High Energy Density Large Particle LiFePO₄

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The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.chemmater.3c02301.

• Figure S1: XRD patterns of a hand-mixed LFP–graphite mixture and F-LFP2 after DPF processing and after heating; Figure S2: XRD patterns of F-LFP composite particles with 0–5% graphite content compared with pristine LFP sample used as a starting material; Figure S3: Williamson–Hall analysis plots used to determine the crystallite size and strain of LFP, F-LFP0, F-LFP2, and F-LFP5 particles; Figure S4: a cross-section image of F-LFP2 particle with interior layering highlighted; Figure S5: SEM images of argon broad ion beam (BIB) cross sections of electrode coatings formulated with LFP, F-LFP0, F-LFP2, and F-LFP5; Figure S6: a plot showing the theoretical and observed capacities of the F-LFP composites prepared; Table S1: listing of the atomic positions of LiFePO₄ as determined by Rietveld refinement of the LFP sample; Table S2: listing of the refined cell parameters for LFP and F-LFP samples containing 0, 2, and 5 wt % graphite; Table S3: listing of the calculated equivalent circuit parameters from EIS fitting analysis for LFP, F-LFP2, and F-LFP5 uncalendered electrodes (PDF)