Table of Contents

Journal Cover
June 19, 2002
Volume 124, Issue 24
Pages 6794-7251
For Selected Content:

COMMUNICATIONS

Hydrogen-Bonding Dynamics in Photoinduced Electron Transfer in a Ferrocene−Quinone Linked Dyad with a Rigid Amide Spacer

pp 6794–6795
Publication Date (Web): May 23, 2002 (Communication)
DOI: 10.1021/ja0157604

Oxo, Sulfido, and Tellurido Mo-enedithiolate Models for Xanthine Oxidase:  Understanding the Basis of Enzyme Reactivity

pp 6796–6797
Publication Date (Web): May 23, 2002 (Communication)
DOI: 10.1021/ja011957k

The First Direct and Enantioselective Cross-Aldol Reaction of Aldehydes

pp 6798–6799
Publication Date (Web): May 08, 2002 (Communication)
DOI: 10.1021/ja0262378

Formation of Alkylsilane-Based Monolayers on Gold

pp 6800–6801
Publication Date (Web): May 21, 2002 (Communication)
DOI: 10.1021/ja025755f

N2-Phenyldeoxyguanosine:  Modulation of the Chemical Properties of Deoxyguanosine toward One-Electron Oxidation in DNA

pp 6802–6803
Publication Date (Web): May 21, 2002 (Communication)
DOI: 10.1021/ja025781d

Five-Coordinate Platinum(IV) Complex as a Precursor to a Novel Pt(II) Olefin Hydride Complex for Alkane Activation

pp 6804–6805
Publication Date (Web): May 22, 2002 (Communication)
DOI: 10.1021/ja0258677

Stable (Amino)(phosphino)carbenes:  Difunctional Molecules

pp 6806–6807
Publication Date (Web): May 22, 2002 (Communication)
DOI: 10.1021/ja026556z

Approaching Exponential Growth with a Self-Replicating Peptide

pp 6808–6809
Publication Date (Web): May 22, 2002 (Communication)
DOI: 10.1021/ja026024i

Chemically Induced Hairpin Formation in DNA Monolayers

pp 6810–6811
Publication Date (Web): May 21, 2002 (Communication)
DOI: 10.1021/ja026356n

The Smallest Resonance Energy Transfer Acceptor for Tryptophan

pp 6812–6813
Publication Date (Web): May 23, 2002 (Communication)
DOI: 10.1021/ja017812v

Activation of Arene C−H Bonds by a Cationic Hafnium Silyl Complex Possessing an α-Agostic Si−H Interaction

pp 6814–6815
Publication Date (Web): May 21, 2002 (Communication)
DOI: 10.1021/ja025940t

An Indication of Magnetic-Field-Induced Superconductivity in a Bifunctional Layered Organic Conductor, κ-(BETS)2FeBr4

pp 6816–6817
Publication Date (Web): May 21, 2002 (Communication)
DOI: 10.1021/ja026067z

Ultrafast Decay of Electronically Excited Singlet Cytosine via a π,π* to nO,π* State Switch

pp 6818–6819
Publication Date (Web): May 25, 2002 (Communication)
DOI: 10.1021/ja0258273

Tolerance of Acyclic Residues in the β-Peptide 12-Helix:  Access to Diverse Side-Chain Arrays for Biological Applications

pp 6820–6821
Publication Date (Web): May 23, 2002 (Communication)
DOI: 10.1021/ja017869h

FTIR Investigation of the Intermediates Formed in the Reaction of Nitroprusside and Thiolates

pp 6822–6823
Publication Date (Web): May 24, 2002 (Communication)
DOI: 10.1021/ja017061x

Rapid Ruthenium-Catalyzed Synthesis of Pyranopyrandiones by Reconstructive Carbonylation of Cyclopropenones Involving C−C Bond Cleavage

pp 6824–6825
Publication Date (Web): May 22, 2002 (Communication)
DOI: 10.1021/ja0260521

Proton Coupling to [4Fe-4S]2+/+ and [4Fe-4Se]2+/+ Oxidation and Reduction in a Designed Protein

pp 6826–6827
Publication Date (Web): May 24, 2002 (Communication)
DOI: 10.1021/ja0171613

Nonnatural Amino Acid Ligands in Heme Protein Design

pp 6828–6829
Publication Date (Web): May 24, 2002 (Communication)
DOI: 10.1021/ja025534+

Chiroptical Properties of Poly(p-phenyleneethynylene) Copolymers in Thin Films:  Large g-Values

pp 6830–6831
Publication Date (Web): May 22, 2002 (Communication)
DOI: 10.1021/ja026532s

Observation of the Glycines in Elastin Using 13C and 15N Solid-State NMR Spectroscopy and Isotopic Labeling

pp 6832–6833
Publication Date (Web): May 22, 2002 (Communication)
DOI: 10.1021/ja017711x

Aminoacyl-tRNA Synthesis by a Resin-Immobilized Ribozyme

pp 6834–6835
Publication Date (Web): May 22, 2002 (Communication)
DOI: 10.1021/ja025872a

Helicoid Shiftamers

pp 6836–6837
Publication Date (Web): May 22, 2002 (Communication)
DOI: 10.1021/ja020425g

Sequential Actions of Cobalt Nanoparticles and Palladium(II) Catalysts:  Three-Step One-Pot Synthesis of Fenestranes from an Enyne and an Alkyne Diester

pp 6838–6839
Publication Date (Web): May 22, 2002 (Communication)
DOI: 10.1021/ja0260420

The First General Method for Z-Selective Olefination of Acylsilanes via Ynolate Anions Providing Multisubstituted Alkenes

pp 6840–6841
Publication Date (Web): May 22, 2002 (Communication)
DOI: 10.1021/ja026275r

Mechanism of the Interconversions between C- and N-Bound Transition Metal α-Cyanocarbanions

pp 6842–6843
Publication Date (Web): May 25, 2002 (Communication)
DOI: 10.1021/ja017868p

Ruthenium(II)-Catalyzed [2 + 2 + 2] Cycloaddition of 1,6-Diynes with Tricarbonyl Compounds

pp 6844–6845
Publication Date (Web): May 25, 2002 (Communication)
DOI: 10.1021/ja0264100

Template-Directed Assembly of a de Novo Designed Protein

pp 6846–6848
Publication Date (Web): May 23, 2002 (Communication)
DOI: 10.1021/ja0261271

ARTICLES

Dynamic Docking and Electron Transfer between Zn-myoglobin and Cytochrome b5

pp 6849–6859
Publication Date (Web): May 23, 2002 (Article)
DOI: 10.1021/ja0127032

Molecular Structure of Single DNA Complexes with Positively Charged Dendronized Polymers

pp 6860–6865
Publication Date (Web): May 24, 2002 (Article)
DOI: 10.1021/ja017828l

Phospholipid/Protein Cones

pp 6866–6871
Publication Date (Web): May 25, 2002 (Article)
DOI: 10.1021/ja020067h

Recognition of Ten Base Pairs of DNA by Head-to-Head Hairpin Dimers

pp 6872–6878
Publication Date (Web): May 22, 2002 (Article)
DOI: 10.1021/ja020258k

Evaluation of Norcarane as a Probe for Radicals in Cytochome P450- and Soluble Methane Monooxygenase-Catalyzed Hydroxylation Reactions

pp 6879–6886
Publication Date (Web): May 23, 2002 (Article)
DOI: 10.1021/ja017858o

Metal Ion-Induced Site-Selective RNA Hydrolysis by Use of Acridine-Bearing Oligonucleotide as Cofactor

pp 6887–6894
Publication Date (Web): May 24, 2002 (Article)
DOI: 10.1021/ja025653p

Reduction of Ketones and Alkyl Iodides by SmI2 and Sm(II)-HMPA Complexes. Rate and Mechanistic Studies

pp 6895–6899
Publication Date (Web): May 21, 2002 (Article)
DOI: 10.1021/ja026074n

Total Synthesis of (−)-Rhazinilam:  Asymmetric C−H Bond Activation via the Use of a Chiral Auxiliary

pp 6900–6903
Publication Date (Web): May 23, 2002 (Article)
DOI: 10.1021/ja026130k

Chemistry of a Novel Family of Tridentate Alkoxy Tin(II) Clusters

pp 6904–6913
Publication Date (Web): May 23, 2002 (Article)
DOI: 10.1021/ja0202309

Synthesis and Properties of the First Stable Germabenzene

pp 6914–6920
Publication Date (Web): May 23, 2002 (Article)
DOI: 10.1021/ja0262941

Optimization of Catalyst Enantioselectivity and Activity Using Achiral and Meso Ligands

pp 6929–6941
Publication Date (Web): May 23, 2002 (Article)
DOI: 10.1021/ja0166601

Unique Dual Fluorescence of Sterically Congested Hexaalkyl Benzenehexacarboxylates:  Mechanism and Application to Viscosity Probing

pp 6942–6949
Publication Date (Web): May 23, 2002 (Article)
DOI: 10.1021/ja016858l

Intramolecular Dimers:  A New Strategy to Fluorescence Quenching in Dual-Labeled Oligonucleotide Probes

pp 6950–6956
Publication Date (Web): May 21, 2002 (Article)
DOI: 10.1021/ja025678o

The Contrasting Kinetics of Peroxidation of Vitamin E-Containing Phospholipid Unilamellar Vesicles and Human Low-Density Lipoprotein1

pp 6957–6965
Publication Date (Web): May 24, 2002 (Article)
DOI: 10.1021/ja0127178

Unusual Pathways for Metal-Assisted C−C and C−P Coupling Reactions Using Allenylidenerhodium Complexes as Precursors

pp 6966–6980
Publication Date (Web): May 25, 2002 (Article)
DOI: 10.1021/ja012479g

Total Synthesis of (−)-Bafilomycin A1

pp 6981–6990
Publication Date (Web): May 23, 2002 (Article)
DOI: 10.1021/ja017885e

Efficient Catalytic Enantioselective Synthesis of Unsaturated Amines:  Preparation of Small- and Medium-Ring Cyclic Amines through Mo-Catalyzed Asymmetric Ring-Closing Metathesis in the Absence of Solvent

pp 6991–6997
Publication Date (Web): May 22, 2002 (Article)
DOI: 10.1021/ja012534l

Mechanism of Abietadiene Synthase Catalysis:  Stereochemistry and Stabilization of the Cryptic Pimarenyl Carbocation Intermediates

pp 6998–7006
Publication Date (Web): May 25, 2002 (Article)
DOI: 10.1021/ja017734b

A Mechanistic Study of the Samarium(II)-Mediated Reduction of Aryl Nitro Compounds to the Corresponding Arylamines. The Crystal Structures of {Sm[N(SiMe3)2]2(thf)}22-O) and [(Me3Si)2N]2Sm(thf)(μ-PhNNPh)Sm[N(SiMe3)2]2

pp 7007–7015
Publication Date (Web): May 21, 2002 (Article)
DOI: 10.1021/ja0168918

Measuring Polymer Surface Ordering Differences in Air and Water by Sum Frequency Generation Vibrational Spectroscopy

pp 7016–7023
Publication Date (Web): May 23, 2002 (Article)
DOI: 10.1021/ja012387r

Organocations in Zeolite Synthesis:  Fused Bicyclo [l.m.0] Cations and the Discovery of Zeolite SSZ-48

pp 7024–7034
Publication Date (Web): May 23, 2002 (Article)
DOI: 10.1021/ja011513o

Conversion of Tricoordinate to Hexacoordinate Phosphorus. Formation of a Phosphorane−Phosphatrane System1

pp 7035–7040
Publication Date (Web): May 21, 2002 (Article)
DOI: 10.1021/ja012579m

TpPtMe(H)2:  Why Is There H/D Scrambling of the Methyl Group but Not Methane Loss?

pp 7041–7054
Publication Date (Web): May 23, 2002 (Article)
DOI: 10.1021/ja025667v

Biosynthesis of Nodulisporic Acid A:  Precursor Studies

pp 7055–7060
Publication Date (Web): May 22, 2002 (Article)
DOI: 10.1021/ja017183p

Total Syntheses of the Phytotoxic Lactones Herbarumin I and II and a Synthesis-Based Solution of the Pinolidoxin Puzzle

pp 7061–7069
Publication Date (Web): May 22, 2002 (Article)
DOI: 10.1021/ja020238i

Sorting Fluorescent Nanocrystals with DNA

pp 7070–7074
Publication Date (Web): May 25, 2002 (Article)
DOI: 10.1021/ja017822w

Solution and Solid-State Structural Studies of Epoxide Adducts of Cadmium Phenoxides. Chemistry Relevant to Epoxide Activation for Ring-Opening Reactions

pp 7075–7083
Publication Date (Web): May 25, 2002 (Article)
DOI: 10.1021/ja020184c

Hydrogen Activation on Mo-Based Sulfide Catalysts, a Periodic DFT Study

pp 7084–7095
Publication Date (Web): May 24, 2002 (Article)
DOI: 10.1021/ja011634o

Dynamics and Extent of Ligand Exchange Depend on Electronic Charge of Metal Nanoparticles

pp 7096–7102
Publication Date (Web): May 22, 2002 (Article)
DOI: 10.1021/ja0174985

Extending the Coordination Chemistry of Molecular P4S3:  The Polymeric Ag(P4S3)+ and Ag(P4S3)2+ Cations

pp 7111–7116
Publication Date (Web): May 22, 2002 (Article)
DOI: 10.1021/ja012760v

Impact of Defects on the Surface Chemistry of ZnO(000)−O

pp 7117–7122
Publication Date (Web): May 15, 2002 (Article)
DOI: 10.1021/ja025904u

Long-Lived Charge-Separation by Retarding Reverse Flow of Charge-Balancing Cation and Zeolite-Encapsulated Ru(bpy)32+ as Photosensitized Electron Pump from Zeolite Framework to Externally Placed Viologen

pp 7123–7135
Publication Date (Web): May 23, 2002 (Article)
DOI: 10.1021/ja020446a

Epitaxial Growth and Photochemical Annealing of Graded CdS/ZnS Shells on Colloidal CdSe Nanorods

pp 7136–7145
Publication Date (Web): May 24, 2002 (Article)
DOI: 10.1021/ja025946i

Heme Charge-Transfer Band III Is Vibronically Coupled to the Soret Band

pp 7146–7155
Publication Date (Web): May 23, 2002 (Article)
DOI: 10.1021/ja0172722

Residue-Specific Real-Time NMR Diffusion Experiments Define the Association States of Proteins during Folding

pp 7156–7162
Publication Date (Web): May 22, 2002 (Article)
DOI: 10.1021/ja012699u

Magnitudes and Chemical Consequences of R3N+−C−H···OC Hydrogen Bonding

pp 7163–7169
Publication Date (Web): May 22, 2002 (Article)
DOI: 10.1021/ja012417q

Selective Formation of Cumulative Double Bonds (CCN) in the Attachment of Multifunctional Molecules on Si(111)-7 × 7

pp 7170–7180
Publication Date (Web): May 23, 2002 (Article)
DOI: 10.1021/ja012563w

Mechanism of C−H Bond Activation/C−C Bond Formation Reaction between Diazo Compound and Alkane Catalyzed by Dirhodium Tetracarboxylate

pp 7181–7192
Publication Date (Web): May 23, 2002 (Article)
DOI: 10.1021/ja017823o

A First-Principles Study of Methanol Decomposition on Pt(111)

pp 7193–7201
Publication Date (Web): May 24, 2002 (Article)
DOI: 10.1021/ja017818k

Molecular-Scale Tribology of Amorphous Carbon Coatings:  Effects of Film Thickness, Adhesion, and Long-Range Interactions

pp 7202–7209
Publication Date (Web): May 22, 2002 (Article)
DOI: 10.1021/ja0178618

IR and Theoretical Studies of Monocarbonyl Ni Complexes Formed by Adsorption of CO at Low Pressure on Silica-Supported NiII Ions

pp 7210–7217
Publication Date (Web): May 23, 2002 (Article)
DOI: 10.1021/ja020037e

Theoretical Study of Benzonitrile Clusters in the Gas Phase and Their Adsorption onto a Au(111) Surface

pp 7218–7225
Publication Date (Web): May 21, 2002 (Article)
DOI: 10.1021/ja011744v

The Reaction of Triplet Flavin with Indole. A Study of the Cascade of Reactive Intermediates Using Density Functional Theory and Time Resolved Infrared Spectroscopy

pp 7226–7234
Publication Date (Web): May 22, 2002 (Article)
DOI: 10.1021/ja0123711

Determination of 1H Homonuclear Scalar Couplings in Unlabeled Carbohydrates

pp 7235–7239
Publication Date (Web): May 22, 2002 (Article)
DOI: 10.1021/ja017358v

ADDITIONS AND CORRECTIONS

Total Synthesis of Bafilomycin A1 Relying on Iterative 1,2-Induction in Acyclic Precursors [J. Am. Chem. Soc. 2001, 123, 10200−10206].

p 7249
Publication Date (Web): May 18, 2002 (Addition/Correction)
DOI: 10.1021/ja025105b

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