logo

OR SEARCH CITATIONS

My Activity
Publications
CONTENT TYPES

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:Chem. Mater. 2018, 30, 15, 5397-5403
RETURN TO ISSUEPREVArticleNEXT

Expanding Frontiers of Ultraviolet Nonlinear Optical Materials with Fluorophosphates

  • Bingbing Zhang
    Bingbing Zhang
    CAS Key Laboratory of Functional Materials and Devices for Special Environments, Xinjiang Technical Institute of Physics & Chemistry of CAS, Xinjiang Key Laboratory of Electronic Information Materials and Devices, 40-1 South Beijing Road, Urumqi 830011, China
    More by Bingbing Zhang
    Orcidhttp://orcid.org/0000-0002-1334-5812
    • , 
  • Guopeng Han
    Guopeng Han
    CAS Key Laboratory of Functional Materials and Devices for Special Environments, Xinjiang Technical Institute of Physics & Chemistry of CAS, Xinjiang Key Laboratory of Electronic Information Materials and Devices, 40-1 South Beijing Road, Urumqi 830011, China
    University of Chinese Academy of Sciences, Beijing 100049, China
    More by Guopeng Han
    • , 
  • Ying Wang
    Ying Wang
    CAS Key Laboratory of Functional Materials and Devices for Special Environments, Xinjiang Technical Institute of Physics & Chemistry of CAS, Xinjiang Key Laboratory of Electronic Information Materials and Devices, 40-1 South Beijing Road, Urumqi 830011, China
    More by Ying Wang
    Orcidhttp://orcid.org/0000-0001-6642-543X
    • , 
  • Xinglong Chen
    Xinglong Chen
    CAS Key Laboratory of Functional Materials and Devices for Special Environments, Xinjiang Technical Institute of Physics & Chemistry of CAS, Xinjiang Key Laboratory of Electronic Information Materials and Devices, 40-1 South Beijing Road, Urumqi 830011, China
    University of Chinese Academy of Sciences, Beijing 100049, China
    More by Xinglong Chen
    • , 
  • Zhihua Yang*
    Zhihua Yang
    CAS Key Laboratory of Functional Materials and Devices for Special Environments, Xinjiang Technical Institute of Physics & Chemistry of CAS, Xinjiang Key Laboratory of Electronic Information Materials and Devices, 40-1 South Beijing Road, Urumqi 830011, China
    *E-mail: [email protected]
    More by Zhihua Yang
    Orcidhttp://orcid.org/0000-0001-9214-3612
    • , and 
  • Shilie Pan*
    Shilie Pan
    CAS Key Laboratory of Functional Materials and Devices for Special Environments, Xinjiang Technical Institute of Physics & Chemistry of CAS, Xinjiang Key Laboratory of Electronic Information Materials and Devices, 40-1 South Beijing Road, Urumqi 830011, China
    *E-mail: [email protected]
    More by Shilie Pan
    Orcidhttp://orcid.org/0000-0003-4521-4507
Cite this: Chem. Mater. 2018, 30, 15, 5397–5403
Publication Date (Web):July 17, 2018
https://doi.org/10.1021/acs.chemmater.8b02223
Copyright © 2018 American Chemical Society
RIGHTS & PERMISSIONS
Article Views
993
Altmetric
-
Citations
42
LEARN ABOUT THESE METRICS

Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.

Read OnlinePDF (3 MB)
Supporting Info (2)»
SUBJECTS:

Abstract

Abstract Image

If a bucket is to hold more water, its shortest plank must be made longer. This guideline also applies to the exploration of ultraviolet (UV) and deep-UV (DUV) nonlinear optical (NLO) materials that are limited by multiple criteria. Phosphates are one kind of promising candidate for new NLO materials. Unfortunately, the small birefringence, as the shortest plank, severely restricts the phase-matching of second harmonic generation (SHG) in the UV/DUV region. In this work, fluorophosphates are rationally proposed as substitutes for phosphates to break down the limitation of birefringence and simultaneously enhance SHG response and retain wide UV transmittance. The (PO3F)2– and (PO2F2)− groups are confirmed as superior material genomes to achieve the discussed combination properties. Accordingly, (NH4)2PO3F was screened out by density functional theory calculation, and single crystals with centimeter size have been grown. It possesses a powder SHG efficiency of 1 × KH2PO4 (KDP) and is phase-matchable with output of SHG wavelength at 266 nm. To the best of our knowledge, it is the first time that fluorophosphates are identified and developed as new and ideal candidates to new UV/DUV NLO materials by combining theories and experiments.

Supporting Information

ARTICLE SECTIONS
Jump To

The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.chemmater.8b02223.

  • Photographs of the as-grown single crystals of (NH4)2PO3F; X-ray diffraction (XRD) patterns, thermal gravimetric (TG) analysis, and differential scanning calorimetry (DSC), energy-dispersive X-ray spectroscopy (EDX), IR spectrum, and SHG density of (NH4)2PO3 (PDF)

  • Crystal data and structure refinement for (NH4)2PO3F (CIF)

Terms & Conditions

Electronic Supporting Information files are available without a subscription to ACS Web Editions. The American Chemical Society holds a copyright ownership interest in any copyrightable Supporting Information. Files available from the ACS website may be downloaded for personal use only. Users are not otherwise permitted to reproduce, republish, redistribute, or sell any Supporting Information from the ACS website, either in whole or in part, in either machine-readable form or any other form without permission from the American Chemical Society. For permission to reproduce, republish and redistribute this material, requesters must process their own requests via the RightsLink permission system. Information about how to use the RightsLink permission system can be found at http://pubs.acs.org/page/copyright/permissions.html.

Cited By

This article is cited by 42 publications.

  1. Yunxia Song, Guangsai Yang, Pifu Gong, Min Luo, Zheshuai Lin, Ning Ye. Hydrogen-Bond-Assisted Reinforcement of Interlayer Connections in Zn2BO3X·H2O (X = Cl, Br): Two UV Nonlinear Optical Crystals with KBBF-Type Structure. Inorganic Chemistry 2020, Article ASAP.
  2. Qingran Ding, Xiaomeng Liu, Sangen Zhao, Yusong Wang, Yanqiang Li, Lina Li, Shuai Liu, Zheshuai Lin, Maochun Hong, Junhua Luo. Designing a Deep-UV Nonlinear Optical Fluorooxosilicophosphate. Journal of the American Chemical Society 2020, 142 (14) , 6472-6476. https://doi.org/10.1021/jacs.0c00060
  3. Xin-Rui Yang, He-Jie Lu, Si-Meng Zhang, Jing-Yi Yang, Xi Tang, Chun-Ya Pan, Ling Chen. An Effective and Facile Method To Prepare Monofluorophosphates Overcoming the Common Difficulty of Loss of Fluorine and Serious Corrosion: 12 Examples and Their Characterizations and Properties. Crystal Growth & Design 2020, 20 (1) , 479-485. https://doi.org/10.1021/acs.cgd.9b01441
  4. Zhiyong Bai, Chun-Li Hu, Lehui Liu, Lizhen Zhang, Yisheng Huang, Feifei Yuan, Zhoubin Lin. KMg(H2O)PO4: A Deep-Ultraviolet Transparent Nonlinear Optical Material Derived from KTiOPO4. Chemistry of Materials 2019, 31 (22) , 9540-9545. https://doi.org/10.1021/acs.chemmater.9b03950
  5. Yi Yang, Pifu Gong, Qian Huang, Gaomin Song, Xiaomeng Liu, Zheshuai Lin. KNa4B2P3O13: A Deep-Ultraviolet Transparent Borophosphate Exhibiting Second-Harmonic Generation Response. Inorganic Chemistry 2019, 58 (14) , 8918-8921. https://doi.org/10.1021/acs.inorgchem.9b01198
  6. Bao-Lin Wu, Chun-Li Hu, Fei-Fei Mao, Ru-Ling Tang, Jiang-Gao Mao. Highly Polarizable Hg2+ Induced a Strong Second Harmonic Generation Signal and Large Birefringence in LiHgPO4. Journal of the American Chemical Society 2019, 141 (26) , 10188-10192. https://doi.org/10.1021/jacs.9b05125
  7. Jing Lu, Jia-Ning Yue, Lin Xiong, Wen-Kai Zhang, Ling Chen, Li-Ming Wu. Uniform Alignment of Non-π-Conjugated Species Enhances Deep Ultraviolet Optical Nonlinearity. Journal of the American Chemical Society 2019, 141 (20) , 8093-8097. https://doi.org/10.1021/jacs.9b03858
  8. Yahui Li, Guopeng Han, Hongwei Yu, Hao Li, Zhihua Yang, Shilie Pan. Two Polar Molybdenum(VI) Iodates(V) with Large Second-Harmonic Generation Responses. Chemistry of Materials 2019, 31 (8) , 2992-3000. https://doi.org/10.1021/acs.chemmater.9b00521
  9. Xia-Yan Tang, Jin-Xiao Mi, Rong-Chuan Zhuang, Shuai-Hua Wang, Shao-Fan Wu, Yuanming Pan, Ya-Xi Huang. Rational Design and Synthesis of a Deep-Ultraviolet Nonlinear Optical Fluorinated Orthophosphate: BaZn(PO4)F. Inorganic Chemistry 2019, 58 (7) , 4508-4514. https://doi.org/10.1021/acs.inorgchem.9b00073
  10. Dequan Jiang, Guopeng Han, Ying Wang, Hao Li, Zhihua Yang, Shilie Pan. Designing Three Fluorooxoborates with a Wide Transmittance Window by Anionic Group Substitution. Inorganic Chemistry 2019, 58 (6) , 3596-3600. https://doi.org/10.1021/acs.inorgchem.9b00197
  11. Jianghe Feng, Chun Li Hu, Yuan Lin, Jiang Gao Mao. BaPO3Cl: a Metal Phosphate Chloride with Infinite [PO3]∞ Chains. Inorganic Chemistry 2019, 58 (1) , 73-76. https://doi.org/10.1021/acs.inorgchem.8b03111
  12. Lei Kang, Fei Liang, Zheshuai Lin, Feng Liu, Bing Huang. Cyano-Based Materials with Giant Optical Anisotropy and Second Harmonic-Generation Effect. Inorganic Chemistry 2018, 57 (23) , 15001-15008. https://doi.org/10.1021/acs.inorgchem.8b02795
  13. Jie Chen, Lin Xiong, Ling Chen, Li-Ming Wu. Ba2NaClP2O7: Unprecedented Phase Matchability Induced by Symmetry Breaking and Its Unique Fresnoite-Type Structure. Journal of the American Chemical Society 2018, 140 (43) , 14082-14086. https://doi.org/10.1021/jacs.8b10209
  14. Ping Wei, Wenqiang Chen, Qun Jing, Ming-Hsien Lee, Zhaohui Chen. Effects of P2O7 clusters arrangement on second harmonic generation responses of pyrophosphates. Journal of Alloys and Compounds 2020, 827 , 153922. https://doi.org/10.1016/j.jallcom.2020.153922
  15. Yaoguo Shen, Xiaoling Xue, Renwen Yan, Hong Lin. Synthesis, characterizations and theoretical analysis of a noncentrosymmetric sulfate. Inorganic Chemistry Communications 2020, 116 , 107899. https://doi.org/10.1016/j.inoche.2020.107899
  16. Xinglong Chen, Hongil Jo, Kang Min Ok. Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials. Angewandte Chemie 2020, 132 (19) , 7584-7590. https://doi.org/10.1002/ange.202002291
  17. Xinglong Chen, Hongil Jo, Kang Min Ok. Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials. Angewandte Chemie International Edition 2020, 59 (19) , 7514-7520. https://doi.org/10.1002/anie.202002291
  18. Tianyou Wang, Chao Wu, Lin Lin, Chi Zhang. Synthesis, crystal structures and optical properties of open-framework gallium phosphates: NaGa3F4(PO4)2(H2O)2 and AGa2P2O7(OH)3(H2O) (A = K, Rb). Journal of Solid State Chemistry 2020, , 121412. https://doi.org/10.1016/j.jssc.2020.121412
  19. Minqiang Gai, Ying Wang, Tinghao Tong, Liying Wang, Zhihua Yang, Xin Zhou, Shilie Pan. Ba(B 2 OF 3 (OH) 2 ) 2 with well-ordered OH/F anions and a unique B 2 OF 3 (OH) 2 dimer. Chemical Communications 2020, 56 (22) , 3301-3304. https://doi.org/10.1039/C9CC06532F
  20. Yaoguo Shen, Xiaoling Xue, Wenyuan Tu, Zhiqun Liu, Renwen Yan, Hong Zhang, Junrong Jia. Synthesis, Crystal Structure, and Characterization of a Noncentrosymmetric Sulfate Cs 2 Ca 2 (SO 4 ) 3. European Journal of Inorganic Chemistry 2020, 2020 (10) , 854-858. https://doi.org/10.1002/ejic.202000025
  21. Ya Yang, Kui Wu, Xiaowen Wu, Bingbing Zhang, Lihua Gao. A new family of quaternary thiosilicates SrA 2 SiS 4 (A = Li, Na, Cu) as promising infrared nonlinear optical crystals. Journal of Materials Chemistry C 2020, 8 (5) , 1762-1767. https://doi.org/10.1039/C9TC06077D
  22. Hongkun Liu, Ying Wang, Bingbing Zhang, Zhihua Yang, Shilie Pan. CsAlB 3 O 6 F: a beryllium-free deep-ultraviolet nonlinear optical material with enhanced thermal stability. Chemical Science 2020, 11 (3) , 694-698. https://doi.org/10.1039/C9SC04862F
  23. Xiao-Han Zhang, Bing-Ping Yang, Jin Chen, Chun-Li Hu, Zhi Fang, Zujian Wang, Jiang-Gao Mao. A new iodate-phosphate Pb 2 (IO 3 )(PO 4 ) achieving great improvement in birefringence activated by (IO 3 ) − groups. Chemical Communications 2020, 56 (4) , 635-638. https://doi.org/10.1039/C9CC08739G
  24. Feng Xu, Guang Peng, Chensheng Lin, Dan Zhao, Bingxuan Li, Ge Zhang, Shunda Yang, Ning Ye. Na 3 Sc 2 (PO 4 ) 2 F 3 : rational design and synthesis of an alkali rare-earth phosphate fluoride as an ultraviolet nonlinear optical crystal with an enlarged birefringence. Journal of Materials Chemistry C 2020, 457 https://doi.org/10.1039/D0TC00281J
  25. Qingran Ding, Sangen Zhao, Han Xiao, Yanqiang Li, Shuai Liu, Lina Li, Chunsen Li, Yusong Wang, Maochun Hong, Junhua Luo. An Uncommon Hypervalent Fluorooxosilicophosphate. Chemistry – An Asian Journal 2019, 14 (23) , 4174-4178. https://doi.org/10.1002/asia.201901410
  26. Jingyu Guo, Abudukadi Tudi, Shujuan Han, Zhihua Yang, Shilie Pan. Sn 2 B 5 O 9 Cl: A Material with Large Birefringence Enhancement Activated Prepared via Alkaline‐Earth‐Metal Substitution by Tin. Angewandte Chemie 2019, 131 (49) , 17839-17842. https://doi.org/10.1002/ange.201911187
  27. Jingyu Guo, Abudukadi Tudi, Shujuan Han, Zhihua Yang, Shilie Pan. Sn 2 B 5 O 9 Cl: A Material with Large Birefringence Enhancement Activated Prepared via Alkaline‐Earth‐Metal Substitution by Tin. Angewandte Chemie International Edition 2019, 58 (49) , 17675-17678. https://doi.org/10.1002/anie.201911187
  28. Ru‐Ling Tang, Chun‐Li Hu, Bao‐Lin Wu, Zhi Fang, Yan Chen, Jiang‐Gao Mao. Cs 2 Bi 2 O(Ge 2 O 7 ) (CBGO): A Larger SHG Effect Induced by Synergistic Polarizations of BiO 5 Polyhedra and GeO 4 Tetrahedra. Angewandte Chemie International Edition 2019, 58 (43) , 15358-15361. https://doi.org/10.1002/anie.201909735
  29. Ru‐Ling Tang, Chun‐Li Hu, Bao‐Lin Wu, Zhi Fang, Yan Chen, Jiang‐Gao Mao. Cs 2 Bi 2 O(Ge 2 O 7 ) (CBGO): A Larger SHG Effect Induced by Synergistic Polarizations of BiO 5 Polyhedra and GeO 4 Tetrahedra. Angewandte Chemie 2019, 131 (43) , 15502-15505. https://doi.org/10.1002/ange.201909735
  30. Jun Sun, Hongping Wu, Miriding Mutailipu, Zhihua Yang, Shilie Pan. Structural insights into three phosphates with distinct polyanionic configurations. Dalton Transactions 2019, 48 (35) , 13406-13412. https://doi.org/10.1039/C9DT02842K
  31. Meng Wang, Dequan Wei, Lanju Liang, Xin Yan, Kaikai Lv. Centrosymmetric Rb2Mg3(SO4)4 and non-centrosymmetric Cs2Mg3(SO4)4 with a phase-matching nonlinear optical response. Inorganic Chemistry Communications 2019, 107 , 107486. https://doi.org/10.1016/j.inoche.2019.107486
  32. Shi-Rui Zhang, Dan Zhao, Rui-Juan Zhang, Lin-Ying Shi, Shao-Jie Dai, Yun-Chang Fan. A novel stibium phosphate, LiBa(SbO) 2 (PO 4 ) 3 : synthesis, crystal structure and RE 3+ -activated (RE = Tb 3+ and Eu 3+ ) fluorescence performance. Acta Crystallographica Section C Structural Chemistry 2019, 75 (9) , 1234-1242. https://doi.org/10.1107/S2053229619010155
  33. Mohd. Shkir, Salem AlFaify. Effect of Gd 3+ doping on structural, morphological, optical, dielectric, and nonlinear optical properties of high-quality PbI 2 thin films for optoelectronic applications. Journal of Materials Research 2019, 34 (16) , 2765-2774. https://doi.org/10.1557/jmr.2019.121
  34. Ruiqi Wang, Fei Liang, Fakun Wang, Yangwu Guo, Xian Zhang, Yi Xiao, Kejun Bu, Zheshuai Lin, Jiyong Yao, Tianyou Zhai, Fuqiang Huang. Sr 6 Cd 2 Sb 6 O 7 S 10 : Strong SHG Response Activated by Highly Polarizable Sb/O/S Groups. Angewandte Chemie 2019, 131 (24) , 8162-8165. https://doi.org/10.1002/ange.201902806
  35. Ruiqi Wang, Fei Liang, Fakun Wang, Yangwu Guo, Xian Zhang, Yi Xiao, Kejun Bu, Zheshuai Lin, Jiyong Yao, Tianyou Zhai, Fuqiang Huang. Sr 6 Cd 2 Sb 6 O 7 S 10 : Strong SHG Response Activated by Highly Polarizable Sb/O/S Groups. Angewandte Chemie International Edition 2019, 58 (24) , 8078-8081. https://doi.org/10.1002/anie.201902806
  36. Kun Chai, Shichao Cheng, Hongyi Li, Bin Dai. Modulation of perovskite-related frameworks induced by alkaline earth metals in phosphate fluorides A 2 MPO 4 F (A = K, Rb; M = Ba, Ca). New Journal of Chemistry 2019, 43 (20) , 7839-7845. https://doi.org/10.1039/C9NJ01051C
  37. Yi Yang, Yi Qiu, Pifu Gong, Lei Kang, Gaomin Song, Xiaomeng Liu, Junliang Sun, Zheshuai Lin. Lone‐Pair Enhanced Birefringence in an Alkaline‐Earth Metal Tin(II) Phosphate BaSn 2 (PO 4 ) 2. Chemistry – A European Journal 2019, 25 (22) , 5648-5651. https://doi.org/10.1002/chem.201806108
  38. Fengguang You, Pifu Gong, Fei Liang, Xingxing Jiang, Heng Tu, Ying Zhao, Zhanggui Hu, Zheshuai Lin. M 2 (SeO 3 )F 2 (M = Zn, Cd): understanding the structure directing effect of [SeO 3 ] 2− groups on constructing ordered oxyfluorides. CrystEngComm 2019, 21 (15) , 2485-2489. https://doi.org/10.1039/C9CE00279K
  39. Kui Wu, Yu Chu, Zhihua Yang, Shilie Pan. A 2 SrM IV S 4 (A = Li, Na; M IV = Ge, Sn) concurrently exhibiting wide bandgaps and good nonlinear optical responses as new potential infrared nonlinear optical materials. Chemical Science 2019, 10 (14) , 3963-3968. https://doi.org/10.1039/C9SC00028C
  40. Baolin Wu, Chunli Hu, Ruling Tang, Feifei Mao, Jianghe Feng, Jianggao Mao. Fluoroborophosphates: a family of potential deep ultraviolet NLO materials. Inorganic Chemistry Frontiers 2019, 6 (3) , 723-730. https://doi.org/10.1039/C9QI00006B
  41. Guopeng Han, Ying Wang, Hao Li, Zhihua Yang, Shilie Pan. The first lithium difluorophosphate LiPO 2 F 2 with a neutral polytetrahedral microporous architecture. Chemical Communications 2019, 55 (12) , 1817-1820. https://doi.org/10.1039/C8CC10158B
  42. Ling Huang, Qian Wang, Fangfang He, Xiaoyan Liu, Ziwei Chen, Wen He, Xueying Luo, Daojiang Gao, Jian Bi, Guohong Zou. Synthesis, crystal structures and nonlinear optical properties of polymorphism: α- and β-RbHgI3·H2O. Journal of Alloys and Compounds 2019, 771 , 547-554. https://doi.org/10.1016/j.jallcom.2018.09.005

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

You’ve supercharged your research process with ACS and Mendeley!

STEP 1:
Click to create an ACS ID

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

OOPS

You have to login with your ACS ID befor you can login with your Mendeley account.

MENDELEY PAIRING EXPIRED
Your Mendeley pairing has expired. Please reconnect

This website uses cookies to improve your user experience. By continuing to use the site, you are accepting our use of cookies. Read the ACS privacy policy.

CONTINUE