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Review of Material Properties of Oxide Semiconductor Thin Films Grown by Atomic Layer Deposition for Next-Generation 3D Dynamic Random-Access Memory Devices
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    Review of Material Properties of Oxide Semiconductor Thin Films Grown by Atomic Layer Deposition for Next-Generation 3D Dynamic Random-Access Memory Devices
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    • Ae Rim Choi
      Ae Rim Choi
      Department of Intelligence Semiconductor Engineering, Ajou University, Suwon 16499, Korea
      More by Ae Rim Choi
    • Dong Hyun Lim
      Dong Hyun Lim
      Department of Electrical and Computer Engineering, Ajou University, Suwon 16499, Korea
    • So-Yeon Shin
      So-Yeon Shin
      Department of Intelligence Semiconductor Engineering, Ajou University, Suwon 16499, Korea
      More by So-Yeon Shin
    • Hye Joo Kang
      Hye Joo Kang
      Department of Intelligence Semiconductor Engineering, Ajou University, Suwon 16499, Korea
      More by Hye Joo Kang
    • Dohee Kim
      Dohee Kim
      Revolutionary Technology Center, R&D division, SK hynix Inc., Icheon 17336, Korea
      More by Dohee Kim
    • Ja-Yong Kim
      Ja-Yong Kim
      Revolutionary Technology Center, R&D division, SK hynix Inc., Icheon 17336, Korea
      More by Ja-Yong Kim
    • Youngbae Ahn
      Youngbae Ahn
      Revolutionary Technology Center, R&D division, SK hynix Inc., Icheon 17336, Korea
      More by Youngbae Ahn
    • Seung Wook Ryu
      Seung Wook Ryu
      Revolutionary Technology Center, R&D division, SK hynix Inc., Icheon 17336, Korea
    • Il-Kwon Oh*
      Il-Kwon Oh
      Department of Intelligence Semiconductor Engineering, Ajou University, Suwon 16499, Korea
      Department of Electrical and Computer Engineering, Ajou University, Suwon 16499, Korea
      *Email: [email protected]
      More by Il-Kwon Oh
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    Chemistry of Materials

    Cite this: Chem. Mater. 2024, 36, 5, 2194–2219
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    https://doi.org/10.1021/acs.chemmater.3c02223
    Published February 26, 2024
    Copyright © 2024 American Chemical Society

    Abstract

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    Dynamic random-access memory (DRAM) devices are essential volatile memory components in most digital devices. With the increasing demand for further low-power and high-density devices, the planar structure of DRAM devices encountered a “memory wall”, ushering in an era of 3D DRAM architecture. InGaZnO-based thin-film transistors (IGZO TFTs) have a very low off current (<10–22 A/μm), representing a solution for new channel materials for next-generation 3D DRAM devices. IGZO TFTs are back-end-of-line (BEOL)-compatible, enabling them to move the DRAM peripheral circuitry under the memory array and integrate stacked DRAM cells. IGZO thin films have been widely studied for next-generation flat panel display applications. However, most studies have employed sputtering and solution-based systems, which hinder process compatibility in 3D DRAM devices with complex structures. Atomic layer deposition (ALD) is a viable alternative for solving these challenges. In this paper, we comprehensively review the reported Zn-, In-, Sn-, and Ga-based oxide semiconductors in terms of the ALD process (precursors, reactants, growth temperature, etc.), together with material properties such as purity, crystallinity, and electrical properties.

    Copyright © 2024 American Chemical Society

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    This article is cited by 11 publications.

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    Chemistry of Materials

    Cite this: Chem. Mater. 2024, 36, 5, 2194–2219
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.chemmater.3c02223
    Published February 26, 2024
    Copyright © 2024 American Chemical Society

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