Physicochemical Concepts of the Lithium Metal Anode in Solid-State BatteriesClick to copy article linkArticle link copied!
- Thorben Krauskopf*Thorben Krauskopf*Email: [email protected]Institute of Physical Chemistry, Justus-Liebig-University Giessen, Heinrich-Buff-Ring 17, D-35392 Giessen, GermanyMore by Thorben Krauskopf
- Felix H. RichterFelix H. RichterInstitute of Physical Chemistry, Justus-Liebig-University Giessen, Heinrich-Buff-Ring 17, D-35392 Giessen, GermanyCenter for Materials Research (LaMa), Justus-Liebig-University Giessen, Heinrich-Buff-Ring 16, D-35392 Giessen, GermanyMore by Felix H. Richter
- Wolfgang G. ZeierWolfgang G. ZeierInstitute of Inorganic and Analytical Chemistry, University of Münster, Correnstrasse 30, 48149 Münster, GermanyMore by Wolfgang G. Zeier
- Jürgen Janek*Jürgen Janek*Email: [email protected]Institute of Physical Chemistry, Justus-Liebig-University Giessen, Heinrich-Buff-Ring 17, D-35392 Giessen, GermanyCenter for Materials Research (LaMa), Justus-Liebig-University Giessen, Heinrich-Buff-Ring 16, D-35392 Giessen, GermanyMore by Jürgen Janek
Abstract
Developing reversible lithium metal anodes with high rate capability is one of the central aims of current battery research. Lithium metal anodes are not only required for the development of innovative cell concepts such as lithium–air or lithium–sulfur batteries, they can also increase the energy density of batteries with intercalation-type cathodes. The use of solid electrolyte separators is especially promising to develop well-performing lithium metal anodes, because they can act as a mechanical barrier to avoid unwanted dendritic growth of lithium through the cell. However, inhomogeneous electrodeposition and contact loss often hinder the application of a lithium metal anode in solid-state batteries. In this review, we assess the physicochemical concepts that describe the fundamental mechanisms governing lithium metal anode performance in combination with inorganic solid electrolytes. In particular, our discussion of kinetic rate limitations and morphological stability intends to stimulate further progress in the field of lithium metal anodes.
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