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Polymer–MOF Hybrid Composites with High Porosity and Stability through Surface-Selective Ligand Exchange

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Download Hi-Res ImageDownload to MS-PowerPointCite This:Chem. Mater. 2018, 30, 23, 8639-8649
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    Polymer–MOF Hybrid Composites with High Porosity and Stability through Surface-Selective Ligand Exchange
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    Chemistry of Materials

    Cite this: Chem. Mater. 2018, 30, 23, 8639–8649
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    https://doi.org/10.1021/acs.chemmater.8b03881
    Published November 17, 2018
    Copyright © 2018 American Chemical Society
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    Abstract

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    Hybrid materials containing organic polymers and metal–organic frameworks (MOFs) have attracted attention for their potential to harness both diverse functionality and high processability, but their fabrication is challenged by incompatibilities of the parent components. The poor solubility of MOFs hinders uniform dispersion throughout a polymer matrix and may cause aggregation that is not only detrimental to the permeability of substrates, but also limits the structural integrity of the polymer. Meanwhile, polymer chains can block or penetrate the porous structures and compromise MOF functionality by reducing surface area and pore size. We report a versatile method of covalent hybridization through post-synthetic ligand exchange to form a cross-linked polymer–MOF composite. The resulting network structure allows for the formation of robust, monolithic composites with variable MOF loadings that may exceed 80% wherein ligand exchange is limited to surface sites so as to fully preserve MOF surface area and porosity. The synthesis can be performed from a diverse set of inexpensive starting materials, encouraging the design of new functional materials across a wide range of applications.

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.chemmater.8b03881.

    • Video of composite formation (MPG)

    • PXRD diffractograms of MOF-5, PAA, MOF-5/PAA, and MOF-5/PI; PXRD diffractograms of ZIF-8 and ZIF-8/MOF-5 composites; PXRD diffractograms of UiO-66; 1H NMR spectrum of PAA; 1H NMR spectrum of MEPA; 1H NMR spectrum of PVBA; GPC traces of PAA-high, PAA-low, and MEPA; polymer molecular weight data; SEM images of free polymer-coated MOF-5; FT-IR spectra of PAA and PI; FT-IR spectra of MOF-5/PAA and MOF-5/PI; TGA curves of microcrystalline MOF-5, PAA, and microcrystalline MOF-5/PAA; TGA curves of nanocrystalline MOF-5, PAA, and nanocrystalline MOF-5/PAA; TGA curves of ZIF-8, PAA, and ZIF-8/PAA; DSC curves of PAA, microcrystalline MOF-5/PAA, nanocrystalline MOF-5/PAA, and ZIF-8/PAA; N2 adsorption–desorption isotherms of ZIF-8 and ZIF-8/PAA; and N2 adsorption–desorption isotherms of nanocrystalline MOF-5 and nanocrystalline MOF-5/PAA (PDF)

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    8. Matthew A. Pearson, Mircea Dincă, Jeremiah A. Johnson. Radical PolyMOFs: A Role for Ligand Dispersity in Enabling Crystallinity. Chemistry of Materials 2021, 33 (24) , 9508-9514. https://doi.org/10.1021/acs.chemmater.1c02411
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    10. Yansong Jiang, Jing Sun, Xiaona Yang, Jieyu Shen, Yu Fu, Yong Fan, Jianing Xu, Li Wang. Cd-MOF@PVDF Mixed-Matrix Membrane with Good Catalytic Activity and Recyclability for the Production of Benzimidazole and Amino Acid Derivatives. Inorganic Chemistry 2021, 60 (3) , 2087-2096. https://doi.org/10.1021/acs.inorgchem.1c00084
    11. Liang Feng, Kun-Yu Wang, Gregory S. Day, Matthew R. Ryder, Hong-Cai Zhou. Destruction of Metal–Organic Frameworks: Positive and Negative Aspects of Stability and Lability. Chemical Reviews 2020, 120 (23) , 13087-13133. https://doi.org/10.1021/acs.chemrev.0c00722
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    13. Vincent J. Pastore, Timothy R. Cook. Coordination-Driven Self-Assembly in Polymer–Inorganic Hybrid Materials. Chemistry of Materials 2020, 32 (9) , 3680-3700. https://doi.org/10.1021/acs.chemmater.0c00851
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    15. Daniel S. Kissel . Integrating Faculty Research into the Undergraduate Chemistry Curriculum: A CURE Using Porous Composite Materials for Water Remediation. 2020, 79-104. https://doi.org/10.1021/bk-2020-1351.ch005
    16. Mohamed E. Mahmoud, Asmaa K. Mohamed, Mohamed F. Amira, Seleim M. Seleim. Novel Nanostructured Metal–Organic Framework-Bonded Silica Amine and Polymer: Facile Synthesis, Kinetics, Isotherms, and Thermodynamics Evaluation for Adsorption of Yttrium(III) Ions. Journal of Chemical & Engineering Data 2019, 64 (12) , 6060-6070. https://doi.org/10.1021/acs.jced.9b00918
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    23. Brahim Nomeir, Sara Lakhouil, Sofia Boukheir, Mustapha Ait Ali, Sanae Naamane. Recent advances in polymer-based superhydrophobic coatings: preparation, properties, and applications. Journal of Coatings Technology and Research 2024, 132 https://doi.org/10.1007/s11998-024-00955-y
    24. Daeyeon Lee, Sangho Lee, Isaac Choi, Min Kim. Positional functionalizations of metal–organic frameworks through invasive ligand exchange and additory MOF‐on‐MOF strategies: A review. Smart Molecules 2024, 2 (2) https://doi.org/10.1002/smo.20240002
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    26. Fateme Parsapour, Morteza Moradi, Vahid Safarifard, Soheil Sojdeh. Polymer/MOF composites for metal-ion batteries: A mini review. Journal of Energy Storage 2024, 82 , 110487. https://doi.org/10.1016/j.est.2024.110487
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    31. B.D.S Deeraj, Jitha S Jayan, Akhila Raman, Aparna Asok, Rhiya Paul, Appukuttan Saritha, Kuruvilla Joseph. A comprehensive review of recent developments in metal-organic framework/polymer composites and their applications. Surfaces and Interfaces 2023, 43 , 103574. https://doi.org/10.1016/j.surfin.2023.103574
    32. Khaled Dassouki, Sanchari Dasgupta, Eddy Dumas, Nathalie Steunou. Interfacing metal organic frameworks with polymers or carbon-based materials: from simple to hierarchical porous and nanostructured composites. Chemical Science 2023, 14 (45) , 12898-12925. https://doi.org/10.1039/D3SC03659F
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    35. Dudu Li, Ning Li, Wenbin Liu, Shanshan Xu, Yuxiu Sun, Zhihua Qiao, Chongli Zhong. Highly water-stable MOF-74 synthesized by in-situ trace polymer modification. Polymer 2023, 281 , 126112. https://doi.org/10.1016/j.polymer.2023.126112
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    49. Siyi Rong, Pengcheng Su, Shizheng Chen, Miaomiao Jia, Wanbin Li. Sub-5 nm porous polymer decoration toward superhydrophobic MOFs with enhanced stability and processability. Chinese Chemical Letters 2022, 33 (4) , 2134-2138. https://doi.org/10.1016/j.cclet.2021.09.012
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    53. Ming-Ming Xu, Lin-Hua Xie, Jian-Rong Li. Metal–Organic Framework/Polymer Hybrid Materials. 2021, 72-97. https://doi.org/10.1039/9781839163456-00072
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    56. Gregory W. Peterson, Dennis T. Lee, Heather F. Barton, Thomas H. Epps, Gregory N. Parsons. Fibre-based composites from the integration of metal–organic frameworks and polymers. Nature Reviews Materials 2021, 6 (7) , 605-621. https://doi.org/10.1038/s41578-021-00291-2
    57. Fazheng Jin, Jinjin Liu, Yao Chen, Zhenjie Zhang. Tethering Flexible Polymers to Crystalline Porous Materials: A Win–Win Hybridization Approach. Angewandte Chemie 2021, 133 (26) , 14342-14355. https://doi.org/10.1002/ange.202011213
    58. Fazheng Jin, Jinjin Liu, Yao Chen, Zhenjie Zhang. Tethering Flexible Polymers to Crystalline Porous Materials: A Win–Win Hybridization Approach. Angewandte Chemie International Edition 2021, 60 (26) , 14222-14235. https://doi.org/10.1002/anie.202011213
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    61. Vishnu Unnikrishnan, Omid Zabihi, Mojtaba Ahmadi, Quanxiang Li, Patrick Blanchard, Alper Kiziltas, Minoo Naebe. Metal–organic framework structure–property relationships for high-performance multifunctional polymer nanocomposite applications. Journal of Materials Chemistry A 2021, 9 (8) , 4348-4378. https://doi.org/10.1039/D0TA11255K
    62. Vincent J. Pastore, Meghan G. Sullivan, Javid Rzayev, Timothy R. Cook. Postsynthetic polymer-ligand exchange hybridization in M-MOF-74 composites. Journal of Coordination Chemistry 2021, 74 (1-3) , 178-189. https://doi.org/10.1080/00958972.2021.1876852
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    64. Nurul N. M. Ishak, N. N. M. Khiruddin, N. Nasri, T. B. S. A. Ravoof. Metal-Organic Frameworks (MOFs). 2021, 105-146. https://doi.org/10.1007/978-3-030-62761-4_5
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    72. Yuwei Gu, Julia Zhao, Jeremiah A. Johnson. Polymer Networks: From Plastics and Gels to Porous Frameworks. Angewandte Chemie International Edition 2020, 59 (13) , 5022-5049. https://doi.org/10.1002/anie.201902900
    73. Bernhard V. K. J. Schmidt. Metal‐Organic Frameworks in Polymer Science: Polymerization Catalysis, Polymerization Environment, and Hybrid Materials. Macromolecular Rapid Communications 2020, 41 (1) https://doi.org/10.1002/marc.201900333
    74. Dimitrios Giliopoulos, Alexandra Zamboulis, Dimitrios Giannakoudakis, Dimitrios Bikiaris, Konstantinos Triantafyllidis. Polymer/Metal Organic Framework (MOF) Nanocomposites for Biomedical Applications. Molecules 2020, 25 (1) , 185. https://doi.org/10.3390/molecules25010185
    75. Zhouqing Xu, Jiwei Wang, Huijun Li, Yan Wang. Coating sponge with multifunctional and porous metal-organic framework for oil spill remediation. Chemical Engineering Journal 2019, 370 , 1181-1187. https://doi.org/10.1016/j.cej.2019.03.288
    76. Mohamed H. Hassan, Mohamed H. Alkordi, Abdou Hassanien. Probing the conductivity of metal-organic framework-graphene nanocomposite. Materials Letters 2019, 246 , 13-16. https://doi.org/10.1016/j.matlet.2019.02.124
    77. Ross S. Forgan. The surface chemistry of metal–organic frameworks and their applications. Dalton Transactions 2019, 48 (25) , 9037-9042. https://doi.org/10.1039/C9DT01710K
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    Cite this: Chem. Mater. 2018, 30, 23, 8639–8649
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    https://doi.org/10.1021/acs.chemmater.8b03881
    Published November 17, 2018
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