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From Waste-Heat Recovery to Refrigeration: Compositional Tuning of Magnetocaloric Mn1+xSb

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    From Waste-Heat Recovery to Refrigeration: Compositional Tuning of Magnetocaloric Mn1+xSb
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    • Joya A. Cooley
      Joya A. Cooley
      Materials Research Laboratory, University of California Santa Barbara, Santa Barbara, California 93106, United States
      More by Joya A. Cooley
      Orcidhttp://orcid.org/0000-0001-7187-3261
    • Matthew K. Horton
      Matthew K. Horton
      Energy Storage and Distributed Resources Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States
      More by Matthew K. Horton
      Orcidhttp://orcid.org/0000-0001-7777-8871
    • Emily E. Levin
      Emily E. Levin
      Materials Research Laboratory, University of California Santa Barbara, Santa Barbara, California 93106, United States
      Materials Department, University of California Santa Barbara, Santa Barbara, California 93106, United States
      More by Emily E. Levin
      Orcidhttp://orcid.org/0000-0002-8663-8018
    • Saul H. Lapidus
      Saul H. Lapidus
      X-ray Sciences Division, Argonne National Laboratory, Lemont, Illinois 60439, United States
      More by Saul H. Lapidus
    • Kristin A. Persson
      Kristin A. Persson
      Energy Storage and Distributed Resources Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States
      Materials Science and Engineering, University of California Berkeley, Berkeley, California 94720, United States
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      Orcidhttp://orcid.org/0000-0003-2495-5509
    • Ram Seshadri*
      Ram Seshadri
      Materials Research Laboratory, University of California Santa Barbara, Santa Barbara, California 93106, United States
      Materials Department, University of California Santa Barbara, Santa Barbara, California 93106, United States
      Department of Chemistry and Biochemistry, University of California Santa Barbara, Santa Barbara, California 93106, United States
      *E-mail: [email protected]
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      Orcidhttp://orcid.org/0000-0001-5858-4027
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    Chemistry of Materials

    Cite this: Chem. Mater. 2020, 32, 3, 1243–1249
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    https://doi.org/10.1021/acs.chemmater.9b04643
    Published January 22, 2020
    Copyright © 2020 American Chemical Society
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    Abstract

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    Magnetic refrigeration, as well as waste-heat recovery, can be accomplished through the magnetocaloric effect, where temperature changes the magnetic state of a material or vice versa. Promising magnetocaloric materials display large changes in magnetic entropy (ΔSM) upon application of a moderate magnetic field and are often associated with magnetic materials possessing some degree of magnetostructural coupling. In such compounds, the magnetic transition is coupled to some structural transition at the ordering temperature, and indicators for these are readily calculated by the magnetic deformation proxy ΣM. MnSb, with a Curie temperature TC = 577 K, has a calculated magnetic deformation of ΣM = 5.9% and is a promising candidate material for waste-heat recovery. The temperature dependence of structural, magnetic, and magnetocaloric properties of Mn1+xSb, where x is a tunable amount of interstitial Mn, is studied here. Excess Mn is incorporated as an interstitial whose magnetic moment is antialigned with the stoichiometric Mn, and the excess Mn has the effect of lowering TC, such that the Curie temperature can be tuned from 577 K to nearly room temperature at 318 K for x = 0.2. For x = 0.0, 0.1, and 0.2, values of ΔSM under a maximum magnetic field H = 5 T are found to be 3.65, 3.00, and 2.83 J K–1 kg–1, respectively. While the maximum ΔSM decreases with x, the high refrigerant capacity—a more holistic measure of performance—is retained in this highly tunable system.

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.chemmater.9b04643.

    • Details of compositional analysis by EDS, Rietveld refinement, and magnetic properties of all samples; synchrotron XRD data and Rietveld refinements, Arrott plots, and calculated ΔSM plots (PDF)

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    Chemistry of Materials

    Cite this: Chem. Mater. 2020, 32, 3, 1243–1249
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.chemmater.9b04643
    Published January 22, 2020
    Copyright © 2020 American Chemical Society
    Request reuse permissions

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