Table of Contents

May 8, 2003
Volume 107, Issue 18
Pages 3147-3575

About the Cover: Artwork from the 1996 commemorative Centennial Issue of The Journal of Physical Chemistry (Volume 100, Issue No. 31, August 1, 1996). Special Issue honoring George S. Hammond and Michael Kasha

For Selected Content:

GEORGE S. HAMMOND and MICHAEL KASHA FESTSCHRIFT

Special Issue Honoring George S. Hammond and Michael Kasha

Jack SaltielRobert S. H. Liu
pp 3147–3148
Publication Date (Web): May 1, 2003 (Article)
DOI: 10.1021/jp030182u

Biography of George S. Hammond

Carl C. Wamser
pp 3149–3150
Publication Date (Web): April 11, 2003 (Article)
DOI: 10.1021/jp030184e

Researchers Associated with George S. Hammond

p 3151
Publication Date (Web): May 1, 2003 (Article)
DOI: 10.1021/jp030274j

Publications of George S. Hammond

pp 3152–3160
Publication Date (Web): May 1, 2003 (Article)
DOI: 10.1021/jp030183m

Research Career of Michael Kasha

Robin HochstrasserJack Saltiel
pp 3161–3162
Publication Date (Web): May 1, 2003 (Article)
DOI: 10.1021/jp030179a

Researchers Associated with Michael Kasha

p 3163
Publication Date (Web): May 1, 2003 (Article)
DOI: 10.1021/jp030180+

Publications of Michael Kasha

pp 3164–3168
Publication Date (Web): May 1, 2003 (Article)
DOI: 10.1021/jp0301812

ARTICLES

Layered Nanocomposites of Aggregated Dyes and Inorganic Scaffolding

Ileana Place, Thomas L. Penner, Duncan W. McBranch, and David G. Whitten
pp 3169–3177
Publication Date (Web): October 10, 2002 (Article)
DOI: 10.1021/jp026048b

Photoisomerization of all-trans-1,6-Diphenyl-1,3,5-hexatriene. Temperature and Deuterium Isotope Effects

Jack Saltiel, Govindarajan Krishnamoorthy, Zhennian Huang, Dong-Hoon Ko, and Shujun Wang
pp 3178–3186
Publication Date (Web): December 17, 2002 (Article)
DOI: 10.1021/jp021540g

Alkali Ion-Controlled Excited-State Ordering of Acetophenones Included in Zeolites:  Emission, Solid-State NMR, and Computational Studies

J. Shailaja, P. H. Lakshminarasimhan, Ajit R. Pradhan, R. B. Sunoj, Steffen Jockusch, S. Karthikeyan, Sundararajan Uppili, J. Chandrasekhar, Nicholas J. Turro, and V. Ramamurthy
pp 3187–3198
Publication Date (Web): December 4, 2002 (Article)
DOI: 10.1021/jp0265586

Intramolecular Directional Energy Transfer Processes in Dendrimers Containing Perylene and Terrylene Chromophores

Gerd Schweitzer, Roel Gronheid, Sven Jordens, Marc Lor, Gino De Belder, Tanja Weil, Erik Reuther, Klaus Müllen, and Frans C. De Schryver
pp 3199–3207
Publication Date (Web): November 27, 2002 (Article)
DOI: 10.1021/jp026459s

Application of Time-Resolved Step-Scan Fourier Transform Infrared Spectroscopy to Photochemical Mechanistic Investigations of Alkyl Phenylglyoxylates,

A. V. Fedorov, E. O. Danilov, A. G. Merzlikine, M. A. J. Rodgers, and D. C. Neckers
pp 3208–3214
Publication Date (Web): February 7, 2003 (Article)
DOI: 10.1021/jp021573w

Synthesis and Photophysics of a Copper-Porphyrin−Styrene−C60 Hybrid

Dirk M. GuldiBerthold Nuber, Paul J. Bracher, Christopher A. Alabi, Shaun MacMahon, Jonathan W. Kukol, Stephen R. Wilson, and David I. Schuster
pp 3215–3221
Publication Date (Web): February 21, 2003 (Article)
DOI: 10.1021/jp0264836

Two-Bond 13C−15N Spin−Spin Coupling Constants (2hJC-N) Across C−H−N Hydrogen Bonds

Janet E. Del Bene, S. Ajith Perera, Rodney J. Bartlett, Manuel Yañez, Otilia Mó, José Elguero, and Ibon Alkorta
pp 3222–3227
Publication Date (Web): November 12, 2002 (Article)
DOI: 10.1021/jp021619l

Energy Equilibration among the Chlorophylls in the Electron-Transfer System of Photosystem I Reaction Center from Spinach

Shigeichi Kumazaki, Isamu Ikegami, Hiroko Furusawa, and Keitaro Yoshihara
pp 3228–3235
Publication Date (Web): December 20, 2002 (Article)
DOI: 10.1021/jp026532e

CH-Stretching Overtone Spectra of 3-Hexyne and Butane

Bryan R. Henry and David M. TurnbullDaniel P. Schofield and Henrik G. Kjaergaard
pp 3236–3243
Publication Date (Web): January 1, 2003 (Article)
DOI: 10.1021/jp021650n

Ground and Excited-State Acetic Acid Catalyzed Double Proton Transfer in 2-Aminopyridine

Fa-Tsai Hung, Wei-Ping Hu, Tsung-Hui Li, Chung-Chih Cheng, and Pi-Tai Chou
pp 3244–3253
Publication Date (Web): December 6, 2002 (Article)
DOI: 10.1021/jp021620k

Structures and Excited States of Extended and Folded Mono-, Di-, and Tri-N-Arylbenzamides

Frederick D. Lewis, Timothy M. Long, Charlotte L. Stern, and Weizhong Liu
pp 3254–3262
Publication Date (Web): October 31, 2002 (Article)
DOI: 10.1021/jp0264937

The Dynamics of Ultrafast Excited State Proton Transfer in Anionic Micelles

Letícia Giestas, Chang Yihwa, João C. Lima, Carolina Vautier-Giongo, António Lopes, Antonio L. Maçanita, and Frank H. Quina
pp 3263–3269
Publication Date (Web): January 7, 2003 (Article)
DOI: 10.1021/jp0265900

Effect of Noble Gas van der Waals Induced Dipoles on the Work Function of Metals

Bruno Linder and Robert A. Kromhout
pp 3270–3276
Publication Date (Web): January 24, 2003 (Article)
DOI: 10.1021/jp0217334

Photoannulation of 4,4-Dimethylcyclohex-2-en-1-one To 1,1-Diphenylethylene

Richard A. Caldwell, Ralf Constien, and Bryan G. Kriel
pp 3277–3286
Publication Date (Web): April 4, 2003 (Article)
DOI: 10.1021/jp026635x

Photochemistry of Crystalline Chlorodiazirines:  The Influence of Conformational Disorder and Intermolecular Cl···NN Interactions on the Solid-State Reactivity of Singlet Chlorocarbenes

Carlos N. Sanrame, Christopher P. Suhrada, Hung Dang, and Miguel A. Garcia-Garibay
pp 3287–3294
Publication Date (Web): March 27, 2003 (Article)
DOI: 10.1021/jp026641t

Orbital Control of the Color and Excited State Properties of Formylated and Fluorinated Derivatives of Azulene

Sergey V. Shevyakov, Hongru Li, Rajeev Muthyala, Alfred E. Asato, John C. Croney, David M. Jameson, and Robert S. H. Liu
pp 3295–3299
Publication Date (Web): April 4, 2003 (Article)
DOI: 10.1021/jp021605f

Steady-State Fluorescence of Dye-Sensitized TiO2 Xerogels and Aerogels as a Probe for Local Chromophore Aggregation

Annette R. Howells and Marye Anne Fox
pp 3300–3304
Publication Date (Web): November 27, 2002 (Article)
DOI: 10.1021/jp021789y

Photohydration of Benzophenone in Aqueous Acid

Markus Ramseier, Paul Senn, and Jakob Wirz
pp 3305–3315
Publication Date (Web): January 9, 2003 (Article)
DOI: 10.1021/jp026663f

Interplay between Intra- and Intermolecular Excited-State Single- and Double-Proton-Transfer Processes in the Biaxially Symmetric Molecule 3,7-Dihydroxy-4H,6H-pyrano[3,2-g]-chromene-4,6-dione

Elena Falkovskaia, Vasyl G. Pivovarenko, and Juan Carlos del Valle
pp 3316–3325
Publication Date (Web): March 7, 2003 (Article)
DOI: 10.1021/jp021791p

A Novel Approach for Measuring Absolute Rate Constants by Pulsed Electron Spin Resonance:  Addition of Phosphinoyl and 2-Hydroxy-2-propyl Radicals to Several Alkenes,

Matthias Weber and Nicholas J. Turro
pp 3326–3334
Publication Date (Web): March 19, 2003 (Article)
DOI: 10.1021/jp021790x

Electrogenerated Chemiluminescence. 70. The Application of ECL to Determine Electrode Potentials of Tri-n-propylamine, Its Radical Cation, and Intermediate Free Radical in MeCN/Benzene Solutions

Rebecca Y. Lai and Allen J. Bard
pp 3335–3340
Publication Date (Web): April 16, 2003 (Article)
DOI: 10.1021/jp026743j

Energetics of Primary Charge Separation in Bacterial Photosynthetic Reaction Center Mutants:  Triplet Decay in Large Magnetic Fields

Alex de Winter and Steven G. Boxer
pp 3341–3350
Publication Date (Web): November 23, 2002 (Article)
DOI: 10.1021/jp021867h

Stark Spectroscopy of Size-Selected Helical H-Aggregates of a Cyanine Dye Templated by Duplex DNA. Effect of Exciton Coupling on Electronic Polarizabilities

Arindam Chowdhury, Liping Yu, Izzat Raheem, Linda Peteanu, L. Angela Liu, and David J. Yaron
pp 3351–3362
Publication Date (Web): April 10, 2003 (Article)
DOI: 10.1021/jp021866p

Reactant Destabilization in the Bergman Cyclization and Rational Design of Light- and pH-Activated Enediynes

Igor V. Alabugin and Mariappan Manoharan
pp 3363–3371
Publication Date (Web): December 18, 2002 (Article)
DOI: 10.1021/jp026754c

Surface-Enhanced Raman Scattering Studies on Aggregated Gold Nanorods

Babak Nikoobakht and Mostafa A. El-Sayed
pp 3372–3378
Publication Date (Web): April 8, 2003 (Article)
DOI: 10.1021/jp026770+

Effects of Bridging Ligands on the Current−Potential Behavior and Interfacial Kinetics of Ruthenium-Sensitized Nanocrystalline TiO2 Photoelectrodes

Kristine Kilså, Elizabeth I. Mayo, Darius Kuciauskas, Randy Villahermosa, Nathan S. Lewis, Jay R. Winkler, and Harry B. Gray
pp 3379–3383
Publication Date (Web): April 11, 2003 (Article)
DOI: 10.1021/jp021921u

Vibrational Coupling between Amide-I and Amide-A Modes Revealed by Femtosecond Two Color Infrared Spectroscopy

Igor V. Rubtsov, Jianping Wang, and Robin M. Hochstrasser
pp 3384–3396
Publication Date (Web): January 9, 2003 (Article)
DOI: 10.1021/jp021922m

Singlet Oxygen (1Δg) Production by Ruthenium(II) Complexes in Microheterogeneous Systems

María Isela Gutiérrez, Claudia G. Martínez, David García-Fresnadillo, Ana M. Castro, Guillermo Orellana, André M. Braun, and Esther Oliveros
pp 3397–3403
Publication Date (Web): January 4, 2003 (Article)
DOI: 10.1021/jp021923e

Computer Modeling and Simulations on Flexible Bifunctional Systems:  Intramolecular Energy Transfer Implications

Luboš Vrbka, Petr Klán, Zdeněk Kríz, Jaroslav Koca, and Peter J. Wagner
pp 3404–3413
Publication Date (Web): March 11, 2003 (Article)
DOI: 10.1021/jp026890h

Computational Investigation of Vicinal Disulfoxides and Other Sulfinyl Radical Dimers

Daniel D. Gregory and William S. Jenks
pp 3414–3423
Publication Date (Web): March 27, 2003 (Article)
DOI: 10.1021/jp026888q

Ultrafast Dynamics of Gold-Based Nanocomposite Materials

Joseph S. Melinger, Valeria D. Kleiman, and Dale McMorrowFranziska Gröhn, Barry J. Bauer, and Eric Amis
pp 3424–3431
Publication Date (Web): May 1, 2003 (Article)
DOI: 10.1021/jp026885d

Electron-Transfer Photochemistry of cis- and trans-1,2-Diphenylcyclopropane with Singlet Acceptors:  Recombination of Radical Ion Pairs of Singlet and Triplet Multiplicity

Heinz D. Roth
pp 3432–3437
Publication Date (Web): April 5, 2003 (Article)
DOI: 10.1021/jp026902z

Remote Activation of the Quadricyclane Group in a Quadricyclane−Steroid−{Dibenzoylmethanatoboron Difluoride} System by Intramolecular Electron Transfer

Li-Ping Zhang, Bin Chen, Li-Zhu Wu, and Chen-Ho TungHong Cao and Yoshifumi Tanimoto
pp 3438–3442
Publication Date (Web): March 15, 2003 (Article)
DOI: 10.1021/jp026918p

Metal-Enhanced Fluorescence (MEF) Due to Silver Colloids on a Planar Surface:  Potential Applications of Indocyanine Green to in Vivo Imaging

Chris D. Geddes, Haishi Cao, Ignacy Gryczynski, Zygmunt Gryczynski, Jiyu Fang, and Joseph R. Lakowicz
pp 3443–3449
Publication Date (Web): March 20, 2003 (Article)
DOI: 10.1021/jp022040q

Rapid Molecular Motion of Pyrene and Benzene Moieties Covalently Attached to Silica Surfaces

Michael E. Sigman, Shelly Read, John T. Barbas, Ilia Ivanov, Edward W. Hagaman, A. C. Buchanan, III, Reza Dabestani, Michelle K. Kidder, and Phillip F. Britt
pp 3450–3456
Publication Date (Web): February 4, 2003 (Article)
DOI: 10.1021/jp022045n

Isotopic Effects in the Laser Control of Dissociative Ionization at High Intensities:  Role of Permanent Dipole Moments†

J. Levesque, S. Chelkowski, and A. D. Bandrauk
pp 3457–3470
Publication Date (Web): April 1, 2003 (Article)
DOI: 10.1021/jp022044v

Single-Crystal Magic-Angle Spinning 17O NMR and Theoretical Studies of the Antiferroelectric Phase Transition in Squaric Acid

N. S. Dalal, K. L. Pierce, J. Palomar, and R. Fu
pp 3471–3475
Publication Date (Web): March 28, 2003 (Article)
DOI: 10.1021/jp0220478

Photophysics and Photoinduced Electron-Transfer Reactivity of Ruthenium(II) Complexes with Oligo(thiophene-bipyridine) Ligands,1

Yao Liu, Antoinette De Nicola, Olivier Reiff, Raymond Ziessel, and Kirk S. Schanze
pp 3476–3485
Publication Date (Web): March 28, 2003 (Article)
DOI: 10.1021/jp026971d

Substituent and Solvent Effects on the Hyperporphyrin Spectra of Diprotonated Tetraphenylporphyrins

James R. Weinkauf, Sharon W. Cooper, Aaron Schweiger, and Carl C. Wamser
pp 3486–3496
Publication Date (Web): December 20, 2002 (Article)
DOI: 10.1021/jp022046f

Photodissociation of SO2 Clusters

S. M. Hurley, T. E. Dermota, D. P. Hydutsky, and A. W. Castleman, Jr.
pp 3497–3502
Publication Date (Web): March 7, 2003 (Article)
DOI: 10.1021/jp022097c

Synthesis, Photochemistry, and Electrochemistry of a Series of Phthalocyanines with Graded Steric Hindrance

Gongzhen Cheng, Xinzhan Peng, Guolun Hao, Vance O. Kennedy, Ilya N. Ivanov, Kenneth Knappenberger, Tessa J. Hill, Michael A. J. Rodgers, and Malcolm E. Kenney
pp 3503–3514
Publication Date (Web): January 28, 2003 (Article)
DOI: 10.1021/jp027006q

Intersystem Crossing in Charge-Transfer Excited States

Ian R. GouldJames A. Boiani, Elizabeth B. Gaillard, and Joshua L. GoodmanSamir Farid
pp 3515–3524
Publication Date (Web): February 27, 2003 (Article)
DOI: 10.1021/jp022096k

Effect of Base Sequence and Hydration on the Electronic and Hole Transport Properties of Duplex DNA:  Theory and Experiment

Robert N. Barnett, Charles L. Cleveland, Uzi Landman, Edna Boone, Sriram Kanvah, and Gary B. Schuster
pp 3525–3537
Publication Date (Web): February 28, 2003 (Article)
DOI: 10.1021/jp022211r

Analysis of the Gearing−Antigearing Torsional Fundamental Energy Gap in Dimethyl Ether

Vojislava Pophristic and Lionel Goodman
pp 3538–3542
Publication Date (Web): March 25, 2003 (Article)
DOI: 10.1021/jp022212j

Comparison of Energy Deposition Modes in Polyethylene Films by Megaelectronvolt Range Neutrons, Electrons, Protons, and α Particles as Monitored by Covalent Attachment of Doped Pyrene Molecules

Gerald O. Brown, Noel A. Guardala, Jack L. Price, and Richard G. Weiss
pp 3543–3551
Publication Date (Web): April 08, 2003 (Article)
DOI: 10.1021/jp022274+

Non-Stern−Volmer Quenching of S1 pDFB Fluorescence by O2 and the Charge Transfer Complex

Uros S. Tasic, Ernest R. Davidson, and Charles S. Parmenter
pp 3552–3558
Publication Date (Web): April 5, 2003 (Article)
DOI: 10.1021/jp022281y

The Disilane Chromophore:  Photoelectron and Electronic Spectra of Hexaalkyldisilanes and 1,(n+2)-Disila[n.n.n]propellanes

Deborah L. Casher, Hayato Tsuji, Atsushi Sano, Martins Katkevics, Akio Toshimitsu, Kohei Tamao, Mari Kubota, Tsunetoshi Kobayashi, C. Henrik Ottosson, Donald E. David, and Josef Michl
pp 3559–3566
Publication Date (Web): May 1, 2003 (Article)
DOI: 10.1021/jp027380q

Stepwise Sequential and Parallel Photoinduced Charge Separation in a Porphyrin−Triquinone Tetrad

Joseph Springer, Gerdenis Kodis, Linda de la Garza, Ana L. Moore, Thomas A. Moore, and Devens Gust
pp 3567–3575
Publication Date (Web): March 27, 2003 (Article)
DOI: 10.1021/jp022424g
For Selected Content:
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