Table of Contents

March 21, 1997
Volume 62, Issue 6
Pages 1566-1908
For Selected Content:

Articles

Palladium-Catalyzed Carbonylation of o-Iodophenols with Allenes

Kazumi Okuro and Howard Alper
pp 1566–1567
Publication Date (Web): March 21, 1997 (Communication)
DOI: 10.1021/jo962283c

Palladium-Catalyzed Amination of Aryl Bromides:  Use of Phosphinoether Ligands for the Efficient Coupling of Acyclic Secondary Amines

Jean-François Marcoux, Seble Wagaw, and Stephen L. Buchwald
pp 1568–1569
Publication Date (Web): March 21, 1997 (Communication)
DOI: 10.1021/jo9622946

Biomimetic-Type Synthesis of Halogenated Tetrahydrofurans from Laurencia. Total Synthesis of trans-(+)-Deacetylkumausyne

Tomás Martín, Marcos A. Soler, Juan M. Betancort, and Victor S. Martín
pp 1570–1571
Publication Date (Web): March 21, 1997 (Communication)
DOI: 10.1021/jo962135m

Kinetics of the Oxiranylcarbinyl Radical Rearrangement

Venkat Krishnamurthy and Viresh H. Rawal
pp 1572–1573
Publication Date (Web): March 21, 1997 (Communication)
DOI: 10.1021/jo962054q

Enantioselective Syntheses of α-, β-, and γ-Aryl Amino Acids and Esters

Yong Sun Park and Peter Beak
pp 1574–1575
Publication Date (Web): March 21, 1997 (Communication)
DOI: 10.1021/jo9700080

1,1-Bis(dimethylamino)-2,2,2-trifluoroethane, a Readily-Available Precursor to the Novel Fluorinated Building Block 1,1-Bis(dimethylamino)-2,2-difluoroethene

Yuelian Xu, William R. Dolbier, Jr., and Xiao X. Rong
pp 1576–1577
Publication Date (Web): March 21, 1997 (Communication)
DOI: 10.1021/jo9700033

Vinyl Oxocarbenium Ions in Intermolecular [4 + 3] Cycloaddition Reactions

Michael Harmata and Darin E. Jones
pp 1578–1579
Publication Date (Web): March 21, 1997 (Communication)
DOI: 10.1021/jo962374+

Efficient Synthesis of Carbovir and Its Congener via π-Allylpalladium Complex Formation by Ring Strain-Assisted C−N Bond Cleavage

Nobuya Katagiri, Masahiro Takebayashi, Hideaki Kokufuda, Chikara Kaneko, Kouichi Kanehira, and Masahiro Torihara
pp 1580–1581
Publication Date (Web): March 21, 1997 (Communication)
DOI: 10.1021/jo962416u

Sonogashira Coupling of 2-Iodo-2-cycloalkenones:  Synthesis of (+)- and (−)-Harveynone and (−)-Tricholomenyn A

Michael W. Miller and Carl R. Johnson
pp 1582–1583
Publication Date (Web): March 21, 1997 (Communication)
DOI: 10.1021/jo962295y

Facile Preparation of Cyclopropylamines from Carboxamides

Jinhwa Lee and Jin Kun Cha
pp 1584–1585
Publication Date (Web): March 21, 1997 (Communication)
DOI: 10.1021/jo962368d

Solid-Phase Synthesis of Peptide Mimetics with (E)-Alkene Amide Bond Replacements Derived from Alkenylaziridines

Peter Wipf and Todd C. Henninger
pp 1586–1587
Publication Date (Web): March 21, 1997 (Communication)
DOI: 10.1021/jo9701039

2,3,7,8,12,13,17,18-Octafluoro-5,10,15,20-tetraarylporphyrins and Their Zinc Complexes:  First Spectroscopic, Electrochemical, and Structural Characterization of a Perfluorinated Tetraarylmetalloporphyrin

Eric K. Woller and Stephen G. DiMagno
pp 1588–1593
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo962159t

A New Gold Catalyst:  Formation of Gold(I) Carbonyl, [Au(CO)n]+ (n = 1, 2), in Sulfuric Acid and Its Application to Carbonylation of Olefins

Qiang Xu, Yuki Imamura, Masahiro Fujiwara, and Yoshie Souma
pp 1594–1598
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo9620122

Replacement of the 1‘,4‘-Phenylene Region in 5,10-Dideaza-5,6,7,8-tetrahydrofolic Acid (DDATHF) by 4,5,6,7-Tetrahydrobenzo[c]thiophene and 4,5,6,7-Tetrahydroisobenzofuran Nuclei

Edward C. Taylor and James E. Dowling
pp 1599–1603
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo9619903

Enantioselective Allylic Substitutions Catalyzed by [(Hydroxyalkyl)pyridinooxazoline]- and [(Alkoxyalkyl)pyridinooxazoline]palladium Complexes

Kerstin Nordström, Emmanuel Macedo, and Christina Moberg
pp 1604–1609
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo961490+

Diyl Trapping Reactions To Synthesize Taxol Analogs

Michael M. Ott and R. Daniel Little
pp 1610–1616
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo970042e

Mitsunobu C-Alkylation of Meldrum's Acids

Tony K. M. Shing, Lian-Hai Li, and Kesavaram Narkunan
pp 1617–1622
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo962288+

Reaction of α-Peroxy Lactones with C, N, P, and S Nucleophiles:  Adduct Formation and Nucleophile Oxidation by Nucleophilic Attack at and Biphilic Insertion into the Peroxide Bond

Waldemar Adam and Lluís Blancafort
pp 1623–1629
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo962039l

A Stereospecific Access to Allylic Systems Using Rhodium(II)−Vinyl Carbenoid Insertion into Si−H, O−H, and N−H Bonds

Priyadarshanie Bulugahapitiya, Yannick Landais, Liliana Parra-Rapado, Denis Planchenault, and Valéry Weber
pp 1630–1641
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo961952j

Cyclization Reactions of Rhodium Carbene Complexes. Effect of Composition and Oxidation State of the Metal

Albert Padwa, Jamal M. Kassir, and Simon L. Xu
pp 1642–1652
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo962271r

Stereoselective Synthesis of a Key Intermediate of Sanfetrinem by Means of a Chelated Tin(IV) Enolate

Tino Rossi, Carla Marchioro, Alfredo Paio, Russell J. Thomas, and Paola Zarantonello
pp 1653–1661
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo962095m

Biosynthesis of the Brevianamides. An ab Initio Study of the Biosynthetic Intramolecular Diels−Alder Cycloaddition

Luis R. Domingo, Juan F. Sanz-Cervera, Robert M. Williams, M. Teresa Picher, and J. Alberto Marco
pp 1662–1667
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo9621783

Tandem [4 + 2]/[3 + 2] Cycloadditions of Nitroalkenes. 13. The Synthesis of (−)-Detoxinine

Scott E. Denmark, Alexander R. Hurd, and Hubert J. Sacha
pp 1668–1674
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo962306n

Asymmetric Construction of a Quaternary Carbon Center by Tandem [4 + 2]/[3 + 2] Cycloaddition of a Nitroalkene. The Total Synthesis of (−)-Mesembrine

Scott E. Denmark and Lawrence R. Marcin
pp 1675–1686
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo970079z

Synthesis of α-Necrodol:  Unexpected Formation of a Cyclopropene

Douglass F. Taber and Han Yu
pp 1687–1690
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo961780q

Total Synthesis of (−)-Ircinianin and (+)-Wistarin

Jun'ichi Uenishi, Reiko Kawahama, and Osamu Yonemitsu
pp 1691–1701
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo961993f

Single Stereodifferentiation Associated with Carbon Atom Insertion during the Oxonium Ion-Initiated Pinacol Rearrangement of Dihydrofuranyl and Dihydropyranyl Carbinols

Leo A. Paquette, James C. Lanter, and Jeffrey N. Johnston
pp 1702–1712
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo962019j

Practical Synthesis of Spirocyclic Bis-C,C-glycosides. Mechanistic Models in Explanation of Rearrangement Stereoselectivity and the Bifurcation of Reaction Pathways

Leo A. Paquette, Margaret J. Kinney, and Uta Dullweber
pp 1713–1722
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo962020i

Realization of Complete Regiochemical Control during the Conversion of Squarate Esters into Complex Linear and Angular Polyquinanes. The Consequences of Incorporating a Leaving Group into One of the Alkenyllithium Reactants

Leo A. Paquette and Julien Doyon
pp 1723–1729
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo962181m

Sensitivity of Substitution to the Extent of Self-Immolative Chirality Transfer during Reaction Cascades Originating from Squarate Esters

Leo A. Paquette, Lung Huang Kuo, Ashton T. Hamme, II, Rüdiger Kreuzholz, and Julien Doyon
pp 1730–1736
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo962182e

Reactions of Cobalt-Complexed Acetylenic Aldehydes with Chiral (γ-Alkoxyallyl)boranes:  Enantioselective Synthesis of 3,4-Dioxy 1,5-Enynes and Stereoselective Entry to Polyfunctional Building Blocks

P. Ganesh and K. M. Nicholas
pp 1737–1747
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo9619387

Determination of the Relative and Absolute Stereochemistry of Fostriecin (CI-920)

Dale L. Boger, Masataka Hikota, and Bryan M. Lewis
pp 1748–1753
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo962166h

A Short, Flexible Route toward 2‘-C-Branched Ribonucleosides

Rogers E. Harry-O'kuru, Jennifer M. Smith, and Michael S. Wolfe
pp 1754–1759
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo961893+

exo,exo-4,8-Ethenopolyfluoro-2,6-dioxaperhydroindacenes. Unusual Alkenes Flanked with Fluorine Atoms

Wojciech Dmowski, Ireneusz Nowak, Przemysław Gluziński, and Andrei Kemme
pp 1760–1765
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo962023v

λ4σ2-Sulfur Heterocycles. An ab Initio and Density Functional Study

Jürgen FabianB. Andes Hess, Jr.
pp 1766–1774
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo961776e

Ab Initio Study of Stereo- and Regioselectivity in the Diels−Alder Reaction between 2-Phenylcyclopentadiene and α-(Methylthio)acrylonitrile

Luis R. Domingo, M. Teresa Picher, Juan Andrés, and Vicent S. Safont
pp 1775–1778
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo961785n

Electrochemical Reduction of Pyridine- and Benzene-Substituted n-Alkyl Esters and Thioic S-Esters in Acetonitrile

Richard D. Webster and Alan M. Bond
pp 1779–1787
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo961492u

Synthesis of C-Alkylcalix[4]arenes. 5. Design, Synthesis, Computational Studies, and Homodimerization of Polymethylene-Bridged Resorc[4]arenes

Bruno Botta, Giuliano Delle Monache, M. Cristina De Rosa, Catia Seri, Ettore Benedetti, Rosa Iacovino, Maurizio Botta, Federico Corelli, Vega Masignani, Andrea Tafi, Eszter Gacs-Baitz, Antonello Santini, and Domenico Misiti
pp 1788–1794
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo9619692

Conversion of Marcfortine A to Paraherquamide A via Paraherquamide B. The First Formal Synthesis of Paraherquamide A

Byung H. Lee and Michael F. Clothier
pp 1795–1798
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo9622791

Ruthenium Complex-Catalyzed Reaction of Isocyanoacetate and N-Sulfonylimines:  Stereoselective Synthesis of N-Sulfonyl-2-Imidazolines

Ying-Rui Lin, Xiao-Ti Zhou, Li-Xin Dai, and Jie Sun
pp 1799–1803
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo961598p

Construction of Indole and Benzofuran Systems on the Solid Phase via Palladium-Mediated Cyclizations1

Han-Cheng Zhang and Bruce E. Maryanoff
pp 1804–1809
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo962071f

Aeruginosins 205A and -B, Serine Protease Inhibitory Glycopeptides from the Cyanobacterium Oscillatoria agardhii (NIES-205)

Hee Jae Shin, Hisashi Matsuda, Masahiro Murakami, and Katsumi Yamaguchi
pp 1810–1813
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo961902e

Batzelladines F−I, Novel Alkaloids from the Sponge Batzella sp.:  Inducers of p56lck-CD4 Dissociation

Ashok D. Patil, Alan J. Freyer, Paul B. Taylor, Brad Carté, Gary Zuber, Randall K. Johnson, and D. John Faulkner
pp 1814–1819
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo962084t

Covalent Modification of Proteins and Peptides by the Quinone Methide from 2-tert-Butyl-4,6-dimethylphenol:  Selectivity and Reactivity with Respect to Competitive Hydration

Paul G. McCracken, Judy L. Bolton, and Gregory R. J. Thatcher
pp 1820–1825
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo962088y

Molecular Recognition Study on a Supramolecular System. 10.1 Inclusion Complexation of Modified β-Cyclodextrins with Amino Acids:  Enhanced Enantioselectivity for l/d-Leucine

Yu Liu, Yi-Min Zhang, Ai-Di Qi, Rong-Ti Chen, Keiko Yamamoto, Takehiko Wada, and Yoshihisa Inoue
pp 1826–1830
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo961625b

Enantioselective Esterification of 2-Arylpropionic Acids Catalyzed by Immobilized Rhizomucor miehei Lipase

Ma Trinidad López-Belmonte, Andrés R. Alcántara, and José V. Sinisterra
pp 1831–1840
Publication Date (Web): March 21, 1997 (Article)
DOI: 10.1021/jo961342j

Reduction of Imines with Zinc Borohydride Supported on Silica Gel. Highly Stereoselective Synthesis of Substituted Cyclohexylamines

Brindaban C. Ranu, Arunkanti Sarkar, and Adinath Majee
pp 1841–1842
Publication Date (Web): March 21, 1997 (Note)
DOI: 10.1021/jo961736a

Co(III)DMG-Catalyzed Synthesis of Allylamides from Allyl Alcohols and Acetonitrile

Manoj Mukhopadhyay and Javed Iqbal
pp 1843–1845
Publication Date (Web): March 21, 1997 (Note)
DOI: 10.1021/jo960557q

Synthesis and Properties of Oligoribonucleotide Analogs Having Formacetal Internucleoside Linkages

Eriks Rozners and Roger Strömberg
pp 1846–1850
Publication Date (Web): March 21, 1997 (Note)
DOI: 10.1021/jo962080o

Synthesis of 7-Substituted Saccharins and 8-Substituted Oxicams, and a Novel Saccharin to Oxicam Transformation

John R. Proudfoot, Usha R. Patel, and Alexey B. Dyatkin
pp 1851–1853
Publication Date (Web): March 21, 1997 (Note)
DOI: 10.1021/jo961955w

An Easy Approach to the Synthesis of Optically Active vic-Diols:  A New Single-Enzyme System

Olga Bortolini, Giancarlo Fantin, Marco Fogagnolo, Pier Paolo Giovannini, Alessandra Guerrini, and Alessandro Medici
pp 1854–1856
Publication Date (Web): March 21, 1997 (Note)
DOI: 10.1021/jo9618381

Neighboring Methoxy Group Effect in Solvolysis Reactions of Cyclopentyl and Cyclohexyl p-Toluenesulfonates

Donald D. Roberts
pp 1857–1859
Publication Date (Web): March 21, 1997 (Note)
DOI: 10.1021/jo961941q

Chiroptical Spectra of 1,2-Cyclopropanedicarboxylic Monothioimides1

Maria J. Milewska, Maria Gdaniec, and Tadeusz Połoński
pp 1860–1862
Publication Date (Web): March 21, 1997 (Note)
DOI: 10.1021/jo961724p

Hydroxylation of Marcfortine A at C14, C15, and C16 via a Novel Cyanogen Iodide Reaction

Byung H. Lee and Michael F. Clothier
pp 1863–1867
Publication Date (Web): March 21, 1997 (Note)
DOI: 10.1021/jo962131h

Antitumor Polyether Macrolides:  New and Hemisynthetic Halichondrins from the New Zealand Deep-Water Sponge Lissodendoryx sp.

Marc Litaudon, Sarah J. H. Hickford, Rachel E. Lill, Robin J. Lake, John W. Blunt, and Murray H. G. Munro
pp 1868–1871
Publication Date (Web): March 21, 1997 (Note)
DOI: 10.1021/jo962231n

Preparation and Characterization of trans-1,4-Diazido-1,4-dinitrocyclohexane and exo-2,5-Diazido-endo-2,5-dinitronorbornane:  Stable Geminal Azido−Nitro Compounds

G. K. Surya Prakash, John J. Struckhoff, Jr., Klaus Weber, Andre Schreiber, Robert Bau, and George A. Olah
pp 1872–1874
Publication Date (Web): March 21, 1997 (Note)
DOI: 10.1021/jo9620268

Improved Methods for the Synthesis of Porphyrin Alcohols and Aldehydes from Protoporphyrin IX Dimethyl Ester and Their Further Modification

Stephen B. Kahl, John J. Schaeck, and Myoung-Seo Koo
pp 1875–1880
Publication Date (Web): March 21, 1997 (Note)
DOI: 10.1021/jo961381v

Noncascade Tandem Transformations Involving Allylic Silanes. 1. Pericyclic and Ionic Reactions Combined into “One-Pot” Sequences

Michael G. Organ and Derick D. Winkle
pp 1881–1885
Publication Date (Web): March 21, 1997 (Note)
DOI: 10.1021/jo962025f

Novel Synthesis of Vinylcyclopropyl Ketones and Vinylcyclopropanecarboxylic Acids:  Application to the Stereoselective Synthesis of trans-Chrysanthemic Acid

Alain Krief, Thierry Ollevier, and Willy Dumont
pp 1886–1890
Publication Date (Web): March 21, 1997 (Note)
DOI: 10.1021/jo962015e

Computations and 1H NMR Spectroscopy of the Imide Region Can Distinguish Isomers of Hydrogen-Bonded Aggregates

Donovan N. Chin, Eric E. Simanek, Xinhua Li, Mohammed I. M. Wazeer, and George M. Whitesides
pp 1891–1895
Publication Date (Web): March 21, 1997 (Note)
DOI: 10.1021/jo961176f

Enantioselective Total Synthesis of (−)-α-Kainic Acid through Free Radical Cyclization of an Alkenyl Monothioformimide

Mario D. Bachi and Artem Melman
pp 1896–1898
Publication Date (Web): March 21, 1997 (Note)
DOI: 10.1021/jo962100m

Synthesis of Covalently-Linked exo-Calix[4]arenes

Thomas N. Sorrell and Hongping Yuan
pp 1899–1902
Publication Date (Web): March 21, 1997 (Note)
DOI: 10.1021/jo961815m

Monopyrrolo-Annelated Tetrathiafulvalenes

Kyukwan Zong and Michael P. Cava
pp 1903–1905
Publication Date (Web): March 21, 1997 (Note)
DOI: 10.1021/jo962303a

threo-3,4-Divinyladipic Acid

Robert B. Grossman
pp 1906–1908
Publication Date (Web): March 21, 1997 (Note)
DOI: 10.1021/jo962305v

Pathways for Stereoinformation Transfer:  Enhanced Enantioselectivity via Diastereomeric Recycling of Organolithium/(−)-Sparteine Complexes

Amit Basu, Donald J. Gallagher, and Peter Beak
p 1908
Publication Date (Web): March 21, 1997 (Addition/Correction)
DOI: 10.1021/jo964031h

Facile 1,3- and 1,5-Chlorine Migration

Rainer Koch, Ming Kah Wong, and Curt Wentrup
p 1908
Publication Date (Web): March 21, 1997 (Addition/Correction)
DOI: 10.1021/jo9740002

Palladium-Catalyzed Cross Coupling Reactions of β-Iodo-β,γ-enones with Organozinc Chlorides

Fen-Tair Luo and Li-Chen Hsieh
p 1908
Publication Date (Web): March 21, 1997 (Addition/Correction)
DOI: 10.1021/jo974001u
For Selected Content:
Advertisements
Advertisement
Info for Advertisers
SciFinder subscribers: Click to sign in | Not a SciFinder subscriber? Learn more at www.cas.org

Browse By Issue

List of Issues

Stay Current

Sign up to get notices about the latest articles via e-mail and RSS feed.

Learn more
Advertisements
Advertisement
Info for Advertisers