NanMTh6F30: A Large Family of Quaternary Thorium FluoridesClick to copy article linkArticle link copied!
- Vladislav V. KlepovVladislav V. KlepovDepartment of Chemistry and Biochemistry, University of South Carolina, 631 Sumter Street, Columbia, South Carolina 29208, United StatesMore by Vladislav V. Klepov
- Gregory MorrisonGregory MorrisonDepartment of Chemistry and Biochemistry, University of South Carolina, 631 Sumter Street, Columbia, South Carolina 29208, United StatesMore by Gregory Morrison
- Hans-Conrad zur Loye*Hans-Conrad zur Loye*E-mail for H.-C.z.L.: [email protected]Department of Chemistry and Biochemistry, University of South Carolina, 631 Sumter Street, Columbia, South Carolina 29208, United StatesMore by Hans-Conrad zur Loye
Abstract
Recently we reported the synthesis, crystal structures, and magnetic properties of compounds in the NanMU6F30 series, where n = 4, 3 and where M is a divalent or trivalent metal cation, respectively. In this article we advance our investigation of this structure type by expanding it to the thorium-containing compounds NanMTh6F30, where n = 3 in the case of MIII = Al, Sc, Ti, V, Cr, Fe, Ga, In, n = 4 when MII = Mg, Mn, Co, Ni, Cu, Zn, and n varies from 3.87 to 4.39 when the M site is partially occupied by a trivalent rare-earth element. Magnetic properties of the compounds containing magnetic ions M = Ti3+, V3+, Cr3+, Mn2+, Fe3+, Co2+, Ni2+, Cu2+ were studied to demonstrate that the substitution of Th(IV) for U(IV) prevents the magnetic ions from coupling magnetically and, therefore, they exhibit simple paramagnetic behavior.
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This article is cited by 8 publications.
- Travis K. Deason, Gregory Morrison, Amir Mofrad, Hunter B. Tisdale, Jake Amoroso, David DiPrete, Gary Was, Kai Sun, Theodore M. Besmann, Hans-Conrad zur Loye. Developing Waste Forms for Transuranic Elements: Quaternary Neptunium Fluorides of the Type NaxMNp6F30 (M = Ti, V, Cr, Mn, Fe, Co, Ni, Al, Ga). Journal of the American Chemical Society 2023, 145
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, 465-475. https://doi.org/10.1021/jacs.2c10669
- Cory J. Windorff, Alexander T. Chemey, Joseph M. Sperling, Bonnie E. Klamm, Thomas E. Albrecht-Schmitt. Examination of Molten Salt Reactor Relevant Elements Using Hydrothermal Synthesis. Inorganic Chemistry 2020, 59
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, 4176-4180. https://doi.org/10.1021/acs.inorgchem.0c00360
- Gyanendra B. Ayer, Vladislav V. Klepov, Mark D. Smith, Hans-Conrad zur Loye. Mild Hydrothermal Synthesis of the Complex Hafnium-Containing Fluorides Cs2[M(H2O)6][Hf2F12] (M = Ni, Co, Zn), CuHfF6(H2O)4, and Cs2Hf3Mn3F20 Based on HfF7 and HfF6 Coordination Polyhedra. Inorganic Chemistry 2019, 58
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- Joseph W. Kolis, Colin D. McMillen. High temperature hydrothermal synthesis of inorganic compounds. 2023, 628-657. https://doi.org/10.1016/B978-0-12-823144-9.00088-1
- Kristen A. Pace, Vladislav V. Klepov, Travis K. Deason, Mark D. Smith, Gyanendra B. Ayer, David P. Diprete, Jake W. Amoroso, Hans‐Conrad zur Loye. Expansion of the Na
3
M
III
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Series: Incorporation of Plutonium into a Highly Robust and Stable Framework. Chemistry – A European Journal 2020, 26
(57)
, 12941-12944. https://doi.org/10.1002/chem.202002774
- Navindra Keerthisinghe, Vladislav V. Klepov, Eric Zhang, Mark D. Smith, Shani Egodawatte, Stephen H. Foulger, Hans-Conrad zur Loye. Hydrothermal synthesis and properties of MMF5(H2O)7 (M = Co2+ and Ni2+, M = Mn3+, Ga3+, and In3+). Solid State Sciences 2020, 108 , 106374. https://doi.org/10.1016/j.solidstatesciences.2020.106374
- Benjamin Scheibe, Juliane März, Moritz Schmidt, Thorsten Stumpf, Florian Kraus. Synthesis and Crystal Structures of Transition Metal(II) Fluoridometallate(IV) Hydrates of Neptunium and Plutonium:
A
II
M
IV
F
6
·3H
2
O (
A
II
= Mn, Zn;
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IV
= Np, Pu). European Journal of Inorganic Chemistry 2020, 2020
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, 2279-2284. https://doi.org/10.1002/ejic.202000298
- Gyanendra B. Ayer, Vladislav V. Klepov, Kristen A. Pace, Hans-Conrad zur Loye. Quaternary cerium(
iv
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sheets and Ce
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frameworks. Dalton Transactions 2020, 49
(18)
, 5898-5905. https://doi.org/10.1039/D0DT00616E
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