Large Pore Isoreticular Strontium-Organic Frameworks: Syntheses, Crystal Structures, and Thermal and Luminescent PropertiesClick to copy article linkArticle link copied!
- Afsaneh KhansariAfsaneh KhansariSchool of Chemistry and Biomolecular Science, Faculty of Science, Medicine and Health, University of Wollongong, Wollongong, New South Wales 2522, AustraliaMore by Afsaneh Khansari
- Shane G. TelferShane G. TelferMacDiarmid Institute of Advanced Materials and Nanotechnology, Institute of Fundamental Sciences, Massey University, Palmerston North 4442, New ZealandMore by Shane G. Telfer
- Christopher Richardson*Christopher Richardson*E-mail: [email protected]School of Chemistry and Biomolecular Science, Faculty of Science, Medicine and Health, University of Wollongong, Wollongong, New South Wales 2522, AustraliaMore by Christopher Richardson
Abstract
Two isoreticular and topologically unique metal–organic frameworks (MOFs) have been synthesized using Sr(NO3)2 and the organic linkers 2-nitro-[1,1′-biphenyl]-4,4′-dicarboxylic acid (H2bpdcNO2) and 2,2′-dinitro-[1,1′-biphenyl]-4,4′-dicarboxylic acid (H2bpdc(NO2)2). The structures of [Sr(bpdcNO2)2(DMF)2(H2O)2] (WUF-15; WUF = Wollongong University Framework) and [Sr4(bpdc(NO2)2)4(DMF)2(H2O)4·2DMF] (WUF-16) were determined by single crystal X-ray diffraction (SCXRD) and are composed of infinite strontium carboxylate SBUs and contain large square (∼18 Å) and smaller triangular channels (∼9 Å) orientated parallel to each other and lined with nitro functional groups. An in situ ligand transformation of H2bpdc(NO2)2 to benzo[c]cinnoline-3,8-dicarboxylic acid (H2bc) and formation of a nonporous coordination polymer of formula [Sr(bc)(H2O)2] (WUF-17) with interesting photoluminescent properties was discovered. Independent synthesis of H2bc enabled the preparation of WUF-17 crystals suitable for SCXRD structure determination. Powder X-ray diffraction and thermal and elemental analyses support the structures of all complexes.
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