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November 20, 2009

Gold(III) Adducts with Chiral Pyridinyl-Oxazolines. Synthesis, Reactivity of the Coordinated Ligands, and Structural Characterizations

Maria A. Cinellu, Laura Maiore, Giovanni Minghetti, Fabio Cocco, Sergio Stoccoro, Antonio Zucca, Mario Manassero and Carlo Manassero
Publication Date (Web): November 20, 2009 (Article)
DOI: 10.1021/om900841b

November 19, 2009

Introduction to the Review by H. Schmidbaur and A. Schier in This Issue of Organometallics

Dietmar Seyferth
Publication Date (Web): November 19, 2009 (Editor's Page)
DOI: 10.1021/om900979t
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Gold η2-Coordination to Unsaturated and Aromatic Hydrocarbons: The Key Step in Gold-Catalyzed Organic Transformations

Hubert Schmidbaur and Annette Schier
Publication Date (Web): November 19, 2009 (Review)
DOI: 10.1021/om900900u

November 18, 2009

Transmetalation of a Primary Amino-Functionalized N-Heterocyclic Carbene Ligand from an Axially Chiral Square-Planar Nickel(II) Complex to a Ruthenium(II) Precatalyst for the Transfer Hydrogenation of Ketones

Wylie W. N. O, Alan J. Lough and Robert H. Morris
Publication Date (Web): November 18, 2009 (Article)
DOI: 10.1021/om9007746

“Metastable” Lu(GaMe4)3 Reacts Like Masked [LuMe3]: Synthesis of an Unsolvated Lanthanide Dimethyl Complex

Melanie Zimmermann, Rannveig Litlabø, Karl W. Trnroos and Reiner Anwander
Publication Date (Web): November 18, 2009 (Communication)

November 17, 2009

Kinetic and Mechanistic Studies of the Formal (1+2)- and (1+4)-Cycloadditions of Germylenes to Conjugated Dienes

Lawrence A. Huck and William J. Leigh
Publication Date (Web): November 17, 2009 (Article)
DOI: 10.1021/om900791e

November 16, 2009

Preparation, Characterization, and Catalytic Properties of Ruthenium(II) Nitrosyl Complexes with α-Diimine Ligands

Hui-Jun Xu, Xiang-Yong Lu, Yong Cheng, Jia-Feng Sun, Xue-Tai Chen and Zi-Ling Xue
Publication Date (Web): November 16, 2009 (Article)
DOI: 10.1021/om9006714

Phosphino and Phosphonito Carbyne Complexes: [Mo(≡CX)(CO)2{HB(pzMe2)3}] (X = PPh2, P(═O)(OEt)2; pz = Pyrazol-1-yl)

Richard L. Cordiner, Paul A. Gugger, Anthony F. Hill and Anthony C. Willis
Publication Date (Web): November 16, 2009 (Communication)
DOI: 10.1021/om900868s

November 13, 2009

Carbonyl-Substituted Nickelocenes by the Cross-Metathesis Route

Włodzimierz Buchowicz and Magdalena Szmajda
Publication Date (Web): November 13, 2009 (Note)
DOI: 10.1021/om9008444

Synthesis, Properties, and Reactivity of Diketiminate-Supported Cobalt Fluoride Complexes

Keying Ding, Thomas R. Dugan, William W. Brennessel, Eckhard Bill and Patrick L. Holland
Publication Date (Web): November 13, 2009 (Article)
DOI: 10.1021/om900394t

Versatile, Selective, and Switchable Coordination Modes of Pincer Click Ligands

Elaine M. Schuster, Mark Botoshansky and Mark Gandelman
Publication Date (Web): November 13, 2009 (Article)
DOI: 10.1021/om900827g

November 12, 2009

Ruthenium-Diphosphine-Catalyzed Allylation of Phenols: A gem-Dialkyl-Type Effect Induces High Selectivity toward O-Allylation

Jimmy A. van Rijn, Maxime A. Siegler, Anthony L. Spek, Elisabeth Bouwman and Eite Drent
Publication Date (Web): November 12, 2009 (Article)
DOI: 10.1021/om900832g

Syntheses and Properties of Salts of Chromophores with Ferrocenyl Electron Donor Groups and Quaternary Nitrogen Acceptors

Benjamin J. Coe, Rebecca J. Docherty, Simon P. Foxon, Elizabeth C. Harper, Madeleine Helliwell, James Raftery, Koen Clays, Edith Franz and Bruce S. Brunschwig
Publication Date (Web): November 12, 2009 (Article)
DOI: 10.1021/om9007955

November 11, 2009

Bis(o-phosphinophenyl)silane as a Scaffold for Dynamic Behavior of H−Si and C−Si Bonds with Palladium(0)

Jun Takaya and Nobuharu Iwasawa
Publication Date (Web): November 11, 2009 (Communication)
DOI: 10.1021/om900874p

Steric and Electronic Effects of Carbene Substitution in Grubbs First-Generation Catalysts

David R. Lane, Christine M. Beavers, Marilyn M. Olmstead and Neil E. Schore
Publication Date (Web): November 11, 2009 (Article)
DOI: 10.1021/om900762n

Ring-Strain-Formation Lewis Acidity? A Pentacoordinate Silacyclobutane Comprising Exclusively Equatorial Si−C Bonds

Dedicated to Prof. Dr. Reinhold Tacke on the occasion of his 60th birthday.

Robert Gericke, Daniela Gerlach and Jrg Wagler
Publication Date (Web): November 11, 2009 (Note)
DOI: 10.1021/om900741a

Preparation and Characterization of Homologous Diiron Dithiolato, Diselenato, and Ditellurato Complexes: [FeFe]-Hydrogenase Models

Mohammad K. Harb, Ulf-Peter Apfel, Joachim Kbel, Helmar Grls, Greg A. N. Felton, Taka Sakamoto, Dennis H. Evans, Richard S. Glass, Dennis L. Lichtenberger, Mohammad El-khateeb and Wolfgang Weigand
Publication Date (Web): November 11, 2009 (Article)
DOI: 10.1021/om900675q

EPR Monitoring of Vanadium(IV) Species Formed upon Activation of Vanadium(V) Polyphenolate Precatalysts with AlR2Cl and AlR2Cl/Ethyltrichloroacetate (R = Me, Et)

Igor E. Soshnikov, Nina V. Semikolenova, Alexander A. Shubin, Konstantin P. Bryliakov, Vladimir A. Zakharov, Carl Redshaw and Evgenii P. Talsi
Publication Date (Web): November 11, 2009 (Article)
DOI: 10.1021/om900515h

November 10, 2009

Reactivity of Diazoalkanes with Tantalum(V) Complexes of a Tridentate Amido-Bis(phenolate) Ligand

Ryan A. Zarkesh and Alan F. Heyduk
Publication Date (Web): November 10, 2009 (Communication)

Redox-Active N-Heterocyclic Carbenes: Design, Synthesis, and Evaluation of Their Electronic Properties

Evelyn L. Rosen, C. Daniel Varnado, Jr., Andrew G. Tennyson, Dimitri M. Khramov, Justin W. Kamplain, Daphne H. Sung, Philip T. Cresswell, Vincent M. Lynch and Christopher W. Bielawski
Publication Date (Web): November 10, 2009 (Article)
DOI: 10.1021/om900698x

A Kinetics Study of the Oxidative Addition of Bromobenzene to Pd(PCy3)2 (Cy = cyclohexyl) in a Nonpolar Medium: The Influence on Rates of Added PCy3 and Bromide Ion

Emily A. Mitchell, Philip G. Jessop and Michael C. Baird
Publication Date (Web): November 10, 2009 (Article)
DOI: 10.1021/om900679w

Half-Sandwich Lanthanide(III) Complexes Coordinated by Two α-Iminopyridine Radical Anions

Alexander A. Trifonov, Ivan D. Gudilenkov, Joulia Larionova, Carlos Luna, Georgy K. Fukin, Anton V. Cherkasov, Andrei I. Poddel’sky and Nikolai O. Druzhkov
Publication Date (Web): November 10, 2009 (Article)
DOI: 10.1021/om9004143

Iridium−Molybdenum Carbido Complex via C−Se Activation of a Selenocarbonyl Ligand: (μ-Se2)[Ir2{C≡Mo(CO)2(Tp*)}2(CO)2(PPh3)2] (Tp* = hydrotris(dimethylpyrazolyl)borate)

Ian A. Cade, Anthony F. Hill and Caitlin M. A. McQueen
Publication Date (Web): November 10, 2009 (Communication)
DOI: 10.1021/om9008873

Redox-Active Phosphorus Ligands Bearing a [4Fe−4C] Core Substituent

Masaaki Okazaki, Ken-ichi Yoshimura, Masato Takano and Fumiyuki Ozawa
Publication Date (Web): November 10, 2009 (Note)
DOI: 10.1021/om900811u

November 9, 2009

Application of Tautomerism of Ferrocenyl Secondary Phosphine Oxides in Suzuki−Miyaura Cross Coupling Reactions

Lin-Ying Jung, Shih-Hung Tsai and Fung-E Hong
Publication Date (Web): November 9, 2009 (Addition/Correction)
DOI: 10.1021/om9009685

User-Friendly Precatalyst for the Methylation of Polyfluoroaryl Imines

Heather L. Buckley, Alex D. Sun and Jennifer A. Love
Publication Date (Web): November 9, 2009 (Communication)
DOI: 10.1021/om9008229

November 6, 2009

Reactivity and Stability of 2-Platinaoxetanes

Jianguo Wu and Paul R. Sharp
Publication Date (Web): November 6, 2009 (Article)
DOI: 10.1021/om900828k

Reactivity Consequences of Steric Reduction in Cyclopentadienyl Chromium β-Diketiminate Complexes

K. Cory MacLeod, Julia L. Conway, Liming Tang, Joshua J. Smith, Liam D. Corcoran, Katherine H. D. Ballem, Brian O. Patrick and Kevin M. Smith
Publication Date (Web): November 6, 2009 (Article)

Chelation-Assisted Reactions of Phosphine- and Olefin-Tethered Imidazolium Derivatives and Their Affiliated N-Heterocyclic Carbenes with Roper’s Complex Ru(CO)2(PPh3)3

Laure Benhamou, Joffrey Wolf, Vincent Csar, Agns Labande, Rinaldo Poli, Nol Lugan and Guy Lavigne
Publication Date (Web): November 6, 2009 (Article)
DOI: 10.1021/om900813p

Olefin Metathesis Catalysts Containing Acyclic Diaminocarbenes

Evelyn L. Rosen, Daphne H. Sung, Zheng Chen, Vincent M. Lynch and Christopher W. Bielawski
Publication Date (Web): November 6, 2009 (Article)
DOI: 10.1021/om9008718

Microwave Synthesis of Benchmark Organo-Iron Complexes

Sean M. Garringer, Andrew J. Hesse, John R. Magers, Kristopher R. Pugh, Stacy A. O’Reilly and Anne M. Wilson
Publication Date (Web): November 6, 2009 (Note)
DOI: 10.1021/om900821c

Crown Ether Palladacycles as Metalloligands: Suitable Precursors for Tetranuclear Mixed Transition/Non-Transition Metal Complexes

Samuel Castro-Juiz, Alberto Fernndez, Margarita Lpez-Torres, Digna Vzquez-Garca, Antonio J. Surez, Jos M. Vila and Jess J. Fernndez
Publication Date (Web): November 6, 2009 (Article)

Migratory Insertion of Allyl Groups across the Pd−C Bond in Palladium(II) Isocyanide Complexes. The Fundamental Interplay between Temperature and Allyl Hapticity

Luciano Canovese, Fabiano Visentin, Claudio Santo and Carlo Levi
Publication Date (Web): November 6, 2009 (Article)
DOI: 10.1021/om900786e

Monomeric Tetraalkylaluminates of Divalent Ytterbium Stabilized by a Bulky Tris(pyrazolyl)borate Ligand

Rannveig Litlabø, Kuburat Saliu, Michael J. Ferguson, Robert McDonald, Josef Takats and Reiner Anwander
Publication Date (Web): November 6, 2009 (Article)
DOI: 10.1021/om900744k

November 4, 2009

Palladium-Catalyzed Nonalternating Copolymerization of Ethene and Carbon Monoxide: Scope and Mechanism

Rong Luo, David K. Newsham and Ayusman Sen
Publication Date (Web): November 4, 2009 (Article)

Reactions of Oxygen with Metallaheterocyclic Alkyl Amide Complexes. Selective Insertion of Oxygen into Metal−Carbon Bonds

Xianghua Yu, Xue-Tai Chen and Zi-Ling Xue
Publication Date (Web): November 4, 2009 (Communication)
DOI: 10.1021/om900773w

Tetramethylaluminate and Tetramethylgallate Coordination in Rare-Earth Metal Half-Sandwich and Metallocene Complexes

H. Martin Dietrich, Karl W. Trnroos, Eberhardt Herdtweck and Reiner Anwander
Publication Date (Web): November 4, 2009 (Article)
DOI: 10.1021/om9007168

Hexameric Methylstannoxyl Carbonate Ion [MeSn(O)CO3]66−. A Missing Link with a Drum-Type Structure

S. Usman Ahmad, Jens Beckmann and Andrew Duthie
Publication Date (Web): November 4, 2009 (Note)
DOI: 10.1021/om900797a

Synthesis, Structure, and Reactivity of Alkyl-Substituted Half-Sandwich η5-Pentadienyl Complexes of Cobalt

Kai E. O. Ylijoki, Ross D. Witherell, Andrew D. Kirk, Sebastian Bcklein, Verner A. Lofstrand, Robert McDonald, Michael J. Ferguson and Jeffrey M. Stryker
Publication Date (Web): November 4, 2009 (Article)
DOI: 10.1021/om900754h

Reactivity of [(2-Phosphino)ethenyl]zirconocene Chloride toward CpM(CO)3Cl (M = Mo, W): Formation of [(3-Phosphino)propenoyl]dicarbonyl(cyclopentadienyl)metal, {CpM(CO)2[(CO)CR═CRPPh2]}

Xiaoyu Yan, Bingran Yu, Lan Wang, Ning Tang and Chanjuan Xi
Publication Date (Web): November 4, 2009 (Note)
DOI: 10.1021/om900595w

November 5, 2009

M−Cl/Si−Cl Preferential Reactivity in Chlorosilyl-Substituted Cyclopentadienyl Early Transition Metal Complexes in Reactions with Amines: Key to Understanding the Nature of the Final Product

Cristina Paniagua, Marta E. G. Mosquera, Heiko Jacobsen, Gerardo Jimnez and Toms Cuenca
Publication Date (Web): November 5, 2009 (Article)
DOI: 10.1021/om9008026

November 3, 2009

An (η3-Disilaallyl)lithium Derivative: Interconversion of π-Allyl-Type Bonding and η1 Coordination to a Silyllithium Fragment

Hiroaki Tanaka, Shigeyoshi Inoue, Masaaki Ichinohe and Akira Sekiguchi
Publication Date (Web): November 3, 2009 (Communication)
DOI: 10.1021/om900861z

October 30, 2009

π Back-Bonding in Dibenzyl-β-diketiminato Copper Olefin Complexes

Paul O. Oguadinma and Frank Schaper
Publication Date (Web): October 30, 2009 (Article)
DOI: 10.1021/om900840f

October 29, 2009

N-Heterocyclic Carbene Transfer from Gold(I) to Palladium(II)

Shiuh-Tzung Liu, Chun-I Lee, Ching-Feng Fu, Chang-Hong Chen, Yi-Hung Liu, Cornelis J. Elsevier, Shei-Ming Peng and Jwu-Ting Chen
Publication Date (Web): October 29, 2009 (Article)
DOI: 10.1021/om900776j

Synthesis and Structure of Polynuclear Indoxanes and Thalloxanes Containing Bulky m-Terphenyl Substituents

S. Usman Ahmad and Jens Beckmann
Publication Date (Web): October 29, 2009 (Article)
DOI: 10.1021/om9007967

October 28, 2009

Synthesis of Arylphosphonates via Palladium-Catalyzed Coupling Reactions of Aryl Imidazolylsulfonates with H-Phosphonate Diesters

Yong Luo and Jie Wu
Publication Date (Web): October 28, 2009 (Note)
DOI: 10.1021/om900771v

β-Diketiminato Nickel(I) Complexes with Very Weak Ligation Allowing for H2 and N2 Activation

Stefan Pfirrmann, Shenglai Yao, Burkhard Ziemer, Reinhard Stsser, Matthias Driess and Christian Limberg
Publication Date (Web): October 28, 2009 (Article)
DOI: 10.1021/om9007983

October 26, 2009

A New Approach to the Reduction of Carbon Dioxide: CO2 Reduction to Formate by Transfer Hydrogenation in iPrOH

Sergio Sanz, Miriam Bentez and Eduardo Peris
Publication Date (Web): October 26, 2009 (Note)
DOI: 10.1021/om900820x

October 23, 2009

Synthesis of Wiberg’s Tetrasilatetrahedrane (tBu3Si)4Si4 by a One-Pot Procedure

Frank Meyer-Wegner, Stefan Scholz, Inge Snger, Frauke Schdel, Michael Bolte, Matthias Wagner and Hans-Wolfram Lerner
Publication Date (Web): October 23, 2009 (Note)
DOI: 10.1021/om900763y

October 21, 2009

Coordination, Agostic Stabilization, and C−H Bond Activation of N-Alkyl Heterocyclic Carbenes by Coordinatively Unsaturated Ruthenium Hydride Chloride Complexes

Suzanne Burling, Elena Mas-Marz, Jos E. V. Valpuesta, Mary F. Mahon and Michael K. Whittlesey
Publication Date (Web): October 21, 2009 (Article)
DOI: 10.1021/om9007532

October 6, 2009

Heteroleptic [M(CH2C6H5)2(I)(THF)3] Complexes (M = Y or Er): Remarkably Stable Precursors to Yttrium and Erbium T-Shaped Carbenes

David P. Mills, Ashley J. Wooles, Jonathan McMaster, William Lewis, Alexander J. Blake and Stephen T. Liddle
Publication Date (Web): October 6, 2009 (Article)
DOI: 10.1021/om9007949
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