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Synthesis of Polycrystalline Ruddlesden–Popper Organic Lead Halides and Their Growth Dynamics

  • Raphael F. Moral
    Raphael F. Moral
    Laboratório de Nanotecnologia e Energia Solar, Chemistry Institute, University of Campinas, Campinas 13083-970, Sao Paulo, Brazil
  • Luiz Gustavo Bonato
    Luiz Gustavo Bonato
    Laboratório de Nanotecnologia e Energia Solar, Chemistry Institute, University of Campinas, Campinas 13083-970, Sao Paulo, Brazil
  • José Carlos Germino
    José Carlos Germino
    Laboratório de Nanotecnologia e Energia Solar, Chemistry Institute, University of Campinas, Campinas 13083-970, Sao Paulo, Brazil
  • Willian Xerxes Coelho Oliveira
    Willian Xerxes Coelho Oliveira
    Laboratório de Nanotecnologia e Energia Solar, Chemistry Institute, University of Campinas, Campinas 13083-970, Sao Paulo, Brazil
    Departamento de Química, Institudo de Ciências Exatas, Universidade Federal de Minas Gerais, Belo Horizonte 31270-901, Minas Gerais, Brazil
  • Rupini Kamat
    Rupini Kamat
    SLAC National Accelerator Laboratory, Stanford Synchrotron Radiation Lightsource, Menlo Park, California 94025, United States
    Department of Applied Physics, Stanford University, Stanford, California 94305, United States
    More by Rupini Kamat
  • Junwei Xu
    Junwei Xu
    SLAC National Accelerator Laboratory, Stanford Synchrotron Radiation Lightsource, Menlo Park, California 94025, United States
    More by Junwei Xu
  • Christopher J. Tassone
    Christopher J. Tassone
    SLAC National Accelerator Laboratory, Stanford Synchrotron Radiation Lightsource, Menlo Park, California 94025, United States
  • Samuel D. Stranks
    Samuel D. Stranks
    Cavendish Laboratory, University of Cambridge, 19 JJ Thomson Avenue, Cambridge CB3 0HE, United Kingdom
  • Michael F. Toney
    Michael F. Toney
    SLAC National Accelerator Laboratory, Stanford Synchrotron Radiation Lightsource, Menlo Park, California 94025, United States
  • , and 
  • Ana Flávia Nogueira*
    Ana Flávia Nogueira
    Laboratório de Nanotecnologia e Energia Solar, Chemistry Institute, University of Campinas, Campinas 13083-970, Sao Paulo, Brazil
    *E-mail: [email protected]. Web: www.lnes.iqm.unicamp.br.
Cite this: Chem. Mater. 2019, 31, 22, 9472–9479
Publication Date (Web):October 25, 2019
https://doi.org/10.1021/acs.chemmater.9b03439
Copyright © 2019 American Chemical Society

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    Abstract

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    Ruddlesden–Popper organic lead halides (RPOLHs) are in the material science spotlight because of their remarkable optoelectronic properties, tailorable compositions, and improved ambient stability over their three-dimensional perovskite analogues. In this report, we introduce a new synthesis method for RPOLHs with general composition L2[FAPbI3]n−1PbI4 [L = butylammonium (BA) or benzylammonium (BZA), FA = formamidinium, and n = 1 and 2]. Our method yields polycrystalline materials useful for thin-film fabrication for optoelectronic applications. Furthermore, we report the growth dynamics of BA2[FAPbI3]PbI4 using in situ small-angle X-ray scattering, revealing that the slabs grow within the first seconds of the reaction and then self-assemble into bulk crystallites.

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.chemmater.9b03439.

    • Lattice constants from Rietveld refinement, GI-XRD color maps, TGA data, and optical characterizations (PDF)

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