Tsukube
Publication Date (Web): November 17, 2009 (Article)
DOI: 10.1021/ic901496s

Syntheses, Crystal Structures, and Properties of Five New Transition Metal Molybdenum(VI) Selenites and Tellurites

Su-Yun Zhang, Hai-Long Jiang, Chuan-Fu Sun and Jiang-Gao Mao
Publication Date (Web): November 17, 2009 (Article)
DOI: 10.1021/ic901855x

La1−xCexCrO3 (0.0 ≤ x ≤ 1.0): A New Series of Solid Solutions with Tunable Magnetic and Optical Properties

Rakesh Shukla, Jayappa Manjanna, Anup K. Bera, Seikh M. Yusuf and Avesh K. Tyagi
Publication Date (Web): November 17, 2009 (Article)
DOI: 10.1021/ic901735d

Formation of Hydrides in (Ti1−xZrx)Co2.00 (0 < x < 1) Pseudobinary Alloys

H. T. Kuo, R. S. Liu, S. M. Filipek, R. Wierzbicki, R. Sato, C. L. Chan, H. D. Yang and J.-F. Lee
Publication Date (Web): November 17, 2009 (Article)
DOI: 10.1021/ic901760j

“Amorphous Nickel Sulfide” Is Hydrated Nanocrystalline NiS with a Core−Shell Structure

Shanshan Huang, Kenneth D. M. Harris, Elisa Lopez-Capel, David A. C. Manning and David Rickard
Publication Date (Web): November 17, 2009 (Communication)
DOI: 10.1021/ic901512z

Syntheses, Crystal and Electronic Structures, and Physical Properties of Two Quaternary Chalcogenides: La4FeSb2Q10 (Q = S, Se)

Hua-Jun Zhao, Long-Hua Li, Li-Ming Wu and Ling Chen
Publication Date (Web): November 17, 2009 (Article)
DOI: 10.1021/ic900784t

November 16, 2009

Facile Room Temperature Ion-Exchange Synthesis of Sn2+ Incorporated Pyrochlore-Type Oxides and Their Photocatalytic Activities

S. Uma, Jyoti Singh and Vaishali Thakral
Publication Date (Web): November 16, 2009 (Article)
DOI: 10.1021/ic901658w

Ligand-Controlled Magnetic Interactions in Mn4 Clusters

Erik Kampert, Femke F. B. J. Janssen, Danil W. Boukhvalov, Jaap C. Russcher, Jan M. M. Smits, Ren de Gelder, Bas de Bruin, Peter C. M. Christianen, Uli Zeitler, Mikhail I. Katsnelson, Jan C. Maan and Alan E. Rowan
Publication Date (Web): November 16, 2009 (Article)
DOI: 10.1021/ic901930w

Anti-Mackay Polyicosahedral Clusters in La−Ni−Mg Ternary Compounds: Synthesis and Crystal Structure of the La43Ni17Mg5 New Intermetallic Phase

Pavlo Solokha, Serena De Negri, Volodymyr Pavlyuk and Adriana Saccone
Publication Date (Web): November 16, 2009 (Article)
DOI: 10.1021/ic901422v

November 13, 2009

Functionalization of Methyl (R)-Phenylglycinate Through Orthopalladation: C−Hal, C−O, C−N, and C−C Bond Coupling

Sonia Nieto, Palmira Arnau, Elena Serrano, Rafael Navarro, Tatiana Soler, Carlos Cativiela and Esteban P. Urriolabeitia
Publication Date (Web): November 13, 2009 (Article)
DOI: 10.1021/ic901941s

Direct Solid-State Synthesis at High Pressures of New Mixed-Metal Oxynitrides: RZrO2N (R = Pr, Nd, and Sm)

Minghui Yang, Jennifer A. Rodgers, Lawrence C. Middler, Judith Or-Sol, A. Beln Jorge, Amparo Fuertes and J. Paul Attfield
Publication Date (Web): November 13, 2009 (Communication)
DOI: 10.1021/ic902020r

Evidence of Disruption of Conjugation Involving Delta Bonds in Intramolecular Electronic Coupling

F. Albert Cotton, Zhong Li and Carlos A. Murillo
Publication Date (Web): November 13, 2009 (Article)
DOI: 10.1021/ic9018647

Synthesis, Structure, and Transformation Studies in a Family of Inorganic−Organic Hybrid Framework Structures Based on Indium

Padmini Ramaswamy, Nayana N. Hegde, Ramanath Prabhu, V. M. Vidya, Ayan Datta and Srinivasan Natarajan
Publication Date (Web): November 13, 2009 (Article)
DOI: 10.1021/ic901744m

Concerning the Possibility of Hidden One-Dimensional Fermi Surfaces for the K0.25WO3 Hexagonal Bronze

Roberta Poloni, Enric Canadell and Jean-Paul Pouget
Publication Date (Web): November 13, 2009 (Communication)
DOI: 10.1021/ic901725f

Selective Complexation and Reactivity of Metallic Nitride and Oxometallic Fullerenes with Lewis Acids and Use as an Effective Purification Method

Steven Stevenson, Mary A. Mackey, Jane E. Pickens, Melissa A. Stuart, Bridget S. Confait and J. Paige Phillips
Publication Date (Web): November 13, 2009 (Article)
DOI: 10.1021/ic9017147

Photophysics in Platinum(II) Bipyridylacetylides

Maria L. Muro, Stphane Diring, Xianghuai Wang, Raymond Ziessel and Felix N. Castellano
Publication Date (Web): November 13, 2009 (Article)
DOI: 10.1021/ic901036a

Synthesis, Characterization, and Magnetism of Divalent Aryl Transition-Metal Complexes of the Simplest Dialkylamide, NMe2: Rare T-Shaped Coordination at Chromium

Chengbao Ni, Gary J. Long, Fernande Grandjean and Philip P. Power
Publication Date (Web): November 13, 2009 (Article)
DOI: 10.1021/ic901462t

Eight-Coordinate Zn(II), Cd(II), and Pb(II) Complexes Based on a 1,7-Diaza-12-crown-4 Platform Endowed with a Remarkable Selectivity over Ca(II)

Raquel Ferreirs-Martnez, David Esteban-Gmez, Andrs de Blas, Carlos Platas-Iglesias and Teresa Rodrguez-Blas
Publication Date (Web): November 13, 2009 (Article)
DOI: 10.1021/ic901883h

Observation of Slow Magnetic Relaxation in Discrete Dysprosium Cubane

Yajie Gao, Gong-Feng Xu, Lang Zhao, Jinkui Tang and Zhiliang Liu
Publication Date (Web): November 13, 2009 (Communication)
DOI: 10.1021/ic901806g

Cerium(IV)−Lanthanide(III)−Pyridine-2,6-dicarboxylic Acid System: Coordination Salts, Chains, and Rings

T. K. Prasad and M. V. Rajasekharan
Publication Date (Web): November 13, 2009 (Article)
DOI: 10.1021/ic901066v

Hydrothermal Synthesis and Luminescent Properties of Novel Ordered Sphere CePO4 Hierarchical Architectures

Mei Yang, Hongpeng You, Yuhua Zheng, Kai Liu, Guang Jia, Yanhua Song, Yeju Huang, Lihui Zhang and Hongjie Zhang
Publication Date (Web): November 13, 2009 (Article)
DOI: 10.1021/ic901829v

Synthesis, Crystal Structure, and Vibrational Spectroscopy of K2Ca4Si8O21—An Unusual Single-Layer Silicate Containing Q2 and Q3 Units

E. Arroyabe, R. Kaindl, D.M. Tbbens and V. Kahlenberg
Publication Date (Web): November 13, 2009 (Article)
DOI: 10.1021/ic901762u

November 12, 2009

Solid State and Solution Dynamics of Pyridine Based Tetraaza-Macrocyclic Lanthanide Chelates Possessing Phosphonate Ligating Functionality (Ln-PCTMB): Effect on Relaxometry and Optical Properties

Garry E. Kiefer and Mark Woods
Publication Date (Web): November 12, 2009 (Article)
DOI: 10.1021/ic901779k

Neptunium Carbonato Complexes in Aqueous Solution: An Electrochemical, Spectroscopic, and Quantum Chemical Study

Atsushi Ikeda-Ohno, Satoru Tsushima, Koichiro Takao, Andr Rossberg, Harald Funke, Andreas C. Scheinost, Gert Bernhard, Tsuyoshi Yaita and Christoph Hennig
Publication Date (Web): November 12, 2009 (Article)
DOI: 10.1021/ic901838r

November 11, 2009

{[Ga(en)3]2(Ge2Te15)}n: A Polymeric Semiconducting Polytelluride with Boat-Shaped Te84− Rings and Cross-Shaped Te56− Units

Qichun Zhang, Christos D. Malliakas and Mercouri G. Kanatzidis
Publication Date (Web): November 11, 2009 (Communication)
DOI: 10.1021/ic9019074

Redox Reactions of Pu(IV) and Pu(III) in the Presence of Acetohydroxamic Acid in HNO3 Solutions

Peter Tkac, Martin Precek and Alena Paulenova
Publication Date (Web): November 11, 2009 (Article)
DOI: 10.1021/ic901081j

Systematic Method for the Incorporation of the {(η6-Arene)Fe} Fragment into Carborane Cages via [(η6-Arene)Fe]2+ Dications. A Series of [3-(η6-Arene)-closo-3,1,2-FeC2B9H11] Complexes. Reliable Synthesis of Polymethylated [(η6-Arene)2Fe]2+ Cations

B. tbr, M. Bakardjiev, Josef Holub, Ale Rika and Magdalena Kvalov
Publication Date (Web): November 11, 2009 (Communication)
DOI: 10.1021/ic901982q

Three-Dimensional Frameworks of Cubic (NH4)5Ga4SbS10, (NH4)4Ga4SbS9(OH)·H2O, and (NH4)3Ga4SbS9(OH2)·2H2O

Joshua L. Mertz, Nan Ding and Mercouri G. Kanatzidis
Publication Date (Web): November 11, 2009 (Communication)
DOI: 10.1021/ic901927r

November 10, 2009

Ferric Stability Constants of Representative Marine Siderophores: Marinobactins, Aquachelins, and Petrobactin

Guangping Zhang, Shady A. Amin, Frithjof C. Kpper, Pamela D. Holt, Carl J. Carrano and Alison Butler
Publication Date (Web): November 10, 2009 (Article)
DOI: 10.1021/ic901739m

Using the Antenna Effect as a Spectroscopic Tool: Photophysics and Solution Thermodynamics of the Model Luminescent Hydroxypyridonate Complex [EuIII(3,4,3-LI(1,2-HOPO))]−

Rebecca J. Abergel, Anthony D’Alo, Clara Ng Pak Leung, David K. Shuh and Kenneth N. Raymond
Publication Date (Web): November 10, 2009 (Communication)
DOI: 10.1021/ic9013703

Synthesis and Optical Properties of Guanosine 5′-Monophosphate-Mediated CdS Nanostructures: An Analysis of their Structure, Morphology, and Electronic Properties

Anil Kumar and Vinit Kumar
Publication Date (Web): November 10, 2009 (Article)
DOI: 10.1021/ic901205c

Heavy Alkali Metal Amides: Role of Secondary Interactions in Metal Stabilization

Ana Torvisco, Katharina Decker, Frank Uhlig and Karin Ruhlandt-Senge
Publication Date (Web): November 10, 2009 (Article)

Copper(I), Silver(I), and Palladium(II) Complexes of a Thiaoxamacrocycle Displaying Unusual Topologies

So Young Lee, Sunhong Park and Shim Sung Lee
Publication Date (Web): November 10, 2009 (Article)
DOI: 10.1021/ic901902t

Guest-Induced Irreversible Sliding in a Flexible 2D Rectangular Grid with Selective Sorption Characteristics

K. L. Gurunatha and Tapas Kumar Maji
Publication Date (Web): November 10, 2009 (Communication)
DOI: 10.1021/ic901804a

Palladium Motion in Cyclomeric Compounds: A Theoretical Study

Antonio J. Mota and Alain Dedieu
Publication Date (Web): November 10, 2009 (Article)
DOI: 10.1021/ic901506v

November 9, 2009

Luminescent Copper(I) Halide Butterfly Dimers Coordinated to [Au(CH3imCH2py)2]BF4 and [Au(CH3imCH2quin)2]BF4

Vincent J. Catalano, Adam L. Moore, Jason Shearer and Jineun Kim
Publication Date (Web): November 9, 2009 (Article)
DOI: 10.1021/ic901914n

November 6, 2009

CuII-Azide Polymers of Cu3 and Cu6 Building Units: Synthesis, Structures, and Magnetic Exchange Mechanism

Sandip Mukherjee, Bappaditya Gole, Rajesh Chakrabarty and Partha Sarathi Mukherjee
Publication Date (Web): November 6, 2009 (Article)
DOI: 10.1021/ic901844j

From Monomers to Geometry-Constrained Molecules: One Step Further Toward Cyanide Bridged Wires

Pablo Albors, Leonardo D. Slep, Livia S. Eberlin, Yuri E. Corilo, Marcos N. Eberlin, Guillermo Bentez, Maria E. Vela, Roberto C. Salvarezza and Luis M. Baraldo
Publication Date (Web): November 6, 2009 (Article)
DOI: 10.1021/ic901710x

Catalytic Aerobic Oxidation by a Trianionic Pincer CrIII/CrV Couple

Matthew O’Reilly, Joseph M. Falkowski, Vasanth Ramachandran, Mekhala Pati, Khalil A. Abboud, Naresh S. Dalal, Thomas G. Gray and Adam S. Veige
Publication Date (Web): November 6, 2009 (Communication)
DOI: 10.1021/ic9019469

Self-Assembly of a Pd6−Molecular Double-Square and a Cu3-Trigonalbipyramidal Cage via a New Tripodal Flexible Ligand

Arun Kumar Bar, Rajesh Chakrabarty and Partha Sarathi Mukherjee
Publication Date (Web): November 6, 2009 (Communication)
DOI: 10.1021/ic901633g

November 5, 2009

Copper(I) Complexes derived from Mono- and Diphosphino-Boranes: Cu→B Interactions Supported by Arene Coordination

M. Sircoglou, S. Bontemps, M. Mercy, K. Miqueu, S. Ladeira, N. Saffon, L. Maron, G. Bouhadir and D. Bourissou
Publication Date (Web): November 5, 2009 (Article)
DOI: 10.1021/ic901896z

Density Functional Theory Study of the Mechanisms of Oxidation of Ethylene by Chromyl Chloride

Richard Tia and Evans Adei
Publication Date (Web): November 5, 2009 (Article)
DOI: 10.1021/ic901648y

Synthesis, Structures, and Luminescent and Magnetic Properties of Ln−Ag Heterometal−Organic Frameworks

Xiao-Qing Zhao, Bin Zhao, Shi Wei and Peng Cheng
Publication Date (Web): November 5, 2009 (Article)
DOI: 10.1021/ic901291b

Direct Synthesis, Crystal Structure, High-Field EPR, and Magnetic Studies on an Octanuclear Heterometallic Cu(II)/Cd Complex of Triethanolamine

Elena A. Buvaylo, Vladimir N. Kokozay, Olga Yu. Vassilyeva, Brian W. Skelton, Igor L. Eremenko, Julia Jezierska and Andrew Ozarowski
Publication Date (Web): November 5, 2009 (Article)
DOI: 10.1021/ic901466h

Theoretical Study of Structure and Electronic Absorption Spectra of Some Schiff Bases and Their Zinc Complexes

Kseniya G. Vladimirova, Alexandra Ya. Freidzon, Oxana V. Kotova, Andrei A. Vaschenko, Leonid S. Lepnev, Alexander A. Bagatur’yants, Alexei G. Vitukhnovskiy, Nickolai F. Stepanov and Michael V. Alfimov
Publication Date (Web): November 5, 2009 (Article)
DOI: 10.1021/ic9015004

November 4, 2009

2-Thienylcarboxylato and 2-Thienylthiocarboxylato Ligands Bonded to MM Quadruple Bonds (M = Mo or W): A Comparison of Ground State, Spectroscopic and Photoexcited State Properties

Brian G. Alberding, Malcolm H. Chisholm, Yi-Hsuan Chou, Yagnaseni Ghosh, Terry L. Gustafson, Yao Liu and Claudia Turro
Publication Date (Web): November 4, 2009 (Article)
DOI: 10.1021/ic901607u

Synthesis of Oxorhenium(V) Complexes with Diamido Amine Ancillary Ligands and Their Role in Oxygen Atom Transfer Catalysis

Yuee Feng, Joel Aponte, Paul J. Houseworth, Paul D. Boyle and Elon A. Ison
Publication Date (Web): November 4, 2009 (Article)
DOI: 10.1021/ic901434u

Ag(I)-Mediated In situ Dehydrogenative Coupling of 3-Amino-1,2,4-triazole into 3,3′-Azobis(1,2,4-triazole) in Cd(II) Coordination Polymers

Pei-Xiu Yin, Jian-Kai Cheng, Zhao-Ji Li, Lei Zhang, Ye-Yan Qin, Jian Zhang and Yuan-Gen Yao
Publication Date (Web): November 4, 2009 (Communication)
DOI: 10.1021/ic9007813

Study of the Influence of the Bridge on the Magnetic Coupling in Cobalt(II) Complexes

Oscar Fabelo, Laura Caadillas-Delgado, Jorge Pasn, Fernando S. Delgado, Francesc Lloret, Joan Cano, Miguel Julve and Catalina Ruiz-Prez
Publication Date (Web): November 4, 2009 (Article)
DOI: 10.1021/ic901843r

(I,0) Mixed-Valence State of a Diiron Complex with Pertinence to the [FeFe]-Hydrogenase Active Site: An IR, EPR, and Computational Study

Pradyumna S. Singh, Hans Christian Rudbeck, Ping Huang, Salah Ezzaher, Lars Eriksson, Matthias Stein, Sascha Ott and Reiner Lomoth
Publication Date (Web): November 4, 2009 (Communication)
DOI: 10.1021/ic9016454

Organoplatinum Complex Promoted the Asymmetric Endo Stereochemically Controlled Diels−Alder Reaction between 3-Diphenylphosphinofuran and Diphenylvinylphosphine

Fengli Liu, Sumod A. Pullarkat, Kien-Wee Tan, Yongxin Li and Pak-Hing Leung
Publication Date (Web): November 4, 2009 (Article)
DOI: 10.1021/ic9014543

November 3, 2009

Six-Coordinate Nitro Complexes of Iron(III) Porphyrins with trans S-Donor Ligands. Oxo-Transfer Reactivity in the Solid State

Tigran S. Kurtikyan, Astghik A. Hovhannisyan, Alexei V. Iretskii and Peter C. Ford
Publication Date (Web): November 3, 2009 (Article)
DOI: 10.1021/ic901722g

Copper(I)/O2 Chemistry with Imidazole Containing Tripodal Tetradentate Ligands Leading to μ-1,2-Peroxo−Dicopper(II) Species

Yunho Lee, Ga Young Park, Heather R. Lucas, Peter L. Vajda, Kaliappan Kamaraj, Michael A. Vance, Ashley E. Milligan, Julia S. Woertink, Maxime A. Siegler, Amy A. Narducci Sarjeant, Lev N. Zakharov, Arnold L. Rheingold, Edward I. Solomon and Kenneth D. Karlin
Publication Date (Web): November 3, 2009 (Article)
DOI: 10.1021/ic9017695

Ligand-Based Modification of the Structures and Optical Properties of New Silver(I)-Rhenate(VII) Oxide/Organic Hybrid Solids

Haisheng Lin, Xiaomeng Wu and Paul A. Maggard
Publication Date (Web): November 3, 2009 (Article)
DOI: 10.1021/ic901749r

Do the Structural Changes Defined by the Electron Density Topology Necessarily Affect the Picture of the Bonding?

Robert Ponec, Carlo Gatti
Publication Date (Web): November 3, 2009 (Article)
DOI: 10.1021/ic901197b

Visible-Light Excitable Europium(III) Complexes with 2,7-Positional Substituted Carbazole Group-Containing Ligands

P. He, H. H. Wang, S. G. Liu, J. X. Shi, G. Wang and M. L. Gong
Publication Date (Web): November 3, 2009 (Article)
DOI: 10.1021/ic901210c

November 2, 2009

Influence of Bonding Mode of the Linkers in the Electronic Communication of Molecular Pairs Having Dimolybdenum Units Linked by Pseudohalides

F. Albert Cotton, Carlos A. Murillo and Qinliang Zhao
Publication Date (Web): November 2, 2009 (Article)
DOI: 10.1021/ic901826y

Binding of 2-Hydroxypyridine-N-oxide on Dicopper(II) Centers: Insights into Tyrosinase Inhibition Mechanism by Transition-State Analogs

Eugnie Peyroux, Wadih Ghattas, Renaud Hardr, Michel Giorgi, Bruno Faure, A. Jalila Simaan, Catherine Belle and Marius Rglier
Publication Date (Web): November 2, 2009 (Communication)
DOI: 10.1021/ic901593x

Phosphonoacetate as a Ligand for Constructing Layered and Framework Alkali Metal Uranyl Compounds

Andrea N. Alsobrook and Thomas E. Albrecht-Schmitt
Publication Date (Web): November 2, 2009 (Article)
DOI: 10.1021/ic9014493

Bismuth Aryloxides

Xiaodi Kou, Xiaoyu Wang, Daniel Mendoza-Espinosa, Lev N. Zakharov, Arnold L. Rheingold, William H. Watson, Kimberly A. Brien, L. Kasun Jayarathna and Tracy A. Hanna
Publication Date (Web): November 2, 2009 (Article)
DOI: 10.1021/ic901134t

DNA-Cleavage Induced by New Macrocyclic Schiff base Dinuclear Cu(I) Complexes Containing Pyridyl Pendant Arms

Arnau Arbuse, Marc Font, Ma Angeles Martnez, Xavier Fontrodona, Ma Jos Prieto, Virtudes Moreno, Xavier Sala and Antoni Llobet
Publication Date (Web): November 2, 2009 (Article)
DOI: 10.1021/ic901488j

Structure and Reactivity of New Iridium Complexes with Bis(Oxazoline)-Phosphonito Ligands

Riccardo Peloso, Roberto Pattacini, Catherine S. J. Cazin and Pierre Braunstein
Publication Date (Web): November 2, 2009 (Article)
DOI: 10.1021/ic901579u

A New 2D Hybrid Indate-Germanate Based on the Linkages of Ge4O10F2 Clusters and {In2O6} Dimers

Jian Zhou, Zhi-Wu Yu, Wei-hui Fang, Feng Deng and Guo-Yu Yang
Publication Date (Web): November 2, 2009 (Communication)
DOI: 10.1021/ic901894m

Synthesis of Copper(I) Complexes Containing Enantiopure Pybox Ligands. First Assays on Enantioselective Synthesis of Propargylamines Catalyzed by Isolated Copper(I) Complexes

Mara Panera, Josefina Dez, Isabel Merino, Eduardo Rubio and M. Pilar Gamasa
Publication Date (Web): November 2, 2009 (Article)
DOI: 10.1021/ic901527x

October 30, 2009

Terphenyl Derivatives as “Turn On” Fluorescent Sensors for Mercury

Vandana Bhalla, Ruchi Tejpal, Manoj Kumar and Amandeep Sethi
Publication Date (Web): October 30, 2009 (Article)
DOI: 10.1021/ic9016933

Varied Reactions of [M(L)]3 with HgCl2, FeBr2, CeCl3, AgOTf; Ligand Transfer, Nucleophilic Attack with Recombination and/or Fragmentation [M = Li or Na; L = N(SiMe3){C(H)N}3SiMe3]

W. Marco Boesveld, Peter B. Hitchcock and Michael F. Lappert
Publication Date (Web): October 30, 2009 (Article)
DOI: 10.1021/ic901687a

Multifaceted Coordination of Naphthyridine−Functionalized N-Heterocyclic Carbene: A Novel “IrIII(CN)(CC)” Compound and Its Evaluation as Transfer Hydrogenation Catalyst

Arup Sinha, S. M. Wahidur Rahaman, Mithun Sarkar, Biswajit Saha, Prosenjit Daw and Jitendra K. Bera
Publication Date (Web): October 30, 2009 (Article)
DOI: 10.1021/ic901502n

Water Exchange Mechanism in the First Excited State of Hydrated Uranyl(VI)

Pernilla Whlin, Valrie Vallet, Ulf Wahlgren and Ingmar Grenthe
Publication Date (Web): October 30, 2009 (Article)
DOI: 10.1021/ic9017689

Electronic and Magnetic Study of Polycationic Mn12 Single-Molecule Magnets with a Ground Spin State S = 11

Juan M. Clemente-Juan, Eugenio Coronado, Alicia Forment-Aliaga, Alejandro Gaita-Ario, Carlos Gimnez-Saiz, Francisco M. Romero, W. Wernsdorfer, R. Biagi and V. Corradini
Publication Date (Web): October 30, 2009 (Article)
DOI: 10.1021/ic901824d

A New Ni12 Cluster Based on Polyoxometalate Ligands

Hong-Mei Zhang, Yang-Guang Li, Ying Lu, Rodolphe Clrac, Zhi-Ming Zhang, Qiong Wu, Xiao-Jia Feng and En-Bo Wang
Publication Date (Web): October 30, 2009 (Communication)
DOI: 10.1021/ic901552f

Probing the Excited State Properties of the Highly Phosphorescent Pt(dpyb)Cl Compound by High-Resolution Optical Spectroscopy

Andreas F. Rausch, Lisa Murphy, J. A. Gareth Williams and Hartmut Yersin
Publication Date (Web): October 30, 2009 (Article)
DOI: 10.1021/ic901523u

Structure Investigations of Dichloroaluminum Benzoates: An Unprecedented Example of a Monomeric Aluminum Complex with a Chelating Carboxylate Ligand

Zbigniew Florjaczyk, Wojciech Bury, Ewa Zygadło-Monikowska, Iwona Justyniak, Robert Balawender and Janusz Lewiski
Publication Date (Web): October 30, 2009 (Communication)
DOI: 10.1021/ic9016307

Structures, Metal Ion Affinities, and Fluorescence Properties of Soluble Derivatives of Tris((6-phenyl-2-pyridyl)methyl)amine

Jian Liang, Jing Zhang, Lei Zhu, Alexander Duarandin, Victor G. Young, , Jr., Nicholas Geacintov and James W. Canary
Publication Date (Web): October 30, 2009 (Article)
DOI: 10.1021/ic901662z

Does Iodate Incorporate into Layered Uranyl Phosphates Under Hydrothermal Conditions?

Jie Ling, Shijun Wu, Fanrong Chen, Antonio Simonetti, John T. Shafer and Thomas E. Albrecht-Schmitt
Publication Date (Web): October 30, 2009 (Article)
DOI: 10.1021/ic9011247

Self-Assembly of Metal-Organic Coordination Polymers Constructed from a Bent Dicarboxylate Ligand: Diversity of Coordination Modes, Structures, and Gas Adsorption

Wenbin Yang, Xiang Lin, Alexander J. Blake, Claire Wilson, Peter Hubberstey, Neil R. Champness and Martin Schrder
Publication Date (Web): October 30, 2009 (Article)
DOI: 10.1021/ic901429u

Selective Chelation of Cd(II) and Pb(II) versus Ca(II) and Zn(II) by Using Octadentate Ligands Containing Pyridinecarboxylate and Pyridyl Pendants

Raquel Ferreirs-Martnez, David Esteban-Gmez, Carlos Platas-Iglesias, Andrs de Blas and Teresa Rodrguez-Blas
Publication Date (Web): October 30, 2009 (Article)
DOI: 10.1021/ic900838j

October 29, 2009

Oxidizing Ru(II) Complexes as Irreversible and Specific Photo-Cross-Linking Agents of Oligonucleotide Duplexes

Liana Ghizdavu, Frdric Pierard, Stphane Rickling, Sabrina Aury, Mathieu Surin, David Beljonne, Roberto Lazzaroni, Pierre Murat, Eric Defrancq, Ccile Moucheron and Andre Kirsch-De Mesmaeker
Publication Date (Web): October 29, 2009 (Article)
DOI: 10.1021/ic901007w

Synthesis, Structure, and Bonding in K12Au21Sn4. A Polar Intermetallic Compound with Dense Au20 and Open AuSn4 Layers

Bin Li, Sung-Jin Kim, Gordon J. Miller and John D. Corbett
Publication Date (Web): October 29, 2009 (Article)
DOI: 10.1021/ic901493j

Molecular Conductors Based on the Mixed-Valence Polyoxometalates [SMo12O40]n− (n = 3 and 4) and the Organic Donors Bis(ethylenedithio)tetrathiafulvalene and Bis(ethylenedithio)tetraselenafulvalene

Eugenio Coronado, Simona Curreli, Carlos Gimnez-Saiz, Carlos J. Gmez-Garca, Antonio Alberola and Enric Canadell
Publication Date (Web): October 29, 2009 (Article)
DOI: 10.1021/ic9018103

Investigation of the Effect of Oxy Bridging Groups in Dinuclear Zn(II) Complexes that Catalyze the Cleavage of a Simple Phosphate Diester RNA Analogue

Mark F. Mohamed, Alexei A. Neverov and R. Stan Brown
Publication Date (Web): October 29, 2009 (Article)
DOI: 10.1021/ic9015965

October 28, 2009

Synthesis, Structure, and Stability of Adducts between Phosphide and Amide Anions and the Lewis Acids Borane, Tris(pentafluorophenyl)borane, and Tris(pentafluorophenyl)alane

Anna-Marie Fuller, Andrew J. Mountford, Matthew L. Scott, Simon J. Coles, Peter N. Horton, David L. Hughes, Michael B. Hursthouse and Simon J. Lancaster
Publication Date (Web): October 28, 2009 (Article)
DOI: 10.1021/ic901799q

Peculiar Binding Modes of a Ligand with Two Adjacent β-Diiminato Binding Sites in Alkali and Alkaline-Earth Metal Chemistry

Dirk F.-J. Piesik, Peter Haack, Sjoerd Harder and Christian Limberg
Publication Date (Web): October 28, 2009 (Article)
DOI: 10.1021/ic9017536

Photogeneration of Nitrosyl Linkage Isomers in Octahedrally Coordinated Platinum Complexes in the Red Spectral Range

Dominik Schaniel, Theo Woike, Norwid-R. Behrnd, Jrg Hauser, Karl W. Krmer, Teodora Todorova and Bernard Delley
Publication Date (Web): October 28, 2009 (Article)
DOI: 10.1021/ic901392q

Measuring Self-Diffusion Coefficients up to 1500 K: A Powerful Tool to Investigate the Dynamics and the Local Structure of Inorganic Melts

Anne-Laure Rollet, Vincent Sarou-Kanian and Catherine Bessada
Publication Date (Web): October 28, 2009 (Article)
DOI: 10.1021/ic9010086

Reduction of Ferricytochrome c Catalyzed by Optically Active Chromium(III) Complexes

Ulrich Scholten, Cline Diserens, Helen Stoeckli-Evans, Klaus Bernauer, Michel Meyer, Ludovic Stuppfler and Dominique Lucas
Publication Date (Web): October 28, 2009 (Article)
DOI: 10.1021/ic900330q

Synthesis, Structure, and Photophysical Characterization of Blue-Green Luminescent Zinc Complexes Containing 2-Iminophenanthropyrrolyl Ligands

Clara S. B. Gomes, Pedro T. Gomes, M. Teresa Duarte, Roberto E. Di Paolo, Antnio L. Maanita and Maria Jos Calhorda
Publication Date (Web): October 28, 2009 (Article)
DOI: 10.1021/ic901519s

Noncentrosymmetry in New Templated Gallium Fluorophosphates

Sarah J. Choyke, Samuel M. Blau, Abigail A. Larner, Amy Narducci Sarjeant, Jeongho Yeon, P. Shiv Halasyamani and Alexander J. Norquist
Publication Date (Web): October 28, 2009 (Article)
DOI: 10.1021/ic901770e

Reactivities of Fe(IV) Complexes with Oxo, Hydroxo, and Alkylperoxo Ligands: An Experimental and Computational Study

Adam T. Fiedler and Lawrence Que, Jr.
Publication Date (Web): October 28, 2009 (Article)
DOI: 10.1021/ic901391y

October 27, 2009

Synthesis and Mssbauer Characterization of Octahedral Iron(II) Carbonyl Complexes FeI2(CO)3L and FeI2(CO)2L2: Developing Models of the [Fe]-H2ase Active Site

Bin Li, Tianbiao Liu, Codrina V. Popescu, Andrey Bilko and Marcetta Y. Darensbourg
Publication Date (Web): October 27, 2009 (Article)
DOI: 10.1021/ic9017882

Syntheses, Characterization, and Computational Study of WSF4 and WSF4·CH3CN

Jared Nieboer, William Hillary, Xin Yu, Hlne P. A. Mercier and Michael Gerken
Publication Date (Web): October 27, 2009 (Article)
DOI: 10.1021/ic901752w

Oxalate Bridged MM (MM = Mo2, MoW, and W2) Quadruply Bonded Complexes As Test Beds for Current Mixed Valence Theory: Looking beyond the Intervalence Charge Transfer Transition

Benjamin J. Lear and Malcolm H. Chisholm
Publication Date (Web): October 27, 2009 (Article)
DOI: 10.1021/ic900995u

Circularly Polarized Luminescence of Eu(III) Complexes with Point- and Axis-Chiral Ligands Dependent on Coordination Structures

Takashi Harada, Yoko Nakano, Michiya Fujiki, Masanobu Naito, Tsuyoshi Kawai and Yasuchika Hasegawa
Publication Date (Web): October 27, 2009 (Article)
DOI: 10.1021/ic901663w

Unprecedent Isolation of a Mixture of Conformational and Linkage Isomers in a Thiosemicarbazone Cobalt Mesocate

Rosa Pedrido, Mara J. Romero, Ana M. Gonzlez-Noya, Manuel R. Bermejo, Miguel Martnez-Calvo and Guillermo Zaragoza
Publication Date (Web): October 27, 2009 (Communication)
DOI: 10.1021/ic901657z

Nitrate and Perchlorate Complexes of Uranium(IV)

Margaret-Jane Crawford, Arkady Ellern, Konstantin Karaghiosoff and Peter Mayer
Publication Date (Web): October 27, 2009 (Communication)
DOI: 10.1021/ic901386y

Synthetic and Structural Studies on l-Cysteinyl Group-Containing Diiron/Triiron Azadithiolates as Active Site Models of [FeFe]-Hydrogenases

Li-Cheng Song, Jing Yan, Yu-Long Li, De-Fu Wang and Qing-Mei Hu
Publication Date (Web): October 27, 2009 (Article)
DOI: 10.1021/ic9006179

Base-Catalyzed Insertion of Dioxygen into Rhodium−Hydrogen Bonds: Kinetics and Mechanism

Ewa Szajna-Fuller and Andreja Bakac
Publication Date (Web): October 27, 2009 (Article)
DOI: 10.1021/ic901808t

October 26, 2009

Fe5O5[B6O10(OH)3]·nH2O: Wave-Layered Iron Borate and Frustrated Antiferromagnetism

Tao Yang, Junliang Sun, Guobao Li, Yingxia Wang, Jeppe Christensen, Zhanbing He, Kirsten E. Christensen, Xiaodong Zou, Fuhui Liao and Jianhua Lin
Publication Date (Web): October 26, 2009 (Article)
DOI: 10.1021/ic9016867

New Reversible Crystal-to-Crystal Conversion of a Mixed-Ligand Lead(II) Coordination Polymer by De- and Rehydration

Homa Sadeghzadeh and Ali Morsali
Publication Date (Web): October 26, 2009 (Communication)
DOI: 10.1021/ic901532x

Crown and Bowl-Shaped Clusters of Uranyl Polyhedra

Ginger E. Sigmon, Brittany Weaver, Karrie-Ann Kubatko and Peter C. Burns
Publication Date (Web): October 26, 2009 (Communication)
DOI: 10.1021/ic9020355

Controlling Electron Transfer through the Manipulation of Structure and Ligand-Based Torsional Motions: A Computational Exploration of Ruthenium Donor−Acceptor Systems using Density Functional Theory

Heather A. Meylemans and Niels H. Damrauer
Publication Date (Web): October 26, 2009 (Article)
DOI: 10.1021/ic901637b

Hydrogen-Bond Directed Cyanide-Bridged Molecular Magnets Derived from Polycyanidemetalates and Schiff Base Manganese(III) Compounds: Synthesis, Structures, and Magnetic Properties

Daopeng Zhang, Hailong Wang, Yuting Chen, Zhong-Hai Ni, Laijin Tian and Jianzhuang Jiang
Publication Date (Web): October 26, 2009 (Article)
DOI: 10.1021/ic901530p

Reactions of Pd(II) with Chelate-Tethered 2,6-Diaminopurine Derivatives: N3-Coordination and Reaction of the Purine System

Miguel A. Galindo, David Amantia, Alberto Martinez-Martinez, William Clegg, Ross W. Harrington, Virtudes Moreno Martinez and Andrew Houlton
Publication Date (Web): October 26, 2009 (Article)
DOI: 10.1021/ic901475y

Kinetic Control of Intralayer Cobalt Coordination in Layered Hydroxides: Co1−0.5xoctCoxtet(OH)2(Cl)x(H2O)n

James R. Neilson, Birgit Schwenzer, Ram Seshadri and Daniel E. Morse
Publication Date (Web): October 26, 2009 (Article)
DOI: 10.1021/ic901167u

October 23, 2009

Syntheses, Structures, and Magnetic Properties of Tetramanganese(III) and Hexamanganese(III) Complexes Containing Derivative of Biguanidate Ligand: Ferromagnetic Interaction via Imino Nitrogen

Asako Igashira-Kamiyama, Takashi Kajiwara, Motohiro Nakano, Takumi Konno and Tasuku Ito
Publication Date (Web): October 23, 2009 (Article)
DOI: 10.1021/ic901219f

Thermochromic Absorption and Photoluminescence in [Pt(ppy)(μ-Ph2pz)]2

Aaron A. Rachford and Felix N. Castellano
Publication Date (Web): October 23, 2009 (Communication)
DOI: 10.1021/ic901156z

October 21, 2009

An Efficient Method for the Preparation of Oxo Molybdenum Salalen Complexes and Their Unusual Use as Hydrosilylation Catalysts

Jeanette E. Ziegler, Guodong Du, Philip E. Fanwick and Mahdi M. Abu-Omar
Publication Date (Web): October 21, 2009 (Article)
DOI: 10.1021/ic901794h

October 19, 2009

Luminescence Properties of Lanthanide and Transition Metal Ion-Doped Ba2LaNbO6: Detection of MnO68− and CrO69− Clusters

Peter A. Tanner and Zaifa Pan
Publication Date (Web): October 19, 2009 (Article)
DOI: 10.1021/ic9015178

October 15, 2009

Characterization and Electronic Structures of Five Members of the Electron Transfer Series [Re(benzene-1,2-dithiolato)3]z (z = 1+, 0, 1−, 2−, 3−): A Spectroscopic and Density Functional Theoretical Study

Stephen Sproules, Flvio Luiz Benedito, Eckhard Bill, Thomas Weyhermller, Serena DeBeer George and Karl Wieghardt
Publication Date (Web): October 15, 2009 (Article)
DOI: 10.1021/ic9010532

Square Planar Bis{3,6-bis(trimethylsilyl)benzene-1,2-dithiolato}metal Complexes of CrII, CoIII, and RhII: An Experimental and Density Functional Theoretical Study

Flvio Luiz Benedito, Taras Petrenko, Eckhard Bill, Thomas Weyhermller and Karl Wieghardt
Publication Date (Web): October 15, 2009 (Article)
DOI: 10.1021/ic9008976

October 14, 2009

Thioester Hydrolysis Reactivity of an Fe(III)Zn(II) Complex

James J. Danford, Piotr Dobrowolski and Lisa M. Berreau
Publication Date (Web): October 14, 2009 (Article)
DOI: 10.1021/ic901890d

Synthesis and Size Control of Cobalt Phosphate Rosettes Using Surfactant-Templated Synthesis

John B. Nelson, Aaron M. Davis and Dawn M. Wellman
Publication Date (Web): October 14, 2009 (Communication)
DOI: 10.1021/ic9016245

October 12, 2009

Vibrioferrin, an Unusual Marine Siderophore: Iron Binding, Photochemistry, and Biological Implications

Shady A. Amin, David H. Green, Frithjof C. Kpper and Carl J. Carrano
Publication Date (Web): October 12, 2009 (Article)
DOI: 10.1021/ic9016883

September 21, 2009

Aryl-Containing Chelates and Amine Debenzylation to Afford 1,3-Di-2-pyridyl-2-azaallyl (smif): Structures of {κ-C,N,Npy2-(2-pyridylmethyl)2N(CH2(4-tBu-phenyl-2-yl))}FeBr and (smif)CrN(TMS)2

Brenda A. Frazier, Peter T. Wolczanski and Emil B. Lobkovsky
Publication Date (Web): September 21, 2009 (Article)
DOI: 10.1021/ic901329z

August 25, 2009

Quaternary Neptunium Compounds: Syntheses and Characterization of KCuNpS3, RbCuNpS3, CsCuNpS3, KAgNpS3, and CsAgNpS3

Daniel M. Wells, Geng Bang Jin, S. Skanthakumar, Richard G. Haire, L. Soderholm and James A. Ibers
Publication Date (Web): August 25, 2009 (Article)
DOI: 10.1021/ic901229d

August 21, 2009

Computational Study of Methane C−H Activation by First-Row Late Transition Metal LnM═E (M: Fe, Co, Ni) Complexes

Aaron W. Pierpont and Thomas R. Cundari
Publication Date (Web): August 21, 2009 (Article)
DOI: 10.1021/ic901250z

December 5, 2008

Conformation Changes and Luminescent Properties of Au−Ln (Ln = Nd, Eu, Er, Yb) Arrays with 5-Ethynyl-2,2′-Bipyridine

Hai-Bing Xu, Li-Yi Zhang, Jun Ni, Hsiu-Yi Chao and Zhong-Ning Chen
Publication Date (Web): December 5, 2008 (Addition/Correction)
DOI: 10.1021/ic802264d

May 6, 2009

Preface:  Palladium Chemistry Relevant to Organic Synthesis

James M. Mayer and Forrest E. Michael
p 2
Publication Date (Web): May 6, 2009 (Forum Article)
DOI: 10.1021/ic700598t

June 3, 2009

A Cyano-Bridged CrIIICoII Ferromagnet with a Chiral Nanotubular Structure Constituted of Interlocked Single and Double Helices

Yuan-Zhu Zhang and Osamu Sato
Publication Date (Web): June 3, 2009 (Communication)
DOI: 10.1021/ic900224b