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ACS Publications. Most Trusted. Most Cited. Most Read
Conjugated Oligomers as Fluorescence Marker for the Determination of the Self-Healing Efficiency in Mussel-Inspired Polymers
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    Conjugated Oligomers as Fluorescence Marker for the Determination of the Self-Healing Efficiency in Mussel-Inspired Polymers
    Click to copy article linkArticle link copied!

    • Johannes Ahner
      Johannes Ahner
      Laboratory of Organic and Macromolecular Chemistry (IOMC), Friedrich Schiller University Jena, Humboldtstraße 10, Jena D-07743, Germany
      Jena Center for Soft Matter (JCSM), Friedrich Schiller University Jena, Philosophenweg 7, Jena D−07743, Germany
    • David Pretzel
      David Pretzel
      Laboratory of Organic and Macromolecular Chemistry (IOMC), Friedrich Schiller University Jena, Humboldtstraße 10, Jena D-07743, Germany
      Jena Center for Soft Matter (JCSM), Friedrich Schiller University Jena, Philosophenweg 7, Jena D−07743, Germany
    • Marcel Enke
      Marcel Enke
      Laboratory of Organic and Macromolecular Chemistry (IOMC), Friedrich Schiller University Jena, Humboldtstraße 10, Jena D-07743, Germany
      Jena Center for Soft Matter (JCSM), Friedrich Schiller University Jena, Philosophenweg 7, Jena D−07743, Germany
      More by Marcel Enke
    • Robert Geitner
      Robert Geitner
      Institute of Physical Chemistry, Friedrich Schiller University Jena, Helmholtzweg 4, Jena D−07743, Germany
    • Stefan Zechel
      Stefan Zechel
      Laboratory of Organic and Macromolecular Chemistry (IOMC), Friedrich Schiller University Jena, Humboldtstraße 10, Jena D-07743, Germany
      Jena Center for Soft Matter (JCSM), Friedrich Schiller University Jena, Philosophenweg 7, Jena D−07743, Germany
    • Jürgen Popp
      Jürgen Popp
      Institute of Physical Chemistry, Friedrich Schiller University Jena, Helmholtzweg 4, Jena D−07743, Germany
      Leibniz Institute of Photonic Technology (IPHT) e.V., Albert-Einstein-Straße 9, Jena D−07745, Germany
      More by Jürgen Popp
    • Ulrich S. Schubert*
      Ulrich S. Schubert
      Laboratory of Organic and Macromolecular Chemistry (IOMC), Friedrich Schiller University Jena, Humboldtstraße 10, Jena D-07743, Germany
      Jena Center for Soft Matter (JCSM), Friedrich Schiller University Jena, Philosophenweg 7, Jena D−07743, Germany
      *E-mail: [email protected]
    • Martin D. Hager*
      Martin D. Hager
      Laboratory of Organic and Macromolecular Chemistry (IOMC), Friedrich Schiller University Jena, Humboldtstraße 10, Jena D-07743, Germany
      Jena Center for Soft Matter (JCSM), Friedrich Schiller University Jena, Philosophenweg 7, Jena D−07743, Germany
      *E-mail: [email protected]
    Other Access OptionsSupporting Information (1)

    Chemistry of Materials

    Cite this: Chem. Mater. 2018, 30, 8, 2791–2799
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.chemmater.8b00623
    Published April 3, 2018
    Copyright © 2018 American Chemical Society

    Abstract

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    Within the current study, a novel approach for the detailed determination of the scratch healing efficiency in mussel-inspired polymer films is presented. For this purpose, a sensor molecule was incorporated into a self-healing polymer network based on reversible zinc–histidine interactions. The fluorescence of the sensor molecule was monitored enabling a detailed depth- and time-resolved determination of the healing efficiency by means of confocal laser scanning microscopy (CLSM). Finally, this concept represents an efficient and detailed approach for the determination of the scratch self-healing efficiency in polymer films and can also be applied for other scratch self-healing systems, which are based on reversible dynamic bonds.

    Copyright © 2018 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.chemmater.8b00623.

    • Experimental section, NMR measurements, ITC investigations, FT-Raman spectra, TGA measurements, DSC spectra, and additional information for the applied self-healing studies (PDF)

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    Cited By

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    This article is cited by 21 publications.

    1. Jiangman Sun, Jianguo Wang, Ming Chen, Xiong Pu, Guan Wang, Lin Li, Guanyu Chen, Yuanjing Cai, Xinggui Gu, Ben Zhong Tang. Fluorescence Turn-On Visualization of Microscopic Processes for Self-Healing Gels by AIEgens and Anticounterfeiting Application. Chemistry of Materials 2019, 31 (15) , 5683-5690. https://doi.org/10.1021/acs.chemmater.9b01611
    2. Meenu Murali, Eric Manoury, Rinaldo Poli. Coordination Adaptable Networks: Introducing Vitrimer Properties Using Dynamic Coordination Bonds. European Journal of Inorganic Chemistry 2023, 26 (36) https://doi.org/10.1002/ejic.202300574
    3. Jianming Shao, Yu Wang, Ping Zhu, Xia Dong, Dujin Wang. Robust polyurethane materials with synergistic ionic and metal-ligand crosslinking double networks for specific Cu-ion removal. Chemical Engineering Journal 2023, 474 , 145719. https://doi.org/10.1016/j.cej.2023.145719
    4. Evgeny S. Sorin, Rose K. Baimuratova, Igor E. Uflyand, Evgeniya O. Perepelitsina, Denis V. Anokhin, Dmitry A. Ivanov, Gulzhian I. Dzhardimalieva. New Self-Healing Metallosupramolecular Copolymers with a Complex of Cobalt Acrylate and 4′-Phenyl-2,2′:6′,2″-terpyridine. Polymers 2023, 15 (6) , 1472. https://doi.org/10.3390/polym15061472
    5. Qiaozhi Zhu, Yuqing Zhu, Weidong Liu, Xinni Ping, Xuting Cai, Jiaqi Zuo, Zhaosheng Qian, Hui Feng. Photochemically Enhanced Emission by Introducing Rational Photoactive Subunits into an Aggregation‐Induced Emission Luminogen. Chemistry – A European Journal 2022, 28 (70) https://doi.org/10.1002/chem.202202178
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    8. Ajit Behera. Self-Healing Materials. 2022, 321-358. https://doi.org/10.1007/978-3-030-80359-9_10
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    10. Christopher Igwe Idumah, Iheoma Nwuzor, Stone R. Odera. Recent advancements in self-healing polymeric hydrogels, shape memory, and stretchable materials. International Journal of Polymeric Materials and Polymeric Biomaterials 2021, 70 (13) , 941-966. https://doi.org/10.1080/00914037.2020.1767615
    11. Stefan Götz, Stefan Zechel, Martin D. Hager, George R. Newkome, Ulrich S. Schubert. Versatile Applications of Metallopolymers. Progress in Polymer Science 2021, 119 , 101428. https://doi.org/10.1016/j.progpolymsci.2021.101428
    12. Bas van Genabeek, Brigitte A. G. Lamers, Craig J. Hawker, E. W. Meijer, Will R. Gutekunst, Bernhard V. K. J. Schmidt. Properties and applications of precision oligomer materials; where organic and polymer chemistry join forces. Journal of Polymer Science 2021, 59 (5) , 373-403. https://doi.org/10.1002/pol.20200862
    13. Qiaoqiao Shen, Hui Liu, Yan Peng, Jing Zheng, Jinrong Wu. Visualization of the self-healing process by directly observing the evolution of fluorescence intensity. Polymer Chemistry 2021, 12 (4) , 494-500. https://doi.org/10.1039/D0PY01476A
    14. Jingcheng Liu, Zhen Zhou, Xunzheng Su, Jiancheng Cao, Mengjia Chen, Ren Liu. Stiff UV-Curable self-healing coating based on double reversible networks containing diels-alder cross-linking and hydrogen bonds. Progress in Organic Coatings 2020, 146 , 105699. https://doi.org/10.1016/j.porgcoat.2020.105699
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    16. Agata Krywko-Cendrowska, Dawid Szweda, Roza Szweda. Well-Defined Conjugated Macromolecules Based on Oligo(Arylene Ethynylene)s in Sensing. Processes 2020, 8 (5) , 539. https://doi.org/10.3390/pr8050539
    17. Stefan Götz, Stefan Zechel, Martin D. Hager, Ulrich S. Schubert. Lanthanoids Goes Healing: Lanthanoidic Metallopolymers and Their Scratch Closure Behavior. Polymers 2020, 12 (4) , 838. https://doi.org/10.3390/polym12040838
    18. Martin D. Hager, Stefan Zechel. Self-healing polymers: from general basics to mechanistic aspects. 2020, 75-94. https://doi.org/10.1016/B978-0-12-818450-9.00003-9
    19. Nediljko Budisa, Tobias Schneider. Expanding the DOPA Universe with Genetically Encoded, Mussel‐Inspired Bioadhesives for Material Sciences and Medicine. ChemBioChem 2019, 20 (17) , 2163-2190. https://doi.org/10.1002/cbic.201900030
    20. Junning Qian, Di Wu, Ping Cai, Jiangbin Xia. Nitrogen atom free polythiophene derivative as an efficient chemosensor for highly selective and sensitive Cu2+ and Ag+ detection. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2019, 218 , 76-84. https://doi.org/10.1016/j.saa.2019.03.093
    21. Stefan Zechel, Martin D. Hager, Tobias Priemel, Matthew J. Harrington. Healing through Histidine: Bioinspired Pathways to Self-Healing Polymers via Imidazole–Metal Coordination. Biomimetics 2019, 4 (1) , 20. https://doi.org/10.3390/biomimetics4010020

    Chemistry of Materials

    Cite this: Chem. Mater. 2018, 30, 8, 2791–2799
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.chemmater.8b00623
    Published April 3, 2018
    Copyright © 2018 American Chemical Society

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