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Control of Strobilurin Fungicides in Wheat Using Direct Analysis in Real Time Accurate Time-of-Flight and Desorption Electrospray Ionization Linear Ion Trap Mass Spectrometry

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    Control of Strobilurin Fungicides in Wheat Using Direct Analysis in Real Time Accurate Time-of-Flight and Desorption Electrospray Ionization Linear Ion Trap Mass Spectrometry
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    Department of Food Chemistry and Analysis, Institute of Chemical Technology Prague, Technická 5, 6 Prague 16628, Czech Republic, RIKILT Institute of Food Safety, P.O. Box 230, 6700 AE Wageningen, The Netherlands, Central Science Laboratory, Sand Hutton, York, U.K. YO41 1LZ, and Wageningen University, Laboratory of Organic Chemistry, Dreijenplein 8, 6703 HB Wageningen, The Netherlands
    * To whom correspondence should be addressed. E-mail: [email protected]
    †Institute of Chemical Technology Prague.
    ‡RIKILT Institute of Food Safety.
    §Central Science Laboratory.
    ∥Wageningen University.
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    Analytical Chemistry

    Cite this: Anal. Chem. 2008, 80, 24, 9567–9575
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    https://doi.org/10.1021/ac8018137
    Published November 13, 2008
    Copyright © 2008 American Chemical Society
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    Abstract

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    Ambient mass spectrometry has been used for the analysis of strobilurin residues in wheat. The use of this novel, challenging technique, employing a direct analysis in a real time (DART) ion-source coupled with a time-of-flight mass spectrometer (TOF MS) and a desorption electrospray ionization (DESI) source coupled with a linear ion trap tandem MS (LIT MSn), permitted a direct screen of the occurrence of target fungicides in treated grains in less than 1 min. For quantification purpose by DART-TOF MS, an ethyl acetate extract had to be prepared. With the use of a prochloraz as an internal standard, the performance characteristics obtained by repeated analyses of extract, spiked at 50 μg kg−1 with six strobilurins (azoxystrobin, picoxystrobin, dimoxystrobin, kresoxim-methyl, pyraclostrobin, and trifloxystrobin), were in the following range: recoveries 78−92%, repeatability (RSD) 8−15%, linearity (R2) 0.9900−0.9978. The analysis of wheat with incurred strobilurin residues demonstrated good trueness of data generated by the DART-TOF MS method; the results were in a good agreement with those obtained by the conventional approach, i.e., by the QuEChERS sample handling procedure followed by identification/quantification employing high-performance liquid chromatography coupled with tandem mass spectrometry (LC−MS/MS). Tandem mass spectrometry using DESI-LIT MSn provided a sufficient number of product ions for confirmation of the identity of azoxystrobin and pyraclostrobin in incurred wheat samples.

    Copyright © 2008 American Chemical Society

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    Analytical Chemistry

    Cite this: Anal. Chem. 2008, 80, 24, 9567–9575
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    https://doi.org/10.1021/ac8018137
    Published November 13, 2008
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