Interpenetrated Luminescent Metal–Organic Frameworks based on 1H-Indazole-5-carboxylic AcidClick to copy article linkArticle link copied!
- Antonio A. Garcı́a-ValdiviaAntonio A. Garcı́a-ValdiviaDepartamento de Quı́mica Inorgánica, Universidad de Granada, 18071, Granada, SpainMore by Antonio A. Garcı́a-Valdivia
- Manuel Pérez-MendozaManuel Pérez-MendozaDepartamento de Quı́mica Inorgánica, Universidad de Granada, 18071, Granada, SpainMore by Manuel Pérez-Mendoza
- Duane Choquesillo-LazarteDuane Choquesillo-LazarteLaboratorio de Estudios Cristalográficos, IACT (CSIC-UGR), Av. De las Palmeras 4, 18100 Armilla, Granada, SpainMore by Duane Choquesillo-Lazarte
- Javier Cepeda*Javier Cepeda*E-mail: [email protected] (J.C.).Departamento de Quı́mica Aplicada, Facultad de Quı́mica, Universidad del Paı́s Vasco/Euskal Herriko Unibertsitatea (UPV/EHU), 20018, San Sebastián, SpainMore by Javier Cepeda
- Belén FernándezBelén FernándezInstitute of Parasitology and Biomedicine “Lopéz-Neyra”, CSIC, Av. Conocimiento s/n, 18600, Granada, SpainMore by Belén Fernández
- Manuel SoutoManuel SoutoInstituto de Ciencia Molecular (ICMol), Universitat de València, c/Catedrático José Beltrán, 2, 46980, Paterna, SpainCICECO -Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, PortugalMore by Manuel Souto
- Marcos González-TejeroMarcos González-TejeroDepartamento de Quı́mica Inorgánica, Universidad de Granada, 18071, Granada, SpainMore by Marcos González-Tejero
- Jose A. Garcı́aJose A. Garcı́aDepartamento de Fı́sica Aplicada II, Facultad de Ciencia y Tecnologı́a, University of Basque Country (UPV/EHU), 48940, Leioa, SpainMore by Jose A. Garcı́a
- Guillermo Mı́nguez Espallargas*Guillermo Mı́nguez Espallargas*E-mail:[email protected] (G.M.E.).Instituto de Ciencia Molecular (ICMol), Universitat de València, c/Catedrático José Beltrán, 2, 46980, Paterna, SpainMore by Guillermo Mı́nguez Espallargas
- Antonio Rodrı́guez-Diéguez*Antonio Rodrı́guez-Diéguez*E-mail: [email protected] (A.R.D.).Departamento de Quı́mica Inorgánica, Universidad de Granada, 18071, Granada, SpainMore by Antonio Rodrı́guez-Diéguez
Abstract
Herein we report the formation and characterization of two novel Zn-based multifunctional metal–organic frameworks (MOFs) based on 1H-indazole-5-carboxylic acid and bipyridine-like linkers, synthesized by soft solvothermal routes. These materials possess isoreticular 2-fold interpenetrated three-dimensional structures that afford a flexible character and allow porosity modulation of the MOFs as confirmed by CO2 sorption measurements. Apart from this attractive structural feature, the MOFs exhibit fascinating luminescent properties involving both luminescence thermometry and long-lasting phosphorescence.
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