Table of Contents

Journal Cover
November 20, 2002
Volume 124, Issue 46
Pages 13642-13960
For Selected Content:

COMMUNICATIONS

Benzyl Alcohol and Transition Metal Chlorides as a Versatile Reaction System for the Nonaqueous and Low-Temperature Synthesis of Crystalline Nano-Objects with Controlled Dimensionality

Markus Niederberger, Michael H. Bartl, and Galen D. Stucky
pp 13642–13643
Publication Date (Web): October 30, 2002 (Communication)
DOI: 10.1021/ja027115i

Enantioselective Synthesis of 1,5-anti- and 1,5-syn-Diols Using a Highly Diastereoselective One-Pot Double Allylboration Reaction Sequence

Eric M. Flamme and William R. Roush
pp 13644–13645
Publication Date (Web): October 26, 2002 (Communication)
DOI: 10.1021/ja028055j

Development of a New Lewis Acid-Catalyzed [3,3]-Sigmatropic Rearrangement:  The Allenoate-Claisen Rearrangement

Tristan H. Lambert and David W. C. MacMillan
pp 13646–13647
Publication Date (Web): October 29, 2002 (Communication)
DOI: 10.1021/ja028090q

The Practical Synthesis of a Novel and Highly Potent Analogue of Bryostatin

Paul A. Wender, Jeremy L. Baryza, Chad E. Bennett, F. Christopher Bi, Stacey E. Brenner, Michael O. Clarke, Joshua C. Horan, Cindy Kan, Emmanuel Lacôte, Blaise Lippa, Peter G. Nell, and Tim M. Turner
pp 13648–13649
Publication Date (Web): October 24, 2002 (Communication)
DOI: 10.1021/ja027509+

Rapid-Injection NMR Study of Iodo- and Cyano-Gilman Reagents with 2-Cyclohexenone:  Observation of π-Complexes and Their Rates of Formation1

Steven H. Bertz, Clifford M. Carlin, Daniel A. Deadwyler, Michael D. Murphy, Craig A. Ogle, and Paul H. Seagle
pp 13650–13651
Publication Date (Web): October 29, 2002 (Communication)
DOI: 10.1021/ja027744s

Rationalization of Anomalous Nonlinear Effects in the Alkylation of Substituted Benzaldehydes

Frederic Buono, Patrick J. Walsh, and Donna G. Blackmond
pp 13652–13653
Publication Date (Web): October 24, 2002 (Communication)
DOI: 10.1021/ja027406r

A de Novo Enantioselective Total Synthesis of (−)-Laulimalide

Scott G. Nelson, Wing S. Cheung, Andrew J. Kassick, and Mark A. Hilfiker
pp 13654–13655
Publication Date (Web): October 26, 2002 (Communication)
DOI: 10.1021/ja028019k

Sterically Induced Shape and Crystalline Phase Control of GaP Nanocrystals

Yong-Ho Kim, Young-wook Jun, Byung-Ho Jun, Sang-Min Lee, and Jinwoo Cheon
pp 13656–13657
Publication Date (Web): October 30, 2002 (Communication)
DOI: 10.1021/ja027575b

The Reactivity of Mo(PMe3)6 towards Heterocyclic Nitrogen Compounds:  Transformations Relevant to Hydrodenitrogenation

Guang Zhu, Joseph M. Tanski, David G. Churchill, Kevin E. Janak, and Gerard Parkin
pp 13658–13659
Publication Date (Web): October 29, 2002 (Communication)
DOI: 10.1021/ja028512w

Au Nanowire Fabrication from Sequenced Histidine-Rich Peptide

Ramin Djalali, Yung-fou Chen, and Hiroshi Matsui
pp 13660–13661
Publication Date (Web): October 23, 2002 (Communication)
DOI: 10.1021/ja028261r

Boronic Acids:  New Coupling Partners in Room-Temperature Suzuki Reactions of Alkyl Bromides. Crystallographic Characterization of an Oxidative-Addition Adduct Generated under Remarkably Mild Conditions

Jan H. Kirchhoff, Matthew R. Netherton, Ivory D. Hills, and Gregory C. Fu
pp 13662–13663
Publication Date (Web): October 23, 2002 (Communication)
DOI: 10.1021/ja0283899

Symmetry-Enforced Conformational Control of Photochemical Reactivity in 2-Vinyl-1,3-terphenyl

Frederick D. Lewis, Xiaobing Zuo, Vladimir Gevorgyan, and Michael Rubin
pp 13664–13665
Publication Date (Web): October 24, 2002 (Communication)
DOI: 10.1021/ja028251q

Tailored Synthesis of Structurally Defined Polymers by Organotellurium-Mediated Living Radical Polymerization (TERP):  Synthesis of Poly(meth)acrylate Derivatives and Their Di- and Triblock Copolymers

Shigeru Yamago, Kazunori Iida, and Jun-ichi Yoshida
pp 13666–13667
Publication Date (Web): October 23, 2002 (Communication)
DOI: 10.1021/ja027599i

First Homoleptic Complexes of Isocyanoferrocene

Mikhail V. Barybin, Thomas C. Holovics, Stephan F. Deplazes, Gerald H. Lushington, Douglas R. Powell, and Masaharu Toriyama
pp 13668–13669
Publication Date (Web): October 26, 2002 (Communication)
DOI: 10.1021/ja028271s

Synthesis of Leucascandrolide A via a Spontaneous Macrolactolization

Ying Wang, Jelena Janjic, and Sergey A. Kozmin
pp 13670–13671
Publication Date (Web): October 24, 2002 (Communication)
DOI: 10.1021/ja028428g

A Unique and Highly Efficient Method for Catalytic Olefin Aziridination

Kiran Guthikonda and J. Du Bois
pp 13672–13673
Publication Date (Web): October 23, 2002 (Communication)
DOI: 10.1021/ja028253a

Nonequilibrium Capillary Electrophoresis of Equilibrium Mixtures − A Single Experiment Reveals Equilibrium and Kinetic Parameters of Protein−DNA Interactions

Maxim Berezovski and Sergey N. Krylov
pp 13674–13675
Publication Date (Web): October 26, 2002 (Communication)
DOI: 10.1021/ja028212e

Direct Determination of Absolute Configuration of Monoalcohols by Bis(magnesium Porphyrin)

Juha M. Lintuluoto, Victor V. Borovkov, and Yoshihisa Inoue
pp 13676–13677
Publication Date (Web): October 23, 2002 (Communication)
DOI: 10.1021/ja0267270

Asymmetric Intramolecular [3 + 2] Cycloaddition Reactions of Acylhydrazones/Olefins Using a Chiral Zirconium Catalyst

Shū Kobayashi, Haruka Shimizu, Yasuhiro Yamashita, Haruro Ishitani, and Jun Kobayashi
pp 13678–13679
Publication Date (Web): October 26, 2002 (Communication)
DOI: 10.1021/ja027681d

Strong Binding in the DNA Minor Groove by an Aromatic Diamidine with a Shape That Does Not Match the Curvature of the Groove

Binh Nguyen, Michael P. H. Lee, Donald Hamelberg, Alexandra Joubert, Christian Bailly, Reto Brun, Stephen Neidle, and W. David Wilson
pp 13680–13681
Publication Date (Web): October 29, 2002 (Communication)
DOI: 10.1021/ja027953c

LNAzymes:  Incorporation of LNA-Type Monomers into DNAzymes Markedly Increases RNA Cleavage

Birte Vester, Lars Bo Lundberg, Mads D. Sørensen, B. Ravindra Babu, Stephen Douthwaite, and Jesper Wengel
pp 13682–13683
Publication Date (Web): October 24, 2002 (Communication)
DOI: 10.1021/ja0276220

A Novel Silver(I)-Mediated DNA Base Pair

Nicole Zimmermann, Eric Meggers, and Peter G. Schultz
pp 13684–13685
Publication Date (Web): October 25, 2002 (Communication)
DOI: 10.1021/ja0279951

The Bicyclic N,N‘-Diacylaminal:  A New Motif for Molecular Self-Assembly

Robert B. Grossman, Kazuyuki Hattori, Sean Parkin, Brian O. Patrick, and Melissa A. Varner
pp 13686–13687
Publication Date (Web): October 26, 2002 (Communication)
DOI: 10.1021/ja026949y

Synthesis of Nearly Uniform Single-Walled Carbon Nanotubes Using Identical Metal-Containing Molecular Nanoclusters as Catalysts

Lei An, Jessica M. Owens, Laurie E. McNeil, and Jie Liu
pp 13688–13689
Publication Date (Web): October 26, 2002 (Communication)
DOI: 10.1021/ja0274958

Direct Conversion of Carbonyl Compounds into Organic Halides:  Indium(III) Hydroxide-Catalyzed Deoxygenative Halogenation Using Chlorodimethylsilane

Yoshiyuki Onishi, Daigo Ogawa, Makoto Yasuda, and Akio Baba
pp 13690–13691
Publication Date (Web): October 26, 2002 (Communication)
DOI: 10.1021/ja0283246

Enantioselective Hydrogenation of 3-Alkylidenelactams:  High-Throughput Screening Provides a Surprising Solution

Tai-Yuen Yue and William A. Nugent
pp 13692–13693
Publication Date (Web): October 29, 2002 (Communication)
DOI: 10.1021/ja028043y

Interconnecting Carbon Nanotubes with an Inorganic Metal Complex

Fiona Frehill, Johannes G. Vos, Sakina Benrezzak, Antal A. Koós, Zoltan Kónya, Manuel G. Rüther, Werner J. Blau, Antonio Fonseca, Janos B. Nagy, Laszlo P. Biró, Andrew I. Minett, and Marc in het Panhuis
pp 13694–13695
Publication Date (Web): October 26, 2002 (Communication)
DOI: 10.1021/ja028119q

NO-Induced Activation Mechanism of the Heme-Regulated eIF2α Kinase

Haruto Ishikawa, Bo-Geon Yun, Satoshi Takahashi, Hiroshi Hori, Robert L. Matts, Koichiro Ishimori, and Isao Morishima
pp 13696–13697
Publication Date (Web): October 25, 2002 (Communication)
DOI: 10.1021/ja0272336

ARTICLES

Metal−Ligand Interplay in Blue Copper Proteins Studied by 1H NMR Spectroscopy:  Cu(II)−Pseudoazurin and Cu(II)−Rusticyanin

Antonio Donaire, Beatriz Jiménez, Claudio O. Fernández, Roberta Pierattelli, Tomotake Niizeki, José-María Moratal, John F. Hall, Takamitsu Kohzuma, S. Samar Hasnain, and Alejandro J. Vila
pp 13698–13708
Publication Date (Web): October 26, 2002 (Article)
DOI: 10.1021/ja0267019

Direct Structure Determination Using Residual Dipolar Couplings: Reaction-Site Conformation of Methionine Sulfoxide Reductase in Solution

Sabine Béraud, Beate Bersch, Bernhard Brutscher, Pierre Gans, Frédéric Barras, and Martin Blackledge
pp 13709–13715
Publication Date (Web): October 25, 2002 (Article)
DOI: 10.1021/ja0268783

Crystal Structure of a B-Form DNA Duplex Containing (l)-α-Threofuranosyl (3‘→2‘) Nucleosides:  A Four-Carbon Sugar Is Easily Accommodated into the Backbone of DNA

Christopher J. Wilds, Zdzislaw Wawrzak, Ramanarayanan Krishnamurthy, Albert Eschenmoser, and Martin Egli
pp 13716–13721
Publication Date (Web): October 26, 2002 (Article)
DOI: 10.1021/ja0207807

Cross-Modulation of Physicochemical Character of Aglycones in Dinucleoside (3‘→5‘) Monophosphates by the Nearest Neighbor Interaction in the Stacked State

S. Acharya, P. Acharya, A. Földesi, and J. Chattopadhyaya
pp 13722–13730
Publication Date (Web): October 29, 2002 (Article)
DOI: 10.1021/ja026831h

Trinuclear Copper(II) Complex Showing High Selectivity for the Hydrolysis of 2‘−5‘ over 3‘−5‘ for UpU and 3‘−5‘ over 2‘−5‘ for ApA Ribonucleotides

Makoto Komiyama, Shinichiro Kina, Kazunari Matsumura, Jun Sumaoka, Suzanne Tobey, Vincent M. Lynch, and Eric Anslyn
pp 13731–13736
Publication Date (Web): October 29, 2002 (Article)
DOI: 10.1021/ja020877t

Self-Organizing Properties of Natural and Related Synthetic Glycolipids

Fabienne Dumoulin, Dominique Lafont, Paul Boullanger, Grahame Mackenzie, Georg H. Mehl, and John W. Goodby
pp 13737–13748
Publication Date (Web): October 23, 2002 (Article)
DOI: 10.1021/ja020396+

A Novel Organic Intercalation System with Layered Polymer Crystals as the Host Compounds Derived from 1,3-Diene Carboxylic Acids

Akikazu Matsumoto, Shinya Oshita, and Daisuke Fujioka
pp 13749–13756
Publication Date (Web): October 24, 2002 (Article)
DOI: 10.1021/ja020869c

Supramolecular Polymer Chemistry:  Self-Assembling Dendrimers Using the DDA·AAD (GC-like) Hydrogen Bonding Motif

Yuguo Ma, Sergei V. Kolotuchin, and Steven C. Zimmerman
pp 13757–13769
Publication Date (Web): October 26, 2002 (Article)
DOI: 10.1021/ja0202006

Cyclooctatetraene Computational Photo- and Thermal Chemistry:  A Reactivity Model for Conjugated Hydrocarbons

Marco Garavelli, Fernando Bernardi, Alessandro Cembran, Obis Castaño, Luis Manuel Frutos, Manuela Merchán, and Massimo Olivucci
pp 13770–13789
Publication Date (Web): October 17, 2002 (Article)
DOI: 10.1021/ja020741v

Amination of Pyridylketenes:  Experimental and Computational Studies of Strong Amide Enol Stabilization by the 2-Pyridyl Group

Austin W. Acton, Annette D. Allen, Luis M. Antunes, Andrei V. Fedorov, Katayoun Najafian, Thomas T. Tidwell, and Brian D. Wagner
pp 13790–13794
Publication Date (Web): October 26, 2002 (Article)
DOI: 10.1021/ja027347h

Structure-Based Design of Selective Agonists for a Rickets-Associated Mutant of the Vitamin D Receptor

Steve L. Swann, Joel Bergh, Mary C. Farach-Carson, Cory A. Ocasio, and John T. Koh
pp 13795–13805
Publication Date (Web): October 25, 2002 (Article)
DOI: 10.1021/ja0268377

Unusual Frequency Dispersion Effects of the Nonlinear Optical Response in Highly Conjugated (Polypyridyl)metal−(Porphinato)zinc(II) Chromophores

H. Tetsuo Uyeda, Yuxia Zhao, Kurt Wostyn, Inge Asselberghs, Koen Clays, André Persoons, and Michael J. Therien
pp 13806–13813
Publication Date (Web): October 25, 2002 (Article)
DOI: 10.1021/ja020651q

Synthesis and Explosive Decomposition of Organometallic Dehydro[18]annulenes:  An Access to Carbon Nanostructures

Matthew Laskoski, Winfried Steffen, Jason G. M. Morton, Mark D. Smith, and Uwe H. F. Bunz
pp 13814–13818
Publication Date (Web): October 24, 2002 (Article)
DOI: 10.1021/ja026809o

Tetrakis(trimethylsilyl)tetrahedrane

Günther Maier, Jörg Neudert, Oliver Wolf, Dirk Pappusch, Akira Sekiguchi, Masanobu Tanaka, and Tsukasa Matsuo
pp 13819–13826
Publication Date (Web): October 25, 2002 (Article)
DOI: 10.1021/ja020863n

Mechanistic Studies on the Addition of Dihydrogen to Tantalocene Complexes

Dawn C. Bregel, Susan M. Oldham, and Richard Eisenberg
pp 13827–13832
Publication Date (Web): October 24, 2002 (Article)
DOI: 10.1021/ja027005b

Nitrosyliron(III) Porphyrinates:  Porphyrin Core Conformation and FeNO Geometry. Any Correlation?

Mary K. Ellison, Charles E. Schulz, and W. Robert Scheidt
pp 13833–13841
Publication Date (Web): October 30, 2002 (Article)
DOI: 10.1021/ja0207145

Spectroscopic and Computational Studies on [(PhTttBu)2Ni2(μ-O)2]:  Nature of the Bis-μ-oxo (Ni3+)2 “Diamond” Core

Ralph Schenker, Beaven S. Mandimutsira, Charles G. Riordan, and Thomas C. Brunold
pp 13842–13855
Publication Date (Web): October 29, 2002 (Article)
DOI: 10.1021/ja027049k

Iron-Catalyzed Cross-Coupling Reactions

Alois Fürstner, Andreas Leitner, María Méndez, and Helga Krause
pp 13856–13863
Publication Date (Web): October 24, 2002 (Article)
DOI: 10.1021/ja027190t

Mesoscopic Monodisperse Ferromagnetic Colloids Enable Magnetically Controlled Photonic Crystals

Xiangling Xu, Sara A. Majetich, and Sanford A. Asher
pp 13864–13868
Publication Date (Web): October 26, 2002 (Article)
DOI: 10.1021/ja026901k

Molecular Structure of the Solvated Proton in Isolated Salts. Short, Strong, Low Barrier (SSLB) H-bonds

Daniel Stasko, Stephan P. Hoffmann, Kee-Chan Kim, Nathanael L. P. Fackler, Anna S. Larsen, Tatiana Drovetskaya, Fook S. Tham, Christopher A. Reed, Clifton E. F. Rickard, Peter D. W. Boyd, and Evgenii S. Stoyanov
pp 13869–13876
Publication Date (Web): October 26, 2002 (Article)
DOI: 10.1021/ja012671i

Novel Mixed-Valent (V/VI) Triple Perovskite Ruthenates:  Observation of a Complex Low-Temperature Structural and Magnetic Transition

Katharine E. Stitzer, Mark D. Smith, William R. Gemmill, and Hans-Conrad zur Loye
pp 13877–13885
Publication Date (Web): October 25, 2002 (Article)
DOI: 10.1021/ja0271781

Synthesis and Properties of 1,3,5-Benzene Periodic Mesoporous Organosilica (PMO):  Novel Aromatic PMO with Three Point Attachments and Unique Thermal Transformations

Masakatsu Kuroki, Tewodros Asefa, Wesley Whitnal, Michal Kruk, Chiaki Yoshina-Ishii, Mietek Jaroniec, and Geoffrey A. Ozin
pp 13886–13895
Publication Date (Web): October 29, 2002 (Article)
DOI: 10.1021/ja027877d

Evidence for Orbital-Specific Electron Transfer to Oriented Haloform Molecules

Beike Jia, Jonathan Laib, R. F. M. Lobo, and Philip R. Brooks
pp 13896–13902
Publication Date (Web): October 29, 2002 (Article)
DOI: 10.1021/ja027710k

Vinylphosphirane−Phospholene Rearrangements:  Pericyclic [1,3]-Sigmatropic Shifts or Not?

Rosa E. Bulo, Andreas W. Ehlers, Stefan Grimme, and Koop Lammertsma
pp 13903–13910
Publication Date (Web): October 24, 2002 (Article)
DOI: 10.1021/ja027925u

Nuclear Magnetic Resonance Shifts in Paramagnetic Metalloporphyrins and Metalloproteins

Junhong Mao, Yong Zhang, and Eric Oldfield
pp 13911–13920
Publication Date (Web): October 26, 2002 (Article)
DOI: 10.1021/ja020297w

Mössbauer Quadrupole Splittings and Electronic Structure in Heme Proteins and Model Systems:  A Density Functional Theory Investigation

Yong Zhang, Junhong Mao, Nathalie Godbout, and Eric Oldfield
pp 13921–13930
Publication Date (Web): October 26, 2002 (Article)
DOI: 10.1021/ja020298o

Electron Density Topological Analysis of Hydrogen Bonding in Glucopyranose and Hydrated Glucopyranose

Roger A. Klein
pp 13931–13937
Publication Date (Web): October 29, 2002 (Article)
DOI: 10.1021/ja0206947

Efficient CH-Group Selection and Identification in 13C Solid-State NMR by Dipolar DEPT and 1H Chemical-Shift Filtering

K. Schmidt-Rohr and J.-D. Mao
pp 13938–13948
Publication Date (Web): October 26, 2002 (Article)
DOI: 10.1021/ja027362m

Photoinduced Electron Transfer between a Carotenoid and TiO2 Nanoparticle

Jie Pan, Gábor Benkö, Yunhua Xu, Torbjörn Pascher, Licheng Sun, Villy Sundström, and Tomáš Polívka
pp 13949–13957
Publication Date (Web): October 26, 2002 (Article)
DOI: 10.1021/ja0279186

ADDITIONS AND CORRECTIONS

Colloidal Synthesis and Self-Assembly of CoPt3 Nanocrystals  [J. Am. Chem. Soc. 2002, 124, 11480−11485].

Elena V. Shevchenko, Dmitri V. Talapin, Andrey L. Rogach, Andreas Kornowski, Markus Haase, and Horst Weller
p 13958
Publication Date (Web): October 26, 2002 (Addition/Correction)
DOI: 10.1021/ja028730p

BOOK REVIEWS

Electrochemistry of Nanomaterials Edited by Gary Hodes (Weizman Institute of Science). Wiley-VCH:  Weinheim, New York. 2001. xvi + 310 pp. $149.95. ISBN 3-527-29836-3.

John L. Stickney
p 13959
Publication Date (Web): September 13, 2002 (Book Review)
DOI: 10.1021/ja025230n

Multidimensional Chromatography Edited by Luigi Mondello (Universita Degli Studi Di Messina), Alastair C. Lewis, and Keith D. Bartle (University of Leeds). J. Wiley & Sons:  New York. 2002. xiv + 436 pp. $140.00. ISBN 0-471-98869-3.

Abdul Malik
pp 13959–13960
Publication Date (Web): September 20, 2002 (Book Review)
DOI: 10.1021/ja0252328

Chromic Phenomena:  Technological Applications of Color Chemistry By Peter Bamfield. Royal Society of Chemistry:  Cambridge. 2001. xx + 374 pp. $59.50. ISBN 0-85404-474-4.

Michael A. J. Rodgers
p 13960
Publication Date (Web): September 19, 2002 (Book Review)
DOI: 10.1021/ja025205h
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