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Understanding the Chemistry of Metal Oxide to Metal–Organic Framework Reactions for Morphology Control

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Download Hi-Res ImageDownload to MS-PowerPointCite This:Chem. Mater. 2023, 35, 5, 1891-1900
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    Understanding the Chemistry of Metal Oxide to Metal–Organic Framework Reactions for Morphology Control
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    Chemistry of Materials

    Cite this: Chem. Mater. 2023, 35, 5, 1891–1900
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    https://doi.org/10.1021/acs.chemmater.2c02946
    Published February 21, 2023
    Copyright © 2023 American Chemical Society
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    Abstract

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    Metal–organic frameworks (MOFs) are a class of porous materials that have been thoroughly investigated in the past two decades; however, three-dimensional (3D) morphological control is still not established to an adequate degree. The use of metal oxides (MOs) with controllable morphology as precursors is a promising approach to overcome this limitation. Here, we investigate the formation of MOFs from different MOs and carry out a detailed case study to rationalize the factors governing the conversion of zinc oxide nanowires into ZIF-8 with the same morphology. This knowledge is then applied to generate complex 3D ZIF-8 and ZnO@ZIF-8 composite structures from different ZnO precursors. In addition, we show that this approach can be used to access new MOF structures, which are not achievable by standard synthetic methods. This study showcases how a deep understanding of the MO-to-MOF conversion can be used for the fabrication of MOF materials with precisely tailored morphology.

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    Supporting Information

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    • Detailed characterization of MO precursors and MOF materials including SEM micrographs, XRD patterns, TGA, and nitrogen adsorption/desorption isotherms; structural analysis of Co(btc); time-dependent dissolution of ZnO nanowires in H2O, DMF, and mixture of H2O and DMF (1:1); screening of different reaction times for the ZnO-to-ZIF-8 conversion; X-ray diffraction patterns of ZIF-8 obtained using ZnO as a precursor by solvothermal method (without microwave irradiation) at different times; and tables presenting conditions for the ZnO-to-ZIF-8 conversion (PDF)

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    Cited By

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    This article is cited by 3 publications.

    1. Aleksander Ejsmont, Subhajit Dutta, Agata Jankowska, Stefan Wuttke, Joanna Goscianska. Governing the Porosity and Morphology of Zeolitic Imidazolate Framework-Derived Functional Carbons toward Improved Adsorption of Cationic Dyes. Chemistry of Materials 2024, 36 (9) , 4468-4480. https://doi.org/10.1021/acs.chemmater.4c00080
    2. Antonio Valverde-Gonzalez, Nastasiya Yuriychuk, M. Carmen Borrallo-Aniceto, Felipe Gándara, Marta Iglesias, Mar López-González, Eva M. Maya. Naphthalene Tetrazole-Based Nickel Metal–Organic Framework as a Filler of Polycarbonate Membranes to Improve CO2 and H2 Separation. ACS Applied Polymer Materials 2024, 6 (7) , 4244-4255. https://doi.org/10.1021/acsapm.4c00277
    3. James A. Godwin, Jonah P. Babusci, Nichole M. Wonderling, Jeffrey R. Shallenberger, Kendhl Seabright, David P. Harper, Stephen C. Chmely. Catalytic Transfer Hydrogenolysis of Switchgrass Lignin with Ethanol Using Spinel-Type Mixed-Metal Oxide Catalysts Affords Control of the Oxidation State of Isolated Aromatic Products. ACS Sustainable Chemistry & Engineering 2024, 12 (7) , 2611-2620. https://doi.org/10.1021/acssuschemeng.3c06392
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    Chemistry of Materials

    Cite this: Chem. Mater. 2023, 35, 5, 1891–1900
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.chemmater.2c02946
    Published February 21, 2023
    Copyright © 2023 American Chemical Society
    Request reuse permissions

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