Style Guides and the Garlic, Shallots, and Butter of Scientific WritingClick to copy article linkArticle link copied!
- Darren J. Lipomi*Darren J. Lipomi*Email: [email protected]Department of NanoEngineering and Chemical Engineering Program, University of California, San Diego, 9500 Gilman Drive, Mail Code 0448, La Jolla, California 92093-0448, United StatesMore by Darren J. Lipomi
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1. Write from the top down
2. Use shorter sentences
3. Avoid noun piles
Example 1. “The glass transition temperature (Tg) is a second-order phase transition that ultimately describes the thermally activated chain reorganization in the polymer specimen amorphous domains. A density vs temperature plot exhibits a slope change in the vicinity of Tg (Figure 6). Similarly, a heat flow vs temperature plot measured by differential scanning calorimetry (DSC) reveals a heat capacity increase. Below Tg, a polymer is said to be glassy; above the Tg, it is rubbery. In a purely amorphous sample (e.g., atactic polystyrene), the material flows readily above its Tg. A semicrystalline sample above its Tg, but below crystalline domain melting temperature (Tm), exists as an ordinary time scale solid and is said to be in its elastomeric state.”
Example 2. “The glass transition temperature (Tg) is a second-order phase transition that ultimately describes the thermally activated reorganization of chains in the amorphous domains of a polymer specimen. A plot of density vs temperature exhibits a change in slope in the vicinity of Tg (Figure 6). Similarly, a plot of heat flow vs temperature measured by differential scanning calorimetry (DSC) reveals an increase in heat capacity. Below Tg, a polymer is said to be glassy; above the Tg, it is rubbery. In a purely amorphous sample (e.g., atactic polystyrene), the material flows readily above its Tg. A semicrystalline sample above its Tg, but below the temperature at which its crystalline domains melt (Tm), exists as a solid at ordinary time scales and is said to be in its elastomeric state.”
Final thoughts
References
This article references 7 other publications.
- 1Bourdain, A. Kitchen Confidential: Adventures in the Culinary Underbelly; HarperCollins: New York, 2000.Google ScholarThere is no corresponding record for this reference.
- 2Strunk, W.; White, E. B. The Elements of Style, 4th ed.; Pearson: 1999; first published 1935, last revision 1999.Google ScholarThere is no corresponding record for this reference.
- 3Pinker, S. The Sense of Style: The Thinking Person’s Guide to Writing in the 21st Century; Penguin: 2014.Google ScholarThere is no corresponding record for this reference.
- 4Whitesides, G. M. Whitesides’ Group: Writing a Paper. Adv. Mater. 2004, 16, 1375– 1377, DOI: 10.1002/adma.200400767Google Scholar4Whitesides' group: Writing a paperWhitesides, George M.Advanced Materials (Weinheim, Germany) (2004), 16 (15), 1375-1377CODEN: ADVMEW; ISSN:0935-9648. (Wiley-VCH Verlag GmbH & Co. KGaA)There is no expanded citation for this reference.
- 5Majoo, F. Space Invaders: Why you should never, ever use two spaces after a period. Slate. Published Jan 12, 2011, https://slate.com/technology/2011/01/two-spaces-after-a-period-why-you-should-never-ever-do-it.html (accessed 5/14/21).Google ScholarThere is no corresponding record for this reference.
- 6Lester, T. A Conversation with Edward O. Wilson. The Atlantic. https://www.theatlantic.com/entertainment/archive/1998/03/books-authors/377071/ (accessed 5/11/21).Google ScholarThere is no corresponding record for this reference.
- 7Root, S. E.; Alkhadra, M. A.; Rodriquez, D.; Printz, A. D.; Lipomi, D. J. Measuring the Glass Transition Temperature of Conjugated Polymer Films with Ultraviolet-Visible Spectroscopy. Chem. Mater. 2017, 29, 2646– 2654, DOI: 10.1021/acs.chemmater.7b00242Google Scholar6Measuring the Glass Transition Temperature of Conjugated Polymer Films with Ultraviolet-Visible SpectroscopyRoot, Samuel E.; Alkhadra, Mohammad A.; Rodriquez, Daniel; Printz, Adam D.; Lipomi, Darren J.Chemistry of Materials (2017), 29 (7), 2646-2654CODEN: CMATEX; ISSN:0897-4756. (American Chemical Society)The glass transition temp. (Tg) of a conjugated polymer can be used to predict its morphol. stability and mech. properties. Despite the importance of this parameter in applications from org. solar cells to wearable electronics, it is not easy to measure. The Tg is often too weak to detect using conventional differential scanning calorimetry (DSC). Alternative methods-e.g., variable temp. ellipsometry-require specialized equipment. This paper describes a technique for measuring the Tg of thin films of semicryst. conjugated polymers using only a hot plate and an UV-visible (UV-vis) spectrometer. UV-vis spectroscopy is used to measure changes in the absorption spectrum due to mol.-scale rearrangement of polymers when heated past Tg, corresponding to the onset of the formation of photophys. aggregates. A deviation metric, defined as the mean-squared deviation in absorbance between as-cast and annealed films, is used to quantify shifts in the absorption spectra. The glass transition is obsd. as a change in slope in a plot of the deviation metric vs. temp. To demonstrate the usefulness of this technique, a variety of semiconducting polymers are tested: P3BT, PBTTT-C14, F8BT, PDTSTPD, PTB7, PCDTBT, TQ1, and MEH-PPV. These polymers represent a range of solid-state morphologies, from highly ordered to predominately amorphous. A successful measurement of Tg depends on the ability of the polymer to form photophys. aggregates. The results obtained using this method for P3BT, PBTTT-C14, F8BT, and PDTSTPD are in agreement with values of Tg that have been reported in the literature. Mol. dynamics simulations are used to show how the morphol. evolves upon annealing: above the Tg, an initially kinetically trapped morphol. undergoes structural rearrangements to assume a more thermodynamically preferred structure. The temp. at which onset of this rearrangement occurs in the simulation is concomitant with the spectroscopically detd. value of Tg.
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References
This article references 7 other publications.
- 1Bourdain, A. Kitchen Confidential: Adventures in the Culinary Underbelly; HarperCollins: New York, 2000.There is no corresponding record for this reference.
- 2Strunk, W.; White, E. B. The Elements of Style, 4th ed.; Pearson: 1999; first published 1935, last revision 1999.There is no corresponding record for this reference.
- 3Pinker, S. The Sense of Style: The Thinking Person’s Guide to Writing in the 21st Century; Penguin: 2014.There is no corresponding record for this reference.
- 4Whitesides, G. M. Whitesides’ Group: Writing a Paper. Adv. Mater. 2004, 16, 1375– 1377, DOI: 10.1002/adma.2004007674Whitesides' group: Writing a paperWhitesides, George M.Advanced Materials (Weinheim, Germany) (2004), 16 (15), 1375-1377CODEN: ADVMEW; ISSN:0935-9648. (Wiley-VCH Verlag GmbH & Co. KGaA)There is no expanded citation for this reference.
- 5Majoo, F. Space Invaders: Why you should never, ever use two spaces after a period. Slate. Published Jan 12, 2011, https://slate.com/technology/2011/01/two-spaces-after-a-period-why-you-should-never-ever-do-it.html (accessed 5/14/21).There is no corresponding record for this reference.
- 6Lester, T. A Conversation with Edward O. Wilson. The Atlantic. https://www.theatlantic.com/entertainment/archive/1998/03/books-authors/377071/ (accessed 5/11/21).There is no corresponding record for this reference.
- 7Root, S. E.; Alkhadra, M. A.; Rodriquez, D.; Printz, A. D.; Lipomi, D. J. Measuring the Glass Transition Temperature of Conjugated Polymer Films with Ultraviolet-Visible Spectroscopy. Chem. Mater. 2017, 29, 2646– 2654, DOI: 10.1021/acs.chemmater.7b002426Measuring the Glass Transition Temperature of Conjugated Polymer Films with Ultraviolet-Visible SpectroscopyRoot, Samuel E.; Alkhadra, Mohammad A.; Rodriquez, Daniel; Printz, Adam D.; Lipomi, Darren J.Chemistry of Materials (2017), 29 (7), 2646-2654CODEN: CMATEX; ISSN:0897-4756. (American Chemical Society)The glass transition temp. (Tg) of a conjugated polymer can be used to predict its morphol. stability and mech. properties. Despite the importance of this parameter in applications from org. solar cells to wearable electronics, it is not easy to measure. The Tg is often too weak to detect using conventional differential scanning calorimetry (DSC). Alternative methods-e.g., variable temp. ellipsometry-require specialized equipment. This paper describes a technique for measuring the Tg of thin films of semicryst. conjugated polymers using only a hot plate and an UV-visible (UV-vis) spectrometer. UV-vis spectroscopy is used to measure changes in the absorption spectrum due to mol.-scale rearrangement of polymers when heated past Tg, corresponding to the onset of the formation of photophys. aggregates. A deviation metric, defined as the mean-squared deviation in absorbance between as-cast and annealed films, is used to quantify shifts in the absorption spectra. The glass transition is obsd. as a change in slope in a plot of the deviation metric vs. temp. To demonstrate the usefulness of this technique, a variety of semiconducting polymers are tested: P3BT, PBTTT-C14, F8BT, PDTSTPD, PTB7, PCDTBT, TQ1, and MEH-PPV. These polymers represent a range of solid-state morphologies, from highly ordered to predominately amorphous. A successful measurement of Tg depends on the ability of the polymer to form photophys. aggregates. The results obtained using this method for P3BT, PBTTT-C14, F8BT, and PDTSTPD are in agreement with values of Tg that have been reported in the literature. Mol. dynamics simulations are used to show how the morphol. evolves upon annealing: above the Tg, an initially kinetically trapped morphol. undergoes structural rearrangements to assume a more thermodynamically preferred structure. The temp. at which onset of this rearrangement occurs in the simulation is concomitant with the spectroscopically detd. value of Tg.