Table of Contents

Journal Cover
November 26, 2003
Volume 125, Issue 47
Pages 14212-14650
For Selected Content:

COMMUNICATIONS

Iridium-Mediated Asymmetric Hydrogenation of 2,3-Diphenylbutadiene:  A Revealing Kinetic Study

Xiuhua Cui and Kevin Burgess
pp 14212–14213
Publication Date (Web): October 30, 2003 (Communication)
DOI: 10.1021/ja037653a

Orientation and Conformation of Cell-Penetrating Peptide Penetratin in Phospholipid Vesicle Membranes Determined by Polarized-Light Spectroscopy

Christina E. B. Brattwall, Per Lincoln, and Bengt Nordén
pp 14214–14215
Publication Date (Web): October 30, 2003 (Communication)
DOI: 10.1021/ja0366989

Multiple Intermolecular Interaction Modes of Positively Charged Residues with Adenine in ATP-Binding Proteins

Lisong Mao, Yanli Wang, Yuemin Liu, and Xiche Hu
pp 14216–14217
Publication Date (Web): October 30, 2003 (Communication)
DOI: 10.1021/ja036096p

Surface Vibrational Spectroscopy on Shear-Aligned Poly(tetrafluoroethylene) Films

Na Ji, Victor Ostroverkhov, François Lagugné-Labarthet, and Yuen-Ron Shen
pp 14218–14219
Publication Date (Web): October 30, 2003 (Communication)
DOI: 10.1021/ja037964l

Spectroscopy and Reactivity of a Photogenerated Tryptophan Radical in a Structurally Defined Protein Environment

Jeremiah E. Miller, Cristian Grdinaru, Brian R. Crane, Angel J. Di Bilio, William A. Wehbi, Sun Un, Jay R. Winkler, and Harry B. Gray
pp 14220–14221
Publication Date (Web): November 01, 2003 (Communication)
DOI: 10.1021/ja037203i

High-Sensitivity Observation of Dipolar Exchange and NOEs between Exchangeable Protons in Proteins by 3D Solid-State NMR Spectroscopy

Eric K. Paulson, Corey R. Morcombe, Vadim Gaponenko, Barbara Dancheck, R. Andrew Byrd, and Kurt W. Zilm
pp 14222–14223
Publication Date (Web): November 04, 2003 (Communication)
DOI: 10.1021/ja037559u

Synergy between Spin Crossover and Metallophilicity in Triple Interpenetrated 3D Nets with the NbO Structure Type

Ana Galet, Virginie Niel, M. Carmen Muñoz, and José A. Real
pp 14224–14225
Publication Date (Web): November 01, 2003 (Communication)
DOI: 10.1021/ja0377347

Insulating Tubular BN Sheathing on Semiconducting Nanowires

Ying-Chun Zhu, Yoshio Bando, Dong-Feng Xue, Fang-Fang Xu, and Dmitri Golberg
pp 14226–14227
Publication Date (Web): October 30, 2003 (Communication)
DOI: 10.1021/ja0381196

Jahn−Teller Distortion in the Phosphorescent Excited State of Three-Coordinate Au(I) Phosphine Complexes

Khaldoon A. Barakat, Thomas R. Cundari, and Mohammad A. Omary
pp 14228–14229
Publication Date (Web): November 04, 2003 (Communication)
DOI: 10.1021/ja036508u

RNA Degradation in Cell Extracts:  Real-Time Monitoring by Fluorescence Resonance Energy Transfer

Sarah A. Uhler, Dawen Cai, Yunfang Man, Carina Figge, and Nils G. Walter
pp 14230–14231
Publication Date (Web): October 30, 2003 (Communication)
DOI: 10.1021/ja036854b

Quantum Chemistry Can Locally Improve Protein Crystal Structures

Ulf Ryde and Kristina Nilsson
pp 14232–14233
Publication Date (Web): October 30, 2003 (Communication)
DOI: 10.1021/ja0365328

A Hexapeptide Motif that Electrostatically Binds to the Surface of Titanium

Ken-Ichi Sano and Kiyotaka Shiba
pp 14234–14235
Publication Date (Web): October 30, 2003 (Communication)
DOI: 10.1021/ja038414q

The Post-Polyketide Synthase Modification Steps in the Biosynthesis of the Antitumor Agent Ansamitocin by Actinosynnema pretiosum

Peter Spiteller, Linquan Bai, Guangdong Shang, Brian J. Carroll, Tin-Wein Yu, and Heinz G. Floss
pp 14236–14237
Publication Date (Web): November 01, 2003 (Communication)
DOI: 10.1021/ja038166y

A New Approach to the Chemical Synthesis of Keto-Proteins

David Tumelty, Maia Carnevali, and Les P. Miranda
pp 14238–14239
Publication Date (Web): November 01, 2003 (Communication)
DOI: 10.1021/ja037357y

A Programmable Molecular Diode Driven by Charge-Induced Conformational Changes

Pedro A. Derosa, Suneel Guda, and Jorge M. Seminario
pp 14240–14241
Publication Date (Web): October 30, 2003 (Communication)
DOI: 10.1021/ja035071n

Oxidative Cycloamination of Olefins with Aziridines as a Versatile Route to Saturated Nitrogen-Containing Heterocycles

Mikio Sasaki and Andrei K. Yudin
pp 14242–14243
Publication Date (Web): November 04, 2003 (Communication)
DOI: 10.1021/ja037726q

Fast Protein Structure Prediction Using Monte Carlo Simulations with Modal Moves

Paolo Carnevali, Gergely Tóth, Garrick Toubassi, and Siavash N. Meshkat
pp 14244–14245
Publication Date (Web): October 30, 2003 (Communication)
DOI: 10.1021/ja036647b

Parallel Molecular Computations of Pairwise Exclusive-Or (XOR) Using DNA “String Tile” Self-Assembly

Hao Yan, Liping Feng, Thomas H. LaBean, and John H. Reif
pp 14246–14247
Publication Date (Web): October 30, 2003 (Communication)
DOI: 10.1021/ja036676m

Versatile Fluorescence Probes of Protein Kinase Activity

Melissa D. Shults and Barbara Imperiali
pp 14248–14249
Publication Date (Web): November 04, 2003 (Communication)
DOI: 10.1021/ja0380502

Fast Mapping of Protein−Protein Interfaces by NMR Spectroscopy

Michael L. Reese and Volker Dötsch
pp 14250–14251
Publication Date (Web): November 04, 2003 (Communication)
DOI: 10.1021/ja037640x

Orthogonal Self-Assembly of Low Molecular Weight Hydrogelators and Surfactants

André Heeres, Cornelia van der Pol, Marc Stuart, Arianna Friggeri, Ben L. Feringa, and Jan van Esch
pp 14252–14253
Publication Date (Web): October 31, 2003 (Communication)
DOI: 10.1021/ja036954h

Aryl−Oxygen Bond Cleavage by a Trihydride-Bridging Ditantalum Complex

Hiroyuki Kawaguchi and Tsukasa Matsuo
pp 14254–14255
Publication Date (Web): October 30, 2003 (Communication)
DOI: 10.1021/ja037551k

Radical Reactions of Didehydroarenes with a 1,4-Relationship

F. Sedinam Amegayibor, John J. Nash, and Hilkka I. Kenttämaa
pp 14256–14257
Publication Date (Web): November 04, 2003 (Communication)
DOI: 10.1021/ja0360079

Laser-Induced Temperature Jump Electrochemistry on Gold Nanoparticle-Coated Electrodes

Lisa B. Lowe, Scott H. Brewer, Stephan Krämer, Ryan R. Fuierer, Guoguang Qian, Chiamaka O. Agbasi-Porter, Selina Moses, Stefan Franzen, and Daniel L. Feldheim
pp 14258–14259
Publication Date (Web): November 04, 2003 (Communication)
DOI: 10.1021/ja036672h

Asymmetric, Catalytic Synthesis of α-Chiral Amines Using a Novel Bis(phosphine) Monoxide Chiral Ligand

Alessandro A. Boezio, Julien Pytkowicz, Alexandre Côté, and André B. Charette
pp 14260–14261
Publication Date (Web): October 30, 2003 (Communication)
DOI: 10.1021/ja038291+

γ-Allyl Phosphinoyl Phenyl Sulfone (GAPPS):  A Conjunctive Reagent for the Synthesis of EE, EZ, and ET 1,3-Dienes

Xiaojin Li, Douglas Lantrip, and Philip L. Fuchs
pp 14262–14263
Publication Date (Web): October 30, 2003 (Communication)
DOI: 10.1021/ja0377596

A Monometallic f Element Complex of Dinitrogen:  (C5Me5)3U(η1-N2)

William J. Evans, Stosh A. Kozimor, and Joseph W. Ziller
pp 14264–14265
Publication Date (Web): November 01, 2003 (Communication)
DOI: 10.1021/ja037647e

Accelerating Effect of a Proton on the Reduction of CO2 Dissolved in Water under Acidic Conditions. Isolation, Crystal Structure, and Reducing Ability of a Water-Soluble Ruthenium Hydride Complex

Hideki Hayashi, Seiji Ogo, Tsutomu Abura, and Shunichi Fukuzumi
pp 14266–14267
Publication Date (Web): November 01, 2003 (Communication)
DOI: 10.1021/ja036117f

Organic Functionalization and Optical Properties of Carbon Onions

Vasilios Georgakilas, Dirk M. Guldi, Raffaella Signorini, Renato Bozio, and Maurizio Prato
pp 14268–14269
Publication Date (Web): October 31, 2003 (Communication)
DOI: 10.1021/ja0342805

A “Turn-On” Fluorescent Sensor for the Selective Detection of Mercuric Ion in Aqueous Media

Elizabeth M. Nolan and Stephen J. Lippard
pp 14270–14271
Publication Date (Web): October 30, 2003 (Communication)
DOI: 10.1021/ja037995g

Identification of an Activated Catalyst in the Iridium-Catalyzed Allylic Amination and Etherification. Increased Rates, Scope, and Selectivity

Christoph A. Kiener, Chutian Shu, Christopher Incarvito, and John F. Hartwig
pp 14272–14273
Publication Date (Web): October 31, 2003 (Communication)
DOI: 10.1021/ja038319h

A Highly Stable Gadolinium Complex with a Fast, Associative Mechanism of Water Exchange

Marlon K. Thompson, Mauro Botta, Gaëlle Nicolle, Lothar Helm, Silvio Aime, André E. Merbach, and Kenneth N. Raymond
pp 14274–14275
Publication Date (Web): November 04, 2003 (Communication)
DOI: 10.1021/ja037441d

Epoxide-Opening and Group-Transfer Reactions Mediated by Monomeric Zirconium Imido Complexes

Suzanne A. Blum, Patrick J. Walsh, and Robert G. Bergman
pp 14276–14277
Publication Date (Web): November 04, 2003 (Communication)
DOI: 10.1021/ja037267t

Polarizing the Nazarov Cyclization:  Efficient Catalysis under Mild Conditions

Wei He, Xiufeng Sun, and Alison J. Frontier
pp 14278–14279
Publication Date (Web): October 30, 2003 (Communication)
DOI: 10.1021/ja037910b

Single-Phase and Gram-Scale Routes toward Nearly Monodisperse Au and Other Noble Metal Nanocrystals

Nikhil R. Jana and Xiaogang Peng
pp 14280–14281
Publication Date (Web): November 04, 2003 (Communication)
DOI: 10.1021/ja038219b

The 4-Oxalocrotonate Tautomerase- and YwhB-Catalyzed Hydration of 3E-Haloacrylates:  Implications for the Evolution of New Enzymatic Activities

Susan C. Wang, William H. Johnson, Jr., and Christian P. Whitman
pp 14282–14283
Publication Date (Web): November 01, 2003 (Communication)
DOI: 10.1021/ja0370948

Nanocrystalline Todorokite-Like Manganese Oxide Produced by Bacterial Catalysis

Hack-Sung Kim, Pablo A. Pastén, Jean-François Gaillard, and Peter C. Stair
pp 14284–14285
Publication Date (Web): October 31, 2003 (Communication)
DOI: 10.1021/ja0375784

Intermolecular, Markovnikov Hydroamination of Vinylarenes with Alkylamines

Masaru Utsunomiya and John F. Hartwig
pp 14286–14287
Publication Date (Web): November 01, 2003 (Communication)
DOI: 10.1021/ja0375535

Regioselectivity in the Stille Coupling Reactions of 3,5-Dibromo-2-pyrone

Won-Suk Kim, Hyung-Jin Kim, and Cheon-Gyu Cho
pp 14288–14289
Publication Date (Web): November 01, 2003 (Communication)
DOI: 10.1021/ja037043a

New Structures from Multiple Rearrangements of Propargylic Dialkoxy Disulfides

Samuel Braverman, Tatiana Pechenick, Hugo E. Gottlieb, and Milon Sprecher
pp 14290–14291
Publication Date (Web): November 04, 2003 (Communication)
DOI: 10.1021/ja036962y

Alkane C−H Activation and Catalysis by an O-Donor Ligated Iridium Complex

Antek G. Wong-Foy, Gaurav Bhalla, Xiang Yang Liu, and Roy A. Periana
pp 14292–14293
Publication Date (Web): November 04, 2003 (Communication)
DOI: 10.1021/ja037849a

Total Synthesis of Gymnocin-A

Chihiro Tsukano and Makoto Sasaki
pp 14294–14295
Publication Date (Web): November 04, 2003 (Communication)
DOI: 10.1021/ja038547b

Evidence for Homo-Conjugation between Two Revolving 14π-Electron Systems in 10b-Methyl-10c-[2-(10b,10c-dimethyl-10b,10c-dihydropyrenyl)]-10b,10c-dihydropyrene

Jianping Jiang and Yee-Hing Lai
pp 14296–14297
Publication Date (Web): November 04, 2003 (Communication)
DOI: 10.1021/ja0382260

Rational Design of Transglutaminase Substrate Peptides for Rapid Enzymatic Formation of Hydrogels

Bi-Huang Hu and Phillip B. Messersmith
pp 14298–14299
Publication Date (Web): October 31, 2003 (Communication)
DOI: 10.1021/ja038593b

ARTICLES

Crystal Structure and Hydrogen Bonding System in Cellulose Iα from Synchrotron X-ray and Neutron Fiber Diffraction

Yoshiharu Nishiyama, Junji Sugiyama, Henri Chanzy, and Paul Langan
pp 14300–14306
Publication Date (Web): November 05, 2003 (Article)
DOI: 10.1021/ja037055w

Enhancing the Modularity of the Modular Polyketide Synthases:  Transacylation in Modular Polyketide Synthases Catalyzed by Malonyl-CoA:ACP Transacylase

Pawan Kumar, Andrew T. Koppisch, David E. Cane, and Chaitan Khosla
pp 14307–14312
Publication Date (Web): October 31, 2003 (Article)
DOI: 10.1021/ja037429l

Iminosugar Glycosidase Inhibitors:  Structural and Thermodynamic Dissection of the Binding of Isofagomine and 1-Deoxynojirimycin to β-Glucosidases

David L. Zechel, Alisdair B. Boraston, Tracey Gloster, Catherine M. Boraston, James M. Macdonald, D. Matthew G. Tilbrook, Robert V. Stick, and Gideon J. Davies
pp 14313–14323
Publication Date (Web): November 04, 2003 (Article)
DOI: 10.1021/ja036833h

Disulfide Bond Isomerization in Basic Pancreatic Trypsin Inhibitor:  Multisite Chemical Exchange Quantified by CPMG Relaxation Dispersion and Chemical Shift Modeling

Michael J. Grey, Chunyu Wang, and Arthur G. Palmer, III
pp 14324–14335
Publication Date (Web): October 29, 2003 (Article)
DOI: 10.1021/ja0367389

Molecular Recognition of Protein Surfaces:  High Affinity Ligands for the CBP KIX Domain

Stacey E. Rutledge, Heather M. Volkman, and Alanna Schepartz
pp 14336–14347
Publication Date (Web): November 04, 2003 (Article)
DOI: 10.1021/ja034508o

Anion-Mediated Transfer of Polyarginine across Liquid and Bilayer Membranes

Naomi Sakai and Stefan Matile
pp 14348–14356
Publication Date (Web): October 31, 2003 (Article)
DOI: 10.1021/ja037601l

Enzymatic Synthesis of Chondroitin and Its Derivatives Catalyzed by Hyaluronidase

Shiro Kobayashi, Shun-ichi Fujikawa, and Masashi Ohmae
pp 14357–14369
Publication Date (Web): November 04, 2003 (Article)
DOI: 10.1021/ja036584x

Superoxide Dismutase Targets NO from GSNO to Cysβ93 of Oxyhemoglobin in Concentrated but Not Dilute Solutions of the Protein

Andrea A. Romeo, John A. Capobianco, and Ann M. English
pp 14370–14378
Publication Date (Web): October 31, 2003 (Article)
DOI: 10.1021/ja0289752

Universal NMR Databases for Contiguous Polyols

Shuhei Higashibayashi, Werngard Czechtizky, Yoshihisa Kobayashi, and Yoshito Kishi
pp 14379–14393
Publication Date (Web): November 01, 2003 (Article)
DOI: 10.1021/ja0375481

Prototypal Dithiazolodithiazolyl Radicals:  Synthesis, Structures, and Transport Properties

Leanne Beer, James F. Britten, Jaclyn L. Brusso, A. Wallace Cordes, Robert C. Haddon, Mikhail E. Itkis, Douglas S. MacGregor, Richard T. Oakley, Robert W. Reed, and Craig M. Robertson
pp 14394–14403
Publication Date (Web): November 04, 2003 (Article)
DOI: 10.1021/ja0371350

Phosphine Coordination Complexes of the Diphenylphosphenium Cation:  A Versatile Synthetic Methodology for P−P Bond Formation

Neil Burford, Paul J. Ragogna, Robert McDonald, and Michael J. Ferguson
pp 14404–14410
Publication Date (Web): November 04, 2003 (Article)
DOI: 10.1021/ja036649w

Ketone Enolization by Lithium Hexamethyldisilazide:  Structural and Rate Studies of the Accelerating Effects of Trialkylamines

Pinjing Zhao and David B. Collum
pp 14411–14424
Publication Date (Web): October 31, 2003 (Article)
DOI: 10.1021/ja030168v

A Computational Study of the Cycloaddition of Thiobenzophenone S-Methylide to Thiobenzophenone

Reiner Sustmann, Willi Sicking, and Rolf Huisgen
pp 14425–14434
Publication Date (Web): November 01, 2003 (Article)
DOI: 10.1021/ja0377551

Multicomponent Linchpin Couplings. Reaction of Dithiane Anions with Terminal Epoxides, Epichlorohydrin, and Vinyl Epoxides:  Efficient, Rapid, and Stereocontrolled Assembly of Advanced Fragments for Complex Molecule Synthesis

Amos B. Smith, III, Suresh M. Pitram, Armen M. Boldi, Matthew J. Gaunt, Chris Sfouggatakis, and William H. Moser
pp 14435–14445
Publication Date (Web): October 30, 2003 (Article)
DOI: 10.1021/ja0376238

Exclusive Formation of α-Methyleneoxetanes in Ketene−Alkene Cycloadditions. Evidence for Intervention of Both an α-Methyleneoxetane and the Subsequent 1,4-Zwitterion

Takahisa Machiguchi, Junko Okamoto, Junpei Takachi, Toshio Hasegawa, Shinichi Yamabe, and Tsutomu Minato
pp 14446–14448
Publication Date (Web): October 31, 2003 (Article)
DOI: 10.1021/ja030191g

Ammonium Cyanate Shows N−H···N Hydrogen Bonding, Not N−H···O

Elizabeth J. MacLean, Kenneth D. M. Harris, Benson M. Kariuki, Simon J. Kitchin, Rik R. Tykwinski, Ian P. Swainson, and Jack D. Dunitz
pp 14449–14451
Publication Date (Web): November 01, 2003 (Article)
DOI: 10.1021/ja021156x

A Reverse Turn Structure Induced by a d,l-α-Aminoxy Acid Dimer

Dan Yang, Jin Qu, Wei Li, De-Ping Wang, Yi Ren, and Yun-Dong Wu
pp 14452–14457
Publication Date (Web): October 29, 2003 (Article)
DOI: 10.1021/ja029514j

Ion Pairing in Fast-Exchange Host−Guest Systems:  Concentration Dependence of Apparent Association Constants for Complexes of Neutral Hosts and Divalent Guest Salts with Monovalent Counterions

Feihe Huang, Jason W. Jones, Carla Slebodnick, and Harry W. Gibson
pp 14458–14464
Publication Date (Web): November 05, 2003 (Article)
DOI: 10.1021/ja036606f

Reversible Light-Driven Structural Changes between the Mono- and Bilayer Stacking Alignments in 4-Octadecyloxystilbazolium Arylcarboxylate Films

Osamu Ohtani, Hiroki Kato, Tatsuto Yui, and Katsuhiko Takagi
pp 14465–14472
Publication Date (Web): October 31, 2003 (Article)
DOI: 10.1021/ja030310s

Synthesis of Porous Emulsion-Templated Polymers Using High Internal Phase CO2-in-Water Emulsions

R. Butler, I. Hopkinson, and A. I. Cooper
pp 14473–14481
Publication Date (Web): November 01, 2003 (Article)
DOI: 10.1021/ja037570u

Organotitanium-Mediated Stereoselective Coordinative/Insertive Homopolymerizations and Copolymerizations of Styrene and Methyl Methacrylate

Tryg R. Jensen, Sung Cheol Yoon, Aswini K. Dash, Lubin Luo, and Tobin J. Marks
pp 14482–14494
Publication Date (Web): November 04, 2003 (Article)
DOI: 10.1021/ja0363664

Correspondence between Molecular Functionality and Crystal Structures. Supramolecular Chemistry of a Family of Homologated Aminophenols

Venu R. Vangala, Balakrishna R. Bhogala, Archan Dey, Gautam R. Desiraju, Charlotte K. Broder, Philip S. Smith, Raju Mondal, Judith A. K. Howard, and Chick C. Wilson
pp 14495–14509
Publication Date (Web): November 01, 2003 (Article)
DOI: 10.1021/ja037227p

Pathways for Photoinduced Charge Separation in DNA Hairpins

D. Beljonne, G. Pourtois, M. A. Ratner, and J. L. Brédas
pp 14510–14517
Publication Date (Web): October 30, 2003 (Article)
DOI: 10.1021/ja035596f

The Effect of Global Compaction on the Local Secondary Structure of Folded Dendrimers

Baohua Huang, Matthew A. Prantil, Terry L. Gustafson, and Jon R. Parquette
pp 14518–14530
Publication Date (Web): October 31, 2003 (Article)
DOI: 10.1021/ja037895a

Electrospun MEH-PPV/SBA-15 Composite Nanofibers Using a Dual Syringe Method

Sudha Madhugiri, Alan Dalton, Jose Gutierrez, John P. Ferraris, and Kenneth J. Balkus Jr.
pp 14531–14538
Publication Date (Web): October 31, 2003 (Article)
DOI: 10.1021/ja030326i

Low-Temperature Synthesis of Soluble and Processable Organic-Capped Anatase TiO2 Nanorods

P. Davide Cozzoli, Andreas Kornowski, and Horst Weller
pp 14539–14548
Publication Date (Web): October 31, 2003 (Article)
DOI: 10.1021/ja036505h

Template Burning inside TS-1 and Fe-MFI Molecular Sieves:  An in Situ XRPD Study

Marco Milanesio, Gilberto Artioli, Alessandro F. Gualtieri, Luca Palin, and Carlo Lamberti
pp 14549–14558
Publication Date (Web): November 04, 2003 (Article)
DOI: 10.1021/ja037229+

Synthesis of Face-Centered Tetragonal FePt Nanoparticles and Granular Films from Pt@Fe2O3 Core−Shell Nanoparticles

Xiaowei Teng and Hong Yang
pp 14559–14563
Publication Date (Web): November 01, 2003 (Article)
DOI: 10.1021/ja0376700

Fluorescence Quenching of Dyes by Tryptophan:  Interactions at Atomic Detail from Combination of Experiment and Computer Simulation

Andrea C. Vaiana, Hannes Neuweiler, Andreas Schulz, Jürgen Wolfrum, Markus Sauer, and Jeremy C. Smith
pp 14564–14572
Publication Date (Web): November 04, 2003 (Article)
DOI: 10.1021/ja036082j

Novel Microporous Lanthanide Silicates with Tobermorite-Like Structure

Artur Ferreira, Duarte Ananias, Luís D. Carlos, Cláudia M. Morais, and João Rocha
pp 14573–14579
Publication Date (Web): November 01, 2003 (Article)
DOI: 10.1021/ja036988p

Degradation of Myoglobin by Polymeric Artificial Metalloproteases Containing Catalytic Modules with Various Catalytic Group Densities:  Site Selectivity in Peptide Bond Cleavage

Chang Eun Yoo, Pil Seok Chae, Jung Eun Kim, Eui June Jeong, and Junghun Suh
pp 14580–14589
Publication Date (Web): November 01, 2003 (Article)
DOI: 10.1021/ja034730t

Solvatomagnetism-Induced Faraday Effect in a Cobalt Hexacyanochromate-Based Magnet

Yusuke Sato, Shin-ichi Ohkoshi, Ken-ichi Arai, Masanori Tozawa, and Kazuhito Hashimoto
pp 14590–14595
Publication Date (Web): November 01, 2003 (Article)
DOI: 10.1021/ja030375v

Role of Entropy in Increased Rates of Intramolecular Reactions

Anthony A. Armstrong and L. Mario Amzel
pp 14596–14602
Publication Date (Web): November 04, 2003 (Article)
DOI: 10.1021/ja0344359

Theoretical Study of a New DNA Structure:  The Antiparallel Hoogsteen Duplex

Elena Cubero, Nicola G. A. Abrescia, Juan A. Subirana, F. Javier Luque, and Modesto Orozco
pp 14603–14612
Publication Date (Web): November 04, 2003 (Article)
DOI: 10.1021/ja035918f

Millisecond Kinetics on a Microfluidic Chip Using Nanoliters of Reagents

Helen Song and Rustem F. Ismagilov
pp 14613–14619
Publication Date (Web): October 29, 2003 (Article)
DOI: 10.1021/ja0354566

A General NMR Method for Rapid, Efficient, and Reliable Biochemical Screening

Claudio Dalvit, Elena Ardini, Maria Flocco, Gian Paolo Fogliatto, Nicola Mongelli, and Marina Veronesi
pp 14620–14625
Publication Date (Web): November 04, 2003 (Article)
DOI: 10.1021/ja038128e

Isomeric Structures and Visible Electronic Spectrum of the C7H3 Radicals

Hongbin Ding, Thomas Pino, Felix Güthe, and John P. Maier
pp 14626–14630
Publication Date (Web): November 01, 2003 (Article)
DOI: 10.1021/ja029650o

Ne3−NH3 van der Waals Tetramer:  Rotational Spectra and ab Initio Study of the Microsolvation of NH3 with Rare Gas Atoms

Jennifer van Wijngaarden and Wolfgang Jäger
pp 14631–14641
Publication Date (Web): October 30, 2003 (Article)
DOI: 10.1021/ja035252p

Overlooked Difference between Hydrogen Bonds of Equal Strength Formed between Catechol and an Oxygen or Nitrogen Base. Experiments and DFT Calculations

Mario C. Foti, Gino A. DiLabio, and K. U. Ingold
pp 14642–14647
Publication Date (Web): October 29, 2003 (Article)
DOI: 10.1021/ja036168c

ADDITIONS AND CORRECTIONS

Intermolecular Transition Metal-Catalyzed [4 + 2 + 2] Cycloaddition Reactions:  A New Approach to the Construction of Eight-Membered Rings   [J. Am. Chem. Soc. 2002, 124 (30), 8782−8783]. 

P. Andrew Evans, John E. Robinson, Erich W. Baum, and Aleem N. Fazal
p 14648
Publication Date (Web): October 21, 2003 (Addition/Correction)
DOI: 10.1021/ja033458k

BOOK REVIEWS

MALDI-TOF Mass Spectrometry of Synthetic Polymers By Harald Pasch (Deutsches Kunststoff-Institut, Darmstadt, Germany) and Wolfgang Schrepp (BASF AG, Ludwigshafen, Germany). Springer-Verlag:  Berlin, Heidelberg, New York. 2003. xviii + 298 pp. $89.95. ISBN 3-540-44259-6.

Mehdi Moini
p 14649
Publication Date (Web): October 21, 2003 (Book Review)
DOI: 10.1021/ja033564m

Progress in the Chemistry of Organic Natural Products, 86 Edited by W. Herz (The Florida State University, Tallahassee), H. Falk (Johannes-Kepler-Universität), and G. W. Kirby (University of Glasgow). Featuring “Monopyrrolic Natural Compounds Including Tetramic Acid Derivatives” by A. Gossauer (University of Fribourg). Springer-Verlag:  Wien. 2003. viii + 222 pp. $149.00. ISBN 3-211-83889-9.

Philip DeShong
pp 14649–14650
Publication Date (Web): October 17, 2003 (Book Review)
DOI: 10.1021/ja0335869

Methods in Polyphenol Analysis Edited by Celestino Santos-Buelga (University of Salamanca) and Gary Williamson (Nestlé Research Center, Lausanne). Royal Society of Chemistry:  Cambridge. 2003. xvi + 384 pp. $199.00. ISBN 0-85404-580-5.

Paul W. Paré
p 14650
Publication Date (Web): October 17, 2003 (Book Review)
DOI: 10.1021/ja033571a
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