ACS Publications. Most Trusted. Most Cited. Most Read
My Activity
CONTENT TYPES

Coordination-Driven Self-Assembly in Polymer–Inorganic Hybrid Materials

Cite this: Chem. Mater. 2020, 32, 9, 3680–3700
Publication Date (Web):April 22, 2020
https://doi.org/10.1021/acs.chemmater.0c00851
Copyright © 2020 American Chemical Society

    Article Views

    4701

    Altmetric

    -

    Citations

    LEARN ABOUT THESE METRICS
    Other access options

    Abstract

    Abstract Image

    As the library of metal–organic frameworks (MOFs) and metal–organic cages (MOCs) continues to grow, their porous, ordered structures are increasingly being applied toward diverse applications that include separations, energy production and storage, and biomedicine. One outstanding challenge facing the adoption of these materials is their limited processability owing to their crystalline or microcrystalline nature. In this perspective, we highlight advances in the hybridization of MOFs or MOCs with organic polymers to form materials with both high functionality and processability. Although this is a relatively new area of research, there are a variety of examples that show how these hybrid materials can be designed to exhibit promising properties derived from both their polymer and inorganic components. We organize our discussion around simple mixed composites and advanced materials that draw upon covalent interactions between polymers and MOF/MOCs. We invoke both pioneering examples from the literature as well as our own work using soluble MOCs and our strategy to use postsynthetic ligand substitution to make high quality hybrid materials.

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.

    Cited By

    This article is cited by 69 publications.

    1. Dino Camdzic, Heshali K. Welgama, Matthew R. Crawley, Anish Avasthi, Timothy R. Cook, Diana S. Aga. Rapid Capture of Per- and Polyfluoroalkyl Substances Using a Self-Assembling Zirconium-Based Metal-Organic Cage. ACS Applied Engineering Materials 2024, 2 (1) , 87-95. https://doi.org/10.1021/acsaenm.3c00592
    2. Fatemeh Keshavarz. Dissecting the Water Uptake Behavior of Metal–Organic Frameworks Using Their Isolated Linkers and Metal Nodes. Chemistry of Materials 2024, 36 (1) , 439-449. https://doi.org/10.1021/acs.chemmater.3c02383
    3. Sarah Bernhardt, Tadahiro Yokosawa, Erdmann Spiecker, Franziska Gröhn. Polythiophene as a Double-Electrostatic Template for Zinc Oxide and Gold: Multicomponent Nano-Objects for Enhanced Photocatalysis. Langmuir 2023, 39 (30) , 10312-10320. https://doi.org/10.1021/acs.langmuir.3c00123
    4. Lele Lei, Jiyun Zhang, Keyu Zha, Sirou Tang, Jiefeng Hai, Dayong Fan, Xueming Li, Ming Li, Yongping Liu, Zhenhuan Lu. Hierarchical Self-Assembly of Organic–Inorganic Hybrid Nanosheets to Construct Tubular Superstructures for Photocatalytic Degradation. ACS Applied Nano Materials 2023, 6 (7) , 6270-6278. https://doi.org/10.1021/acsanm.3c00638
    5. Nika Vrtovec, Sarah Jurjevec, Nataša Zabukovec Logar, Matjaž Mazaj, Sebastijan Kovačič. Metal Oxide-Derived MOF-74 Polymer Composites through Pickering Emulsion-Templating: Interfacial Recrystallization, Hierarchical Architectures, and CO2 Capture Performances. ACS Applied Materials & Interfaces 2023, 15 (14) , 18354-18361. https://doi.org/10.1021/acsami.3c01796
    6. Vincent J. Pastore, Meghan G. Sullivan, Heshali K. Welgama, Matthew R. Crawley, Alan E. Friedman, Clayton Rumsey, Martin Trebbin, Javid Rzayev, Timothy R. Cook. Clickable Norbornene-Based Zirconium Carboxylate Polyhedra. Chemistry of Materials 2023, 35 (4) , 1651-1658. https://doi.org/10.1021/acs.chemmater.2c03252
    7. Mostafa Ahmadi, Albert Poater, Sebastian Seiffert. Self-Sorting of Transient Polymer Networks by the Selective Formation of Heteroleptic Metal–Ligand Complexes. Macromolecules 2023, 56 (4) , 1390-1401. https://doi.org/10.1021/acs.macromol.2c02046
    8. Xin Han, Chenxing Guo, Chen Xu, Linlin Shi, Binghui Liu, Zhe Zhang, Qixia Bai, Bo Song, Fangfang Pan, Shuai Lu, Xinju Zhu, Heng Wang, Xin-Qi Hao, Mao-Ping Song, Xiaopeng Li. Water-Soluble Metallo-Supramolecular Nanoreactors for Mediating Visible-Light-Promoted Cross-Dehydrogenative Coupling Reactions. ACS Nano 2023, 17 (4) , 3723-3736. https://doi.org/10.1021/acsnano.2c10856
    9. Alexandra I. Zvyagina, Alexey E. Alexandrov, Alexey A. Averin, Ivan N. Senchikhin, Maxim R. Sokolov, Alexander A. Ezhov, Alexey R. Tameev, Maria A. Kalinina. One-Step Interfacial Integration of Graphene Oxide and Organic Chromophores into Multicomponent Nanohybrids with Photoelectric Properties. Langmuir 2022, 38 (49) , 15145-15155. https://doi.org/10.1021/acs.langmuir.2c02155
    10. Farzaneh Ghobakhloo, Davood Azarifar, Masoud Mohammadi, Hassan Keypour, Hamid Zeynali. Copper(II) Schiff-Base Complex Modified UiO-66-NH2(Zr) Metal–Organic Framework Catalysts for Knoevenagel Condensation–Michael Addition–Cyclization Reactions. Inorganic Chemistry 2022, 61 (12) , 4825-4841. https://doi.org/10.1021/acs.inorgchem.1c03284
    11. Matthew A. Pearson, Mircea Dincă, Jeremiah A. Johnson. Radical PolyMOFs: A Role for Ligand Dispersity in Enabling Crystallinity. Chemistry of Materials 2021, 33 (24) , 9508-9514. https://doi.org/10.1021/acs.chemmater.1c02411
    12. Yuan Liu, Linkun Cai, Litao Ma, Mu Li, Junsheng Yang, Kun Chen, Panchao Yin. Modulating Polymer Dynamics via Supramolecular Interaction with Ultrasmall Nanocages for Recyclable Gas Separation Membranes with Intrinsic Microporosity. Nano Letters 2021, 21 (21) , 9021-9029. https://doi.org/10.1021/acs.nanolett.1c02379
    13. My Do, Dylan Rogers, Werner Kaminsky, Dianne J. Xiao. Robust Synthetic Route toward Anisotropic Metal–Organic Cages with Tunable Surface Chemistry. Inorganic Chemistry 2021, 60 (11) , 7602-7606. https://doi.org/10.1021/acs.inorgchem.1c00466
    14. Salma Begum, Zahid Hassan, Stefan Bräse, Manuel Tsotsalas. Polymerization in MOF-Confined Nanospaces: Tailored Architectures, Functions, and Applications. Langmuir 2020, 36 (36) , 10657-10673. https://doi.org/10.1021/acs.langmuir.0c01832
    15. Ishani Pandya, Sugam Kumar, Vinod K. Aswal, Omar El Seoud, Mohammed A. Assiri, Naved Malek. Metal organic framework-based polymeric hydrogel: A promising drug delivery vehicle for the treatment of breast cancer. International Journal of Pharmaceutics 2024, 658 , 124206. https://doi.org/10.1016/j.ijpharm.2024.124206
    16. Yuhao Wang, Zhenyu Wang, Shiqi Wei, Sha Wu, Mengbin Wang, Guocan Yu, Peng Chen, Xiaowei Liu, Jiong Zhou. Efficient separation of xylene isomers by nonporous adaptive crystals of hybrid[3]arene in both vapor and liquid phases. Materials Chemistry Frontiers 2024, 8 (10) , 2273-2281. https://doi.org/10.1039/D3QM01231J
    17. Gaurav Verma, Sanjay Kumar, Elliott R. Slaughter, Harsh Vardhan, Thamraa M. Alshahrani, Zheng Niu, Wen‐Yang Gao, Lukasz Wojtas, Yu‐Sheng Chen, Shengqian Ma. Bifunctional Metal‐Organic Nanoballs Featuring Lewis Acidic and Basic Sites as a New Platform for One‐Pot Tandem Catalysis. ChemPlusChem 2024, 46 https://doi.org/10.1002/cplu.202400169
    18. Leila Ghasempour, Sakineh Asghari. Copper (II)‐azo sulfathiazole complex immobilized on UiO‐66‐NH 2 (MOF) as a catalyst for the one‐pot synthesis of spiroindole‐pyranopyrazoles. Applied Organometallic Chemistry 2024, 38 (5) https://doi.org/10.1002/aoc.7402
    19. Takeharu Haino, Natsumi Nitta. Supramolecular Synthesis of Star Polymers. ChemPlusChem 2024, 89 (5) https://doi.org/10.1002/cplu.202400014
    20. Chaolei Hu, Kay Severin. Nanogels with Metal‐Organic Cages as Functional Crosslinks. Angewandte Chemie International Edition 2024, 18 https://doi.org/10.1002/anie.202403834
    21. Chaolei Hu, Kay Severin. Nanogels with Metal‐Organic Cages as Functional Crosslinks. Angewandte Chemie 2024, https://doi.org/10.1002/ange.202403834
    22. Yueyao Liang, Caijiao Yu, Xueyuan Yang, Zhihua Qiao. Preparation of ultrathin and highly loaded MOF mixed matrix membranes with honeycomb-like structure via ordered array self-assembly. Chemical Engineering Journal 2024, 61 , 149749. https://doi.org/10.1016/j.cej.2024.149749
    23. Yu-Kang Teng, Qian Wu, Yao Sun, Chen Wang, Rui Zhang, Zhen-Zhong Lu. Mixed matrix membranes based on fluorescent coordination polymers for the detection of Cr 2 O 7 2− in water. CrystEngComm 2024, 8 https://doi.org/10.1039/D4CE00182F
    24. Soumya Dey, Medha Aggarwal, Debsena Chakraborty, Partha Sarathi Mukherjee. Uncovering tetrazoles as building blocks for constructing discrete and polymeric assemblies. Chemical Communications 2024, 121 https://doi.org/10.1039/D4CC01616E
    25. Feifan Lang, Jiandong Pang, Xian-He Bu. Stimuli-responsive coordination polymers toward next-generation smart materials and devices. eScience 2024, 42 , 100231. https://doi.org/10.1016/j.esci.2024.100231
    26. Dharmendra, Srikanta Moharana, Alekha Kumar Sutar, Tungabidya Maharana. Polythiophene, polypyrrole-NiO ternary hybrid nanocomposites: structural, morphological, dielectric and electrical properties. Journal of Chemical Sciences 2023, 135 (4) https://doi.org/10.1007/s12039-023-02236-4
    27. Kavya Adot Veetil, Asmaul Husna, Md. Homayun Kabir, Insu Jeong, Ook Choi, Iqubal Hossain, Tae-Hyun Kim. Developing Mixed Matrix Membranes with Good CO2 Separation Performance Based on PEG-Modified UiO-66 MOF and 6FDA-Durene Polyimide. Polymers 2023, 15 (22) , 4442. https://doi.org/10.3390/polym15224442
    28. Wojciech Drożdż, Artur Ciesielski, Artur R. Stefankiewicz. Dynamic Cages—Towards Nanostructured Smart Materials. Angewandte Chemie 2023, 135 (43) https://doi.org/10.1002/ange.202307552
    29. Wojciech Drożdż, Artur Ciesielski, Artur R. Stefankiewicz. Dynamic Cages—Towards Nanostructured Smart Materials. Angewandte Chemie International Edition 2023, 62 (43) https://doi.org/10.1002/anie.202307552
    30. Yuan Liu, Binghui Xue, Yuyan Lai, Linkun Cai, Kun Chen, Panchao Yin. Microscopic mechanism of gas transport in mixed matrix membranes of coordination nanocages. Journal of Membrane Science 2023, 683 , 121821. https://doi.org/10.1016/j.memsci.2023.121821
    31. Bo-yu Li, Jia-xiang Liu, Xuan-ting He, Shun Mao, Wen-quan Tao, Zhuo Li, Yue-xian Hong. Polyaniline-grafted Cu-MOFs via coordination-driven strategy constructs facilitated transport hybrid membrane for CO2 separation. Separation and Purification Technology 2023, 323 , 124486. https://doi.org/10.1016/j.seppur.2023.124486
    32. Jingxi Deng, Ruixue Bai, Jun Zhao, Guoquan Liu, Zhaoming Zhang, Wei You, Wei Yu, Xuzhou Yan. Insights into the Correlation of Cross‐linking Modes with Mechanical Properties for Dynamic Polymeric Networks. Angewandte Chemie International Edition 2023, 62 (37) https://doi.org/10.1002/anie.202309058
    33. Jingxi Deng, Ruixue Bai, Jun Zhao, Guoquan Liu, Zhaoming Zhang, Wei You, Wei Yu, Xuzhou Yan. Insights into the Correlation of Cross‐linking Modes with Mechanical Properties for Dynamic Polymeric Networks. Angewandte Chemie 2023, 135 (37) https://doi.org/10.1002/ange.202309058
    34. Asma H. Maneri, Shruti Suhas Varode, Ashakiran Maibam, Priyatosh Ranjan, Sailaja Krishnamurty, Krati Joshi. Quantum dot (Au n /Ag n , n = 3–8) capped single lipids: interactions and physicochemical properties. Physical Chemistry Chemical Physics 2023, 25 (33) , 22294-22303. https://doi.org/10.1039/D3CP01131C
    35. Ji-Ming Xi, Rui Zhu, Yu-Kang Teng, Qian Wu, Meng-Yuan Xu, Rui Zhang, Zhen-Zhong Lu, Ling Huang. Coordination polymers based on di-9,10-(pyridine-4-yl)-anthracene: selective adsorption of CO 2 and fluorescent properties. CrystEngComm 2023, 25 (22) , 3278-3283. https://doi.org/10.1039/D2CE01570F
    36. Matthew A. Pearson, Sachin Bhagchandani, Mircea Dincă, Jeremiah A. Johnson. Mixing ligands to enhance gas uptake in polyMOFs. Molecular Systems Design & Engineering 2023, 8 (5) , 591-597. https://doi.org/10.1039/D2ME00227B
    37. Qiaorong Tang, Lu Shi, Bing Yang, Wei Liu, Baoxin Li, Yan Jin. A biomineralized bi-functional hybrid nanoflower to effectively combat bacteria via a glucose-powered cascade catalytic reaction. Journal of Materials Chemistry B 2023, 11 (15) , 3413-3421. https://doi.org/10.1039/D2TB02704F
    38. Marzena Pander, Rodrigo Gil-San-Millan, Pedro Delgado, Cristina Perona-Bermejo, Urszula Kostrzewa, Karol Kaczkowski, Dominik J. Kubicki, Jorge A. R. Navarro, Wojciech Bury. MOF/polymer hybrids through in situ free radical polymerization in metal-organic frameworks. Materials Horizons 2023, 10 (4) , 1301-1308. https://doi.org/10.1039/D2MH01202B
    39. Ziqi Yang, Zhongjie Wu, Shing Bo Peh, Yunpan Ying, Hao Yang, Dan Zhao. Mixed-Matrix Membranes Containing Porous Materials for Gas Separation: From Metal–Organic Frameworks to Discrete Molecular Cages. Engineering 2023, 23 , 40-55. https://doi.org/10.1016/j.eng.2022.07.022
    40. Meghan G. Sullivan, Gregory E. Sokolow, Eric T. Jensen, Matthew R. Crawley, Samantha N. MacMillan, Timothy R. Cook. Altering the solubility of metal–organic polyhedra via pendant functionalization of Cp 3 Zr 3 O(OH) 3 nodes. Dalton Transactions 2023, 52 (2) , 338-346. https://doi.org/10.1039/D2DT03401H
    41. Farhad Ahmadijokani, Hossein Molavi, Addie Bahi, Roberto Fernández, Parvin Alaee, Siying Wu, Stefan Wuttke, Frank Ko, Mohammad Arjmand. Metal‐Organic Frameworks and Electrospinning: A Happy Marriage for Wastewater Treatment. Advanced Functional Materials 2022, 32 (51) https://doi.org/10.1002/adfm.202207723
    42. Renata Łyszczek, Dmytro Vlasyuk, Beata Podkościelna, Halina Głuchowska, Ryszard Piramidowicz, Anna Jusza. A Top-Down Approach and Thermal Characterization of Luminescent Hybrid BPA.DA-MMA@Ln2L3 Materials Based on Lanthanide(III) 1H-Pyrazole-3,5-Dicarboxylates. Materials 2022, 15 (24) , 8826. https://doi.org/10.3390/ma15248826
    43. Batoul Hosseinzadeh, Mostafa Ahmadi. Coordination geometry in metallo-supramolecular polymer networks. Coordination Chemistry Reviews 2022, 471 , 214733. https://doi.org/10.1016/j.ccr.2022.214733
    44. Matthew L. Schneider, Jonathan A. Campbell, Ashley D. Slattery, Witold M. Bloch. Polymer networks of imine-crosslinked metal–organic cages: tuneable viscoelasticity and iodine adsorption. Chemical Communications 2022, 58 (86) , 12122-12125. https://doi.org/10.1039/D2CC04969D
    45. Jinjin Liu, Jiamin Li, Shan Qiao, Zhifang Wang, Penghui Zhang, Xiangqian Fan, Peng Cheng, Yue‐Sheng Li, Yao Chen, Zhenjie Zhang. Self‐Healing and Shape Memory Hypercrosslinked Metal‐Organic Polyhedra Polymers via Coordination Post‐Assembly. Angewandte Chemie 2022, 134 (43) https://doi.org/10.1002/ange.202212253
    46. Jinjin Liu, Jiamin Li, Shan Qiao, Zhifang Wang, Penghui Zhang, Xiangqian Fan, Peng Cheng, Yue‐Sheng Li, Yao Chen, Zhenjie Zhang. Self‐Healing and Shape Memory Hypercrosslinked Metal‐Organic Polyhedra Polymers via Coordination Post‐Assembly. Angewandte Chemie International Edition 2022, 61 (43) https://doi.org/10.1002/anie.202212253
    47. Jiawei Lu, Mingfu Nie, Youran Li, Huilin Zhu, Guiyang Shi. Design of composite nanosupports and applications thereof in enzyme immobilization: A review. Colloids and Surfaces B: Biointerfaces 2022, 217 , 112602. https://doi.org/10.1016/j.colsurfb.2022.112602
    48. Jinjin Liu, Zhifang Wang, Peng Cheng, Michael J. Zaworotko, Yao Chen, Zhenjie Zhang. Post-synthetic modifications of metal–organic cages. Nature Reviews Chemistry 2022, 6 (5) , 339-356. https://doi.org/10.1038/s41570-022-00380-y
    49. Jiahao Li, Anruo Mao, Wei Yao, Haiyan Zhu, Dawei Wang. Iridium supported on porous polypyridine-oxadiazole as high-activity and recyclable catalyst for the borrowing hydrogen reaction. Green Chemistry 2022, 24 (6) , 2602-2612. https://doi.org/10.1039/D2GC00190J
    50. Esther Frederick, Leah N. Appelhans, Frank W. Del Rio, Kevin T. Strong, Sean Smith, Sara Dickens, Erika Vreeland. Synthesis and Mechanical Properties of sub 5‐μm PolyUiO‐66 Thin Films on Gold Surfaces. ChemPhysChem 2022, 23 (3) https://doi.org/10.1002/cphc.202100673
    51. Taliehsadat Alebrahim, Alisa Chakraborty, Leiqing Hu, Shalin Patil, Shiwang Cheng, Durga Acharya, Cara M. Doherty, Anita J. Hill, Timothy R. Cook, Haiqing Lin. Gas transport characteristics of supramolecular networks of metal-coordinated highly branched Poly(ethylene oxide). Journal of Membrane Science 2022, 644 , 120063. https://doi.org/10.1016/j.memsci.2021.120063
    52. Guoqiang Shao, Shengnan Wang, Hekai Zhao, Guilan Zhao, Lina Yang, Lijie Zhu, He Liu. Tunable arrangement of hydrogel and cyclodextrin-based metal organic frameworks suitable for drug encapsulation and release. Carbohydrate Polymers 2022, 278 , 118915. https://doi.org/10.1016/j.carbpol.2021.118915
    53. Meng-Hao Li, Xin-Yue Lou, Ying-Wei Yang. Pillararene-based molecular-scale porous materials. Chemical Communications 2021, 57 (99) , 13429-13447. https://doi.org/10.1039/D1CC06105D
    54. Muhammad Ahmad Mudassir, Hafiz Zohaib Aslam, Tariq Mahmood Ansari, Haifei Zhang, Irshad Hussain. Fundamentals and Design‐Led Synthesis of Emulsion‐Templated Porous Materials for Environmental Applications. Advanced Science 2021, 8 (22) https://doi.org/10.1002/advs.202102540
    55. Zhen Zou, Libei He, Xiangxi Deng, Huangxiang Wang, Ziyun Huang, Qian Xue, Zhihe Qing, Yanli Lei, Ronghua Yang, Juewen Liu. Zn 2+ ‐Coordination‐Driven RNA Assembly with Retained Integrity and Biological Functions. Angewandte Chemie 2021, 133 (42) , 23152-23158. https://doi.org/10.1002/ange.202110404
    56. Zhen Zou, Libei He, Xiangxi Deng, Huangxiang Wang, Ziyun Huang, Qian Xue, Zhihe Qing, Yanli Lei, Ronghua Yang, Juewen Liu. Zn 2+ ‐Coordination‐Driven RNA Assembly with Retained Integrity and Biological Functions. Angewandte Chemie International Edition 2021, 60 (42) , 22970-22976. https://doi.org/10.1002/anie.202110404
    57. Ziman Chen, Xinle Li, Chongqing Yang, Kaipeng Cheng, Tianwei Tan, Yongqin Lv, Yi Liu. Hybrid Porous Crystalline Materials from Metal Organic Frameworks and Covalent Organic Frameworks. Advanced Science 2021, 8 (20) https://doi.org/10.1002/advs.202101883
    58. Ziqi Yang, Guoliang Liu, Yi Di Yuan, Shing Bo Peh, Yunpan Ying, Weidong Fan, Xin Yu, Hao Yang, Zhongjie Wu, Dan Zhao. Homoporous hybrid membranes containing metal-organic cages for gas separation. Journal of Membrane Science 2021, 636 , 119564. https://doi.org/10.1016/j.memsci.2021.119564
    59. Yu Zhu, Wei Zheng, Wei Wang, Hai-Bo Yang. When polymerization meets coordination-driven self-assembly: metallo-supramolecular polymers based on supramolecular coordination complexes. Chemical Society Reviews 2021, 50 (13) , 7395-7417. https://doi.org/10.1039/D0CS00654H
    60. Gregory W. Peterson, Dennis T. Lee, Heather F. Barton, Thomas H. Epps, Gregory N. Parsons. Fibre-based composites from the integration of metal–organic frameworks and polymers. Nature Reviews Materials 2021, 6 (7) , 605-621. https://doi.org/10.1038/s41578-021-00291-2
    61. Fazheng Jin, Jinjin Liu, Yao Chen, Zhenjie Zhang. Tethering Flexible Polymers to Crystalline Porous Materials: A Win–Win Hybridization Approach. Angewandte Chemie 2021, 133 (26) , 14342-14355. https://doi.org/10.1002/ange.202011213
    62. Fazheng Jin, Jinjin Liu, Yao Chen, Zhenjie Zhang. Tethering Flexible Polymers to Crystalline Porous Materials: A Win–Win Hybridization Approach. Angewandte Chemie International Edition 2021, 60 (26) , 14222-14235. https://doi.org/10.1002/anie.202011213
    63. Yong-Kai Xu, Mei-Mei Meng, Ji-Ming Xi, Li-Fei Wang, Rui Zhu, Xing-Gui Liu, Rui Zhang, Wei Dong, Zhen-Zhong Lu, He-Gen Zheng, Wei Huang. Mixed matrix membranes containing fluorescent coordination polymers for detecting Cr 2 O 7 2− with high sensitivity, stability and recyclability. Dalton Transactions 2021, 50 (23) , 7944-7948. https://doi.org/10.1039/D1DT00894C
    64. Matthew L. Schneider, Adrian W. Markwell-Heys, Oliver M. Linder-Patton, Witold M. Bloch. Assembly and Covalent Cross-Linking of an Amine-Functionalised Metal-Organic Cage. Frontiers in Chemistry 2021, 9 https://doi.org/10.3389/fchem.2021.696081
    65. Ru-Jin Li, Cristian Pezzato, Cesare Berton, Kay Severin. Light-induced assembly and disassembly of polymers with Pd n L 2n -type network junctions. Chemical Science 2021, 12 (13) , 4981-4984. https://doi.org/10.1039/D1SC00127B
    66. Maria A. Syzgantseva, Olga A. Syzgantseva. Structural insights on the metal cross-linking of polymers from the first principles: Calcium – Polymethacrylic acid case study. Polymer 2021, 215 , 123368. https://doi.org/10.1016/j.polymer.2020.123368
    67. Vincent J. Pastore, Meghan G. Sullivan, Javid Rzayev, Timothy R. Cook. Postsynthetic polymer-ligand exchange hybridization in M-MOF-74 composites. Journal of Coordination Chemistry 2021, 74 (1-3) , 178-189. https://doi.org/10.1080/00958972.2021.1876852
    68. Zhiang Fu, Xiaoying Gu, Lingmin Hu, Yongjin Li, Jingye Li. Radiation Induced Surface Modification of Nanoparticles and Their Dispersion in the Polymer Matrix. Nanomaterials 2020, 10 (11) , 2237. https://doi.org/10.3390/nano10112237
    69. Matthew L. Schneider, Oliver M. Linder-Patton, Witold M. Bloch. A covalent deprotection strategy for assembling supramolecular coordination polymers from metal–organic cages. Chemical Communications 2020, 56 (85) , 12969-12972. https://doi.org/10.1039/D0CC05349J

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    MENDELEY PAIRING EXPIRED
    Your Mendeley pairing has expired. Please reconnect