Toward a Rational Design of 3d-4f Heterometallic Coordination Polymers based on Mixed Valence Copper CentersClick to copy article linkArticle link copied!
- Carlos CruzCarlos CruzFacultad de Ciencias Exactas, Departamento de Ciencias Químicas, Universidad Andres Bello, Santiago, ChileCEDENNA, Santiago, ChileMore by Carlos Cruz
- Francisco RubioFrancisco RubioFacultad de Ciencias Exactas, Departamento de Ciencias Químicas, Universidad Andres Bello, Santiago, ChileCEDENNA, Santiago, ChileMore by Francisco Rubio
- Diego Venegas-YazigiDiego Venegas-YazigiCEDENNA, Santiago, ChileFacultad de Quı́mica y Biologı́a, Departamento de Quı́mica de los Materiales, Universidad de Santiago de Chile, Santiago, ChileMore by Diego Venegas-Yazigi
- Nathalie AudebrandNathalie AudebrandUniv de Rennes, ENSCR, INSA, CNRS, ISCR (Institut des Sciences Chimiques de Rennes) - UMR 6226, F-35000 Rennes, FranceMore by Nathalie Audebrand
- Christophe CalersChristophe CalersUniv de Rennes, ENSCR, INSA, CNRS, ISCR (Institut des Sciences Chimiques de Rennes) - UMR 6226, F-35000 Rennes, FranceMore by Christophe Calers
- Evgenia SpodineEvgenia SpodineCEDENNA, Santiago, ChileFacultad de Ciencias Químicas y Farmacéuticas, Departamento de Química Inorgánica y Analítica, Universidad de Chile, Santiago, ChileMore by Evgenia Spodine
- Verónica Paredes-García*Verónica Paredes-García*E-mail: [email protected]. Phone: +56-2-2661 5756.Facultad de Ciencias Exactas, Departamento de Ciencias Químicas, Universidad Andres Bello, Santiago, ChileCEDENNA, Santiago, ChileMore by Verónica Paredes-García
Abstract
In the present work, we report two new CuI/CuII–GdIII mixed valence heterometallic coordination polymers (HCP), [Gd(H2O)4CuIICuI(IDC)2] (1) and [Gd2(H2O)2(C2O4)2CuII(IDC)2CuI2(4,4′-bipy)]·4.5H2O (2) obtained under solvothermal synthesis using 1H-imidazole-4,5-dicarboxylic acid (H3IDC) as a principal N,O-bifunctional organic linker. In both compounds, the stabilization of the CuI cations is achieved only by the coordination of N-atoms belonging to the organic ligands. While 1 presents a two-dimensional honeycomb network obtained by the coordination of single organic linker (IDC3–), 2 contains three different organic ligands (IDC3–, C2O42–, and 4,4′-bipy), which allow the construction of a three-dimensional network. From a magnetic point of view, 1 and 2 behave as simple paramagnets at high temperature, presenting ferromagnetic interactions below 50 K, and a positive magnetic coupling constant of J = 0.60 cm–1 and J = 0.22 cm–1 was obtained for 1 and 2 respectively. To the best our knowledge, 1 and 2 correspond to the second and third reported examples containing a CuI/CuII mixed valence system assembled with GdIII cations, thus enriching the chemistry involved in 3d-4f metal–organic materials.
Cited By
Smart citations by scite.ai include citation statements extracted from the full text of the citing article. The number of the statements may be higher than the number of citations provided by ACS Publications if one paper cites another multiple times or lower if scite has not yet processed some of the citing articles.
This article is cited by 8 publications.
- Dong-Nan Yu, Zi-Xuan Yao, Fahime Bigdeli, Xue-Mei Gao, Xun Cheng, Jing-Zhe Li, Jing-Wen Zhang, Wei Wang, Zong-Jie Guan, Yongfeng Bu, Kuan-Guan Liu, Ali Morsali. Synthesis and Study of Photothermal Properties of a Mixed-Valence Nanocluster CuI/CuII with Strong near-Infrared Optical Absorption Supported by 4-tert-Butylcalix[4]arene Ligand. Inorganic Chemistry 2023, 62
(1)
, 401-407. https://doi.org/10.1021/acs.inorgchem.2c03501
- Gouri Chakraborty, In-Hyeok Park, Raghavender Medishetty, Jagadese J. Vittal. Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications. Chemical Reviews 2021, 121
(7)
, 3751-3891. https://doi.org/10.1021/acs.chemrev.0c01049
- Shu-Fang Zheng, Tian-Biao Qu, Jin-Sheng Zhang, Ju-Wen Zhang, Dong-Mei Ren, Bin-Qiu Liu. Syntheses and properties of seven 3,4-dichlorobenzoate-based zinc-rare earth heterometallic complexes containing a field-induced Zn(II)-Dy(III)-Dy(III)-Zn(II) single-molecule magnet. Journal of Molecular Structure 2024, 1317 , 139156. https://doi.org/10.1016/j.molstruc.2024.139156
- Yuyu Guo, Shen Zhang. Two dinuclear Ln2 compounds: Synthesis, structures, magnetism and luminescence properties. Polyhedron 2024, 255 , 116967. https://doi.org/10.1016/j.poly.2024.116967
- Yury A. Belousov, Andrei A. Drozdov, Ilya V. Taydakov, Fabio Marchetti, Riccardo Pettinari, Claudio Pettinari. Lanthanide azolecarboxylate compounds: Structure, luminescent properties and applications. Coordination Chemistry Reviews 2021, 445 , 214084. https://doi.org/10.1016/j.ccr.2021.214084
- Yanfeng Cui, Yuhan Ding, Steven Eduardo Vilcacundo Molina, Yahong Li. A mixed-valence CuII/CuI coordination polymer based on bridged thiocyanate and in situ formed di(N-heterocyclic) sulfide: Synthesis, structure, and magnetic properties. Journal of Molecular Structure 2021, 1241 , 130623. https://doi.org/10.1016/j.molstruc.2021.130623
- Li-Xin You, Sen-Yue Cao, Yang Guo, Shu-Ju Wang, Gang Xiong, Ileana Dragutan, Valerian Dragutan, Fu Ding, Ya-Guang Sun. Structural insights into new luminescent 2D lanthanide coordination polymers using an N, N′-disubstituted benzimidazole zwitterion. Influence of the ligand. Inorganica Chimica Acta 2021, 525 , 120441. https://doi.org/10.1016/j.ica.2021.120441
- Shen Zhang, Wen-Min Wang, Yan Guo, Chao-Ying Li, Yu-Yu Guo, Yin-Ling Hou. A novel heterometallic [GdIII2MnII2] cluster displaying larger cryogenic magnetocaloric effect. Polyhedron 2020, 191 , 114808. https://doi.org/10.1016/j.poly.2020.114808
Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.
Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.
The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.