Articles ASAP (As Soon As Publishable)

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February 9, 2010

Intramolecular C(sp2)−H Bond Activation in 6,6′-Dimethoxy-2,2′-Bipyridine with Gold(III). Crystal and Molecular Structure of the First N′,C(3) “Rollover” Cycloaurated Derivative

Publication Date (Web): February 9, 2010 (Communication)
DOI: 10.1021/om1000474

Phenoxaphosphine-Based Diphosphine Ligands. Synthesis and Application in the Hydroformylation Reaction

Publication Date (Web): February 9, 2010 (Article)
DOI: 10.1021/om901041r

DFT Study on Activation of Carbon Dioxide by Dimethytin Dimethoxide for Synthesis of Dimethyl Carbonate

Publication Date (Web): February 9, 2010 (Article)
DOI: 10.1021/om901094z

Probing the Mechanism of Aldehyde Addition to a Disilene and Two Silenes: Solvent Effects

Publication Date (Web): February 9, 2010 (Note)
DOI: 10.1021/om900673n

Cationic Organomagnesium Complexes as Highly Active Initiators for the Ring-Opening Polymerization of ε-Caprolactone

Publication Date (Web): February 9, 2010 (Article)
DOI: 10.1021/om900669y

February 8, 2010

Reactions of Aromatic N-Heterocycles with Yttrium and Lutetium Benzyl Complexes Supported by a Pyridine-Diamide Ligand

Publication Date (Web): February 8, 2010 (Article)
DOI: 10.1021/om901052e

Synthesis and Properties of Ferrocenyl Allenylidene Complexes: X-ray Structure of [Ru(C═C═CHFc)(PPh3)25-C5H5)][PF6]·CH2Cl2

Publication Date (Web): February 8, 2010 (Article)
DOI: 10.1021/om9010214

Metal-Free Frustrated Lewis Pair Catalyzed 1,4-Hydrogenation of Conjugated Metallocene Dienamines

Publication Date (Web): February 8, 2010 (Communication)
DOI: 10.1021/om900963p

February 5, 2010

Neutral Pentacoordinate Group 14 Compounds with β-Diketonato ligands

Publication Date (Web): February 5, 2010 (Article)
DOI: 10.1021/om900779s

February 4, 2010

Spectroscopic Properties and Electronic Structure of the Cycloheptatrienyl Molybdenum Alkynyl Complexes [Mo(C≡CR)(Ph2PCH2CH2PPh2)(η-C7H7)]n+ (n = 0 or 1; R = But, Fc, CO2Me, or C6H4-4-X, X = NH2, OMe, Me, H, CHO, CO2Me)

Publication Date (Web): February 4, 2010 (Article)
DOI: 10.1021/om901074b

Well-Defined N-Heterocyclic Carbene Based Ruthenium Catalysts for Direct Amide Synthesis from Alcohols and Amines

Publication Date (Web): February 4, 2010 (Article)
DOI: 10.1021/om901020h

Ferrous and Cobaltous Chlorides Bearing 2,8-Bis(imino)quinolines: Highly Active Catalysts for Ethylene Polymerization at High Temperature

Publication Date (Web): February 4, 2010 (Article)
DOI: 10.1021/om9010142

Formation of Phosphaalkyne Trimers: A Mechanistic Study

Publication Date (Web): February 4, 2010 (Article)
DOI: 10.1021/om900812s

Fragmentation Pathways of [MX2(CO)2(dcbpy)] (M = Ru, Os; X = Cl, Br, I; dcbpy = 2,2′-bipyridine-4,4′-dicarboxylic acid) Complexes

Publication Date (Web): February 4, 2010 (Article)
DOI: 10.1021/om900661t

Carbon−Carbon Bond Formation Involving a Vinylidene Ligand and Ferrocenyl Substituent in Cationic Ruthenium Complexes

Publication Date (Web): February 4, 2010 (Article)
DOI: 10.1021/om900775r

February 3, 2010

Isolation of Tetranuclear Organoantimony Oxo Clusters and Hexa-decanuclear Polyoxostibonates

Publication Date (Web): February 3, 2010 (Article)

Reactivity of [Fe2(CO)6(μ-S2)] toward a Base-Containing Diphosphine (Ph2PCH2)2NCH3: Formation of Diiron Carbonyl Compounds Having Polydentate Heterofunctionalized Phosphine (PNS = Ph2PCH2N(CH3)CH2S) and Bidentate Thiophosphinito (Ph2PS = PS) Bridges

Publication Date (Web): February 3, 2010 (Article)
DOI: 10.1021/om9011054

February 2, 2010

February 1, 2010

Synthesis and Reactivities of Guanidinate Dianion Complexes of Heterobimetallic Lanthanide−Lithium Cp2Ln[(CyN)2CNPh]Li(THF)3

Publication Date (Web): February 1, 2010 (Article)
DOI: 10.1021/om9010615

On the Nature of the Formation of [(η5-Ind)Ru(CO)2H]: Evidence of a Water-Gas Shift Reaction Mechanism via Triethylamine Reduction

Publication Date (Web): February 1, 2010 (Communication)
DOI: 10.1021/om9010774

Formation of Methylmagnesium or Coordinated Ylide? Competition between Decarboxylation of Acetate and Betaine Ligands in [CH3CO2MgO2CCH2X(CH3)2]+ (where X = NCH3 and S)

Publication Date (Web): February 1, 2010 (Article)
DOI: 10.1021/om901050s

Dinuclear Allylpalladium Complexes of C2-Symmetric Pyrazolate-Bridged Bis(oxazoline) Ligands (pyrbox's): Structures, Dynamic Behavior, and Application in Asymmetric Allylic Alkylation

Publication Date (Web): February 1, 2010 (Article)
DOI: 10.1021/om900835f

Cationic Iridium(III) Complexes with Tunable Emission Color as Phosphorescent Dyes for Live Cell Imaging

Publication Date (Web): February 1, 2010 (Article)
DOI: 10.1021/om900691r

January 29, 2010

Unexpected Synthesis of Oligomeric (Dimethylsilyl)-Bridged Ferrocenes from the Desilylative Coupling of Tertiary 1,1′-Bis(dimethylsilyl)ferrocene

Publication Date (Web): January 29, 2010 (Note)
DOI: 10.1021/om100041k

January 28, 2010

Bis(methimazolyl)silyl Complexes of Ruthenium

Publication Date (Web): January 28, 2010 (Article)
DOI: 10.1021/om901067t

Ground-State Electronic Asymmetry in Cp*W(NO)(η1-isonitrile)2 Complexes

Publication Date (Web): January 28, 2010 (Article)
DOI: 10.1021/om901018n

Synthesis of 2,5-Difunctional Phosphaferrocenes

Publication Date (Web): January 28, 2010 (Note)
DOI: 10.1021/om9010164

Synthesis and Preliminary Cytotoxicity Studies of Achiral Indolyl-Substituted Titanocenes

Publication Date (Web): January 28, 2010 (Article)
DOI: 10.1021/om901031m

Palladium-Catalyzed C−H Activation/C−N Bond Formation Reactions: DFT Study of Reaction Mechanisms and Reactive Intermediates

Publication Date (Web): January 28, 2010 (Article)
DOI: 10.1021/om900895t

Syntheses, Characterization, and the Ethylene (Co-)Polymerization Screening of 2-Benzimidazolyl-N-phenylquinoline-8-carboxamide Half-Titanocene Chlorides

Publication Date (Web): January 28, 2010 (Article)
DOI: 10.1021/om9010033

January 26, 2010

DFT Studies on the Carboxylation of Arylboronate Esters with CO2 Catalyzed by Copper(I) Complexes

Publication Date (Web): January 26, 2010 (Article)
DOI: 10.1021/om901047e

Ring-Expanded N-Heterocyclic Carbene Complexes of Ruthenium

Publication Date (Web): January 26, 2010 (Article)
DOI: 10.1021/om901044u

Benzene C−H Bond Activation in Carboxylic Acids Catalyzed by O-Donor Iridium(III) Complexes: An Experimental and Density Functional Study

Publication Date (Web): January 26, 2010 (Article)
DOI: 10.1021/om900036j

Synthesis and Structure of a Heavier Congener of Biphenyl: 1,1′-Disila-4,4′-biphenyl

Publication Date (Web): January 26, 2010 (Communication)
DOI: 10.1021/om901095w

Synthesis and Properties of Sterically Crowded Triarylphosphines Bearing Naphthoquinone Moieties

Publication Date (Web): January 26, 2010 (Article)
DOI: 10.1021/om900526m

January 25, 2010

Bis(NHC)-Palladium(II) Complex-Catalyzed Dioxygenation of Alkenes

Publication Date (Web): January 25, 2010 (Article)
DOI: 10.1021/om900975a

Reactions of [Cp*RuCl]4 and [(p-cymene)RuCl2]2 with the Tridentate Ligand [Ph(pz)B(μ-O)(μ-pz)B(pz)Ph]

Publication Date (Web): January 25, 2010 (Article)
DOI: 10.1021/om901022d

The Phosphorus Version of the Oxaspiropentene−Cyclobutenone Rearrangement

Publication Date (Web): January 25, 2010 (Note)
DOI: 10.1021/om900983k

Theoretical Determination of the Structural, Bonding, and Magnetoresponsive Properties of Square-Planar Ligand-Protected Noble Metal (Cu, Ag, Au) Clusters

Publication Date (Web): January 25, 2010 (Article)
DOI: 10.1021/om9009137

Three-Coordinate N-Heterocyclic Carbene Nickel Nitrosyl Complexes

Publication Date (Web): January 25, 2010 (Communication)
DOI: 10.1021/om900706z

January 22, 2010

Insertion Reactivity of CO2, PhNCO, Me3CC≡N, and Me3CN≡C with the Uranium−Alkynyl Bonds in (C5Me5)2U(C≡CPh)2

Publication Date (Web): January 22, 2010 (Article)
DOI: 10.1021/om901006t

January 21, 2010

Isolation and Characterization of New Mono- and Polynuclear Complexes Formed in the Thermal Reaction of Ru3(CO)12 with 1-(4-Tolyl)-3-phenylaminoprop-2-en-1-one

Publication Date (Web): January 21, 2010 (Article)
DOI: 10.1021/om901109q

Quantum-Chemical Study of Neutral Lewis Base Catalyzed Allylation of Aldehydes with Allyltrichlorosilanes

Publication Date (Web): January 21, 2010 (Article)
DOI: 10.1021/om901086q

Single and Double Electrophilic Addition Reactions to the Aniline Ring Promoted by a Tungsten π-Base

Publication Date (Web): January 21, 2010 (Communication)
DOI: 10.1021/om901048x

Synthesis and Characterization of Magnesium and Aluminum Bis(phosphoranyl)methanediide Complexes

Publication Date (Web): January 21, 2010 (Article)
DOI: 10.1021/om900985f

Ruthenium Olefin Metathesis Catalysts with N-Heterocyclic Carbene Ligands Bearing N-Naphthyl Side Chains

Publication Date (Web): January 21, 2010 (Article)
DOI: 10.1021/om9009697

Reactive Sigma-Aryliron Complexes or Iron-Promoted Coupling of Two Phenyl Anions to One Bis(cyclohexadienylidene) Ligand: Synthesis, Structure, Mass Spectrometry, and DFT Calculations

Publication Date (Web): January 21, 2010 (Article)
DOI: 10.1021/om900870j

January 19, 2010

Photoelectron Spectra of Phosphine Analogue Complexes of Co(CO)3NO and CpMn(CO)3

Publication Date (Web): January 19, 2010 (Article)
DOI: 10.1021/om900351y

Formation of Silicon−Carbon Bonds by Photochemical Irradiation of (η5-C5H5)Fe(CO)2SiR3 and (η5-C5H5)Fe(CO)2Me to Obtain R3SiMe

Publication Date (Web): January 19, 2010 (Article)
DOI: 10.1021/om901114q

Mononuclear and Mixed-Metal Dimethyltin Pacman Complexes of a Schiff-Base Pyrrole Macrocycle

Publication Date (Web): January 19, 2010 (Communication)
DOI: 10.1021/om901081h

Unusual [3+1] Cycloaddition of a Stable Silylene with a 2,3-Diazabuta-1,3-diene versus [4+1] Cycloaddition toward a Buta-1,3-diene

Publication Date (Web): January 19, 2010 (Article)
DOI: 10.1021/om901034w

Dicationic Alkylidene−, Olefin−, and Alkoxyalkenylcarbene−Osmium Complexes Stabilized by a NHC Ligand

Publication Date (Web): January 19, 2010 (Article)
DOI: 10.1021/om900949j

Investigation of Molybdenum Tetracarbonyl Complexes As Precursors to MoVI Catalysts for the Epoxidation of Olefins

Publication Date (Web): January 19, 2010 (Article)
DOI: 10.1021/om900948r

January 15, 2010

Multiple C−H Bond Activation of Phenyl-Substituted Pyrimidines and Triazines Promoted by an Osmium Polyhydride: Formation of Osmapolycycles with Three, Five, and Eight Fused Rings

Publication Date (Web): January 15, 2010 (Article)
DOI: 10.1021/om901030q

Dehydrogenative Formation and Reactivity of the Unsaturated Benzylidyne-Bridged Complex [Mo2Cp2(μ-CPh)(μ-PCy2)(μ-CO)]: C−C and C−P Coupling Reactions

Publication Date (Web): January 15, 2010 (Communication)
DOI: 10.1021/om901053x

Catalytic Ionic Hydrogenation of Ketones by {[Cp*Ru(CO)2]2(μ-H)}+

Publication Date (Web): January 15, 2010 (Note)
DOI: 10.1021/om901005k

Nitrogen Acyclic Gold(I) Carbenes: Excellent and Easily Accessible Catalysts in Reactions of 1,6-Enynes

Publication Date (Web): January 15, 2010 (Article)
DOI: 10.1021/om901026m

Controlled Synthesis of Dinuclear Acetylide-Bridged Ruthenium Complexes

Publication Date (Web): January 15, 2010 (Article)
DOI: 10.1021/om901019y

Heterometallic Derivatives of the Unsaturated Methyl-Bridged Complex [Mo25-C5H5)2(μ-CH3)(μ-PCy2)(CO)2]. Photochemical Generation of Methylidyne-Bridged Clusters

Publication Date (Web): January 15, 2010 (Article)
DOI: 10.1021/om900961u

Oxidation of Organometallic Platinum and Palladium Complexes Obtained from C−H Activation

Publication Date (Web): January 15, 2010 (Article)
DOI: 10.1021/om900678z

Syntheses of Bimetallic Zwitterionic Complexes Containing Stereogenic Bifunctionalized Phosphine through Stepwise Insertion and Hydration Reactions

Publication Date (Web): January 15, 2010 (Article)
DOI: 10.1021/om900958p

Synthesis, Structure, and Reactivity of Group 14 Bis(thiophosphinoyl) Metal Complexes

Publication Date (Web): January 15, 2010 (Article)
DOI: 10.1021/om9008923

Periodic and Molecular Modeling Study of Donor−Acceptor Interactions in (dbbpy)Pt(tdt)·TENF and [Pt(dbbpy)(tdt)]2·TENF

Publication Date (Web): January 15, 2010 (Article)
DOI: 10.1021/om900676m

Functional Group Chemistry at the Group 4 Bent Metallocene Framework: [2+2] Cycloaddition of the Parent Bis(vinyl-Cp/vinyl-Ind)ZrCl2 Systems

Publication Date (Web): January 15, 2010 (Article)
DOI: 10.1021/om900939v

January 14, 2010

Coupling of Aromatic N-Heterocycles Mediated by Group 3 Complexes

Publication Date (Web): January 14, 2010 (Article)
DOI: 10.1021/om900943m

1,1-Diboration of Isocyanides with [2]Borametalloarenophanes

Publication Date (Web): January 14, 2010 (Article)
DOI: 10.1021/om9009813

Diamido-Ether Uranium(IV) Alkyl Complexes as Single-Component Ethylene Polymerization Catalysts

Publication Date (Web): January 14, 2010 (Article)
DOI: 10.1021/om900546p

January 8, 2010

DFT Study on the Mechanism of Amides to Aldehydes Using Cp2Zr(H)Cl

Publication Date (Web): January 8, 2010 (Addition/Correction)
DOI: 10.1021/om901118w

December 31, 2009

New Bimetallic Reactivity in Pt2II,II/Pt2IV,IV Transformation Mediated by a Benzene Ring

Publication Date (Web): December 31, 2009 (Article)
DOI: 10.1021/om901046p
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