ACS Publications. Most Trusted. Most Cited. Most Read
My Activity
CONTENT TYPES

Atomically Precise Colloidal Metal Nanoclusters and Nanoparticles: Fundamentals and Opportunities

View Author Information
Department of Chemistry, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213, United States
Cite this: Chem. Rev. 2016, 116, 18, 10346–10413
Publication Date (Web):September 1, 2016
https://doi.org/10.1021/acs.chemrev.5b00703
Copyright © 2016 American Chemical Society

    Article Views

    48449

    Altmetric

    -

    Citations

    LEARN ABOUT THESE METRICS
    Other access options

    Abstract

    Abstract Image

    Colloidal nanoparticles are being intensely pursued in current nanoscience research. Nanochemists are often frustrated by the well-known fact that no two nanoparticles are the same, which precludes the deep understanding of many fundamental properties of colloidal nanoparticles in which the total structures (core plus surface) must be known. Therefore, controlling nanoparticles with atomic precision and solving their total structures have long been major dreams for nanochemists. Recently, these goals are partially fulfilled in the case of gold nanoparticles, at least in the ultrasmall size regime (1–3 nm in diameter, often called nanoclusters). This review summarizes the major progress in the field, including the principles that permit atomically precise synthesis, new types of atomic structures, and unique physical and chemical properties of atomically precise nanoparticles, as well as exciting opportunities for nanochemists to understand very fundamental science of colloidal nanoparticles (such as the stability, metal–ligand interfacial bonding, ligand assembly on particle surfaces, aesthetic structural patterns, periodicities, and emergence of the metallic state) and to develop a range of potential applications such as in catalysis, biomedicine, sensing, imaging, optics, and energy conversion. Although most of the research activity currently focuses on thiolate-protected gold nanoclusters, important progress has also been achieved in other ligand-protected gold, silver, and bimetal (or alloy) nanoclusters. All of these types of unique nanoparticles will bring unprecedented opportunities, not only in understanding the fundamental questions of nanoparticles but also in opening up new horizons for scientific studies of nanoparticles.

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.

    Cited By

    This article is cited by 2447 publications.

    1. Lisa-Sofie Wagner, Oleg Prymak, Torsten Schaller, Christine Beuck, Kateryna Loza, Felix Niemeyer, Nina Gumbiowski, Kathrin Kostka, Peter Bayer, Marc Heggen, Cristiano L. P. Oliveira, Matthias Epple. The Molecular Footprint of Peptides on the Surface of Ultrasmall Gold Nanoparticles (2 nm) Is Governed by Steric Demand. The Journal of Physical Chemistry B 2024, Article ASAP.
    2. Miaoyu Wang, Fangzhen Tian, Qi Xin, Huizhen Ma, Ling Liu, Shuyu Yang, Si Sun, Nan Song, KeXin Tan, Zhenhua Li, Lijie Zhang, Qi Wang, Liefeng Feng, Hao Wang, Zhidong Wang, Xiao-Dong Zhang. In Vivo Toxicology of Metabolizable Atomically Precise Au25 Clusters at Ultrahigh Doses. Bioconjugate Chemistry 2024, 35 (4) , 540-550. https://doi.org/10.1021/acs.bioconjchem.4c00113
    3. Le Yang, Fahime Bigdeli, Xiaojiao Yang, Lin-Lin Hou, Yue Ma, Wen-Ya Jiang, Xian-Hao Li, Ling-Xiao Wang, Tang Yang, Kangzhou Wang, Jianyu Wei, Ali Morsali, Kuan-Guan Liu. Molybdate-Templated Luminescent Silver Alkynyl Nanoclusters: Total Structure Determination and Optical Property Analysis. Inorganic Chemistry 2024, Article ASAP.
    4. Yitong Wang, Christopher G. Gianopoulos, Zhongyu Liu, Kristin Kirschbaum, Dominic Alfonso, Douglas R. Kauffman, Rongchao Jin. Au36(SR)22 Nanocluster and a Periodic Pattern from Six to Fourteen Free Electrons in Core Size Evolution. JACS Au 2024, Article ASAP.
    5. Yuki Fujiwara, Shun Ito, Kiichirou Koyasu, Tatsuya Tsukuda. Gas-Phase Structures of [Au21(SR)14]− and [Au17(SR)10]− with Eight Electrons: Can They Support an Icosahedral Au13 Core?. The Journal of Physical Chemistry A 2024, Article ASAP.
    6. Yaxuan Shi, Yuying Li, Qifu Liu, Linan Wang, Junle Zhang, Ge Shi, Xiaoguang Qiao, Yanjie He, Wenjie Zhang, Xinchang Pang. Confined Unimolecular Micelles for Directed Self-Assembly of Ultrastable Multiple-Responsive Ratiometric Fluorescent Ultrasmall Nanoparticle Assemblies. The Journal of Physical Chemistry Letters 2024, Article ASAP.
    7. Athulya Kadeprath Satheesan, Nikhil Puthiya Purayil, Jatinderbir Singh, Chandrasekharan Keloth. Tamm Plasmon-Mediated Tunable Absorption Switching in Atomically Precise Pt17 Nanoclusters for Nonlinear Photonic Applications. ACS Applied Nano Materials 2024, 7 (7) , 7486-7495. https://doi.org/10.1021/acsanm.4c00188
    8. Kazuya Terasaka, Toshiaki Kamoshida, Takumi Ichikawa, Takaho Yokoyama, Masahiro Shibuta, Miho Hatanaka, Atsushi Nakajima. Alkaline Earth Metal Superatom of W@Si16: Characterization of Group 6 Metal Encapsulating Si16 Cage on Organic Substrates. Journal of the American Chemical Society 2024, 146 (14) , 9605-9613. https://doi.org/10.1021/jacs.3c12619
    9. Ying Zhang, Wei Zhang, Tai-Song Zhang, Chao Ge, Yang Tao, Wenwen Fei, Weigang Fan, Meng Zhou, Man-Bo Li. Site-Recognition-Induced Structural and Photoluminescent Evolution of the Gold–Pincer Nanocluster. Journal of the American Chemical Society 2024, 146 (14) , 9631-9639. https://doi.org/10.1021/jacs.3c12982
    10. Mengge Bai, Lin Qin, Xiang-Ming Zeng, Minjian Wu, Liao-Yuan Yao, Guo-Yu Yang. Dithiocarbonate-Protected Au25 Nanorods of a Chiral D5 Configuration and NIR-II Phosphorescence. Journal of the American Chemical Society 2024, Article ASAP.
    11. Qing You, He Wang, Yan Zhao, Wentao Fan, Wanmiao Gu, Hai-Long Jiang, Zhikun Wu. Bottom-Up Construction of Metal–Organic Framework Loricae on Metal Nanoclusters with Consecutive Single Nonmetal Atom Tuning for Tailored Catalysis. Journal of the American Chemical Society 2024, 146 (13) , 9026-9035. https://doi.org/10.1021/jacs.3c13635
    12. Daniel J. Heintzelman, Seth A. Nelson, Kenneth L. Knappenberger, Jr.. Influence of Halogen–Solvent Hydrogen Bonding on Gold Nanocluster Photoluminescence. The Journal of Physical Chemistry Letters 2024, 15 (11) , 2951-2956. https://doi.org/10.1021/acs.jpclett.4c00197
    13. Chunwei Dong, Xin Song, Bashir E. Hasanov, Youyou Yuan, Luis Gutiérrez-Arzaluz, Peng Yuan, Saidkhodzha Nematulloev, Mehmet Bayindir, Omar F. Mohammed, Osman M. Bakr. Organic–Inorganic Hybrid Glasses of Atomically Precise Nanoclusters. Journal of the American Chemical Society 2024, 146 (11) , 7373-7385. https://doi.org/10.1021/jacs.3c12296
    14. Zhe Wang, Chunchun Zhang, Shanling Wang, Meng Zhang, Xiaoqin Chen, Chaoran Luan, Kui Yu. Formation and Transformation of ZnTe and CdTe Magic-Size Clusters Assisted by Their Precursor Compounds. Chemistry of Materials 2024, 36 (5) , 2520-2532. https://doi.org/10.1021/acs.chemmater.3c03309
    15. Zhiling Liu, Yufeng Yang, Yonghong Yan, Xiaoyue Yao, Fuqiang Zhang, Jianfeng Jia, Ya Li. Structural and Chemical Bonding Properties of AuS2H0/–: A Photoelectron Velocity-Map Imaging Spectroscopic and Theoretical Study. The Journal of Physical Chemistry A 2024, 128 (9) , 1646-1655. https://doi.org/10.1021/acs.jpca.4c00089
    16. Emily L. Albright, Tetyana I. Levchenko, Viveka K. Kulkarni, Angus I. Sullivan, Joseph F. DeJesus, Sami Malola, Shinjiro Takano, Masakazu Nambo, Kevin Stamplecoskie, Hannu Häkkinen, Tatsuya Tsukuda, Cathleen M. Crudden. N-Heterocyclic Carbene-Stabilized Atomically Precise Metal Nanoclusters. Journal of the American Chemical Society 2024, 146 (9) , 5759-5780. https://doi.org/10.1021/jacs.3c11031
    17. Xi Fan, Kexiu Zuo, Furong Yuan, Yunbin Li, Lu Li, Si Lin, Jiali Huang, Shengchang Xiang, Jia-Qi Wang, Zhangjing Zhang. High-Nuclear Alkynyl Cu(I) Cluster-Based Framework for Efficient Xe/Kr Separation. ACS Materials Letters 2024, 6 (3) , 1007-1011. https://doi.org/10.1021/acsmaterialslett.3c01630
    18. Yanshuang Li, Chaoqiang Yan, Endong Wang, Wen Wu Xu. Proposed Structural Model for Chiral Au40(SC2H4Ph)24 Nanoclusters. The Journal of Physical Chemistry Letters 2024, 15 (8) , 2241-2246. https://doi.org/10.1021/acs.jpclett.4c00130
    19. Mengting Cui, Yanan Shi, Xiangyu Ma, Qingliang Li, Ling Chen, Lichao Zhang, Junfei Wu, Haizhu Yu, Manzhou Zhu. The Pivotal Radical Intermediate [Au21(SR)15]+ in the Ligand-Exchange-Induced Size-Reduction of [Au23(SR)16]− to Au16(SR)12. ACS Nano 2024, 18 (8) , 6591-6599. https://doi.org/10.1021/acsnano.3c12765
    20. Vikas Tiwari, Sonali Garg, Tarak Karmakar. Insights into the Interactions of Peptides with Monolayer-Protected Metal Nanoclusters. ACS Applied Bio Materials 2024, 7 (2) , 685-691. https://doi.org/10.1021/acsabm.2c00997
    21. Jie Tang, Kexin Jia, Ruiqi Zhang, Chao Liu, Xinzhang Lin, Tingting Ge, Xiaorui Liu, Qiao Zhao, Wei Liu, Ding Ma, Hongjun Fan, Jiahui Huang. Selective Hydrogenation of Alkyne by Atomically Precise Pd6 Nanocluster Catalysts: Accurate Construction of the Coplanar and Specific Active Sites. ACS Catalysis 2024, 14 (4) , 2463-2472. https://doi.org/10.1021/acscatal.3c05833
    22. Jianxun Lu, Bingyao Shao, Ren-Wu Huang, Luis Gutiérrez-Arzaluz, Shulin Chen, Zhen Han, Jun Yin, Hongwei Zhu, Sergey Dayneko, Mohamed Nejib Hedhili, Xin Song, Peng Yuan, Chunwei Dong, Renqian Zhou, Makhsud I. Saidaminov, Shuang-Quan Zang, Omar F. Mohammed, Osman M. Bakr. High-Efficiency Circularly Polarized Light-Emitting Diodes Based on Chiral Metal Nanoclusters. Journal of the American Chemical Society 2024, 146 (6) , 4144-4152. https://doi.org/10.1021/jacs.3c13065
    23. Emily L. Albright, Sami Malola, Samuel I. Jacob, Hong Yi, Shinjiro Takano, Koichi Mimura, Tatsuya Tsukuda, Hannu Häkkinen, Masakazu Nambo, Cathleen M. Crudden. Enantiopure Chiral Au13 Nanoclusters Stabilized by Ditopic N-Heterocyclic Carbenes: Synthesis, Characterization, and Electrocatalytic Reduction of CO2. Chemistry of Materials 2024, 36 (3) , 1279-1289. https://doi.org/10.1021/acs.chemmater.3c02288
    24. Hao-Nan Qin, Meng-Wei He, Jie Wang, Hai-Yang Li, Zhao-Yang Wang, Shuang-Quan Zang, Thomas C. W. Mak. Thiacalix[4]arene Etching of an Anisotropic Cu70H22 Intermediate for Accessing Robust Modularly Assembled Copper Nanoclusters. Journal of the American Chemical Society 2024, 146 (5) , 3545-3552. https://doi.org/10.1021/jacs.3c13965
    25. Riki Nakatani, Sourav Biswas, Tsukasa Irie, Yoshiki Niihori, Saikat Das, Yuichi Negishi. Unlocking the Potential of an Atom-Precise Ag12 Cluster Assembled Material as a Highly Efficient SERS Sensor for the Detection of Hg2+ Ions. ACS Materials Letters 2024, 6 (2) , 438-445. https://doi.org/10.1021/acsmaterialslett.3c01198
    26. Jian Yao, Lili Shao, Xi Kang, Manzhou Zhu, Xiaohong Huo, Xiaoming Wang. Direct α-Arylation of Benzo[b]furans Catalyzed by a Pd3 Cluster. The Journal of Organic Chemistry 2024, 89 (3) , 1719-1726. https://doi.org/10.1021/acs.joc.3c02428
    27. Sourav Biswas, Yuichi Negishi. A Comprehensive Analysis of Luminescent Crystallized Cu Nanoclusters. The Journal of Physical Chemistry Letters 2024, 15 (4) , 947-958. https://doi.org/10.1021/acs.jpclett.3c03374
    28. Anushna Bhattacharyya, Vikas Tiwari, Tarak Karmakar. Electrostatic-Driven Self-Assembly of Janus-like Monolayer-Protected Metal Nanoclusters. The Journal of Physical Chemistry Letters 2024, 15 (3) , 687-692. https://doi.org/10.1021/acs.jpclett.3c03508
    29. Bingzheng Yan, Xuexin You, Xiongkai Tang, Jing Sun, Qinghua Xu, Lin Wang, Zong-Jie Guan, Fengyu Li, Hui Shen. Carboxylate-Protected “Isostructural” Cu20 Nanoclusters as a Model System: Carboxylate Effect on Controlling Catalysis. Chemistry of Materials 2024, 36 (2) , 1004-1012. https://doi.org/10.1021/acs.chemmater.3c03131
    30. Qi Zhou, Yuting Du, Liya Zhang, Ding Yi. Structural Evolution of Pt Nanoclusters on Graphene Moiré Superlattices. The Journal of Physical Chemistry C 2024, 128 (2) , 968-973. https://doi.org/10.1021/acs.jpcc.3c07123
    31. Yanming Liu, Hao Li, Xuejuan Zou, Xi Kang, Manzhou Zhu. Parasitism in Metal Nanoclusters: A Case Study of (AuAg)25·(AuAg)27. ACS Nano 2024, 18 (2) , 1555-1562. https://doi.org/10.1021/acsnano.3c09207
    32. Huiyan Xie, Yuqing Wang, Na Zhang, Shulin Li, Jinrui Li, Xia Xin. Solvent-Induced Self-Assembly of Silver Nanoclusters for White-Light-Emitting Diodes and Temperature Sensing. ACS Applied Nano Materials 2024, 7 (1) , 1009-1018. https://doi.org/10.1021/acsanm.3c05006
    33. Subarna Maity, Shinjiro Takano, Shinya Masuda, Tatsuya Tsukuda. Bonding and Electronic Interactions of Hydrogen with Gold Superatoms. The Journal of Physical Chemistry C 2024, 128 (1) , 19-30. https://doi.org/10.1021/acs.jpcc.3c07090
    34. Zhi Wang, Hui Zhao, Ying-Zhou Li, Chengkai Zhang, Rakesh Kumar Gupta, Chen-Ho Tung, Di Sun. Thiacalix[4]arene-Protected Silver Nanoclusters Encapsulating Different Two-Electron Superatom Oligomers. Nano Letters 2024, 24 (1) , 458-465. https://doi.org/10.1021/acs.nanolett.3c04307
    35. Sikta Chakraborty, Sarita Kolay, Subarna Maity, Amitava Patra. Copper Nanoclusters as Multienzymes Mimic Activities of Oxidase and Ascorbic Acid Oxidase in the Presence of Imidazole. Langmuir 2024, 40 (1) , 317-324. https://doi.org/10.1021/acs.langmuir.3c02570
    36. Jing Sun, Xiongkai Tang, Zhuang-Hua Liu, Zhenlang Xie, Bingzheng Yan, Runfang Yin, Chaolumen Chaolumen, Jian Zhang, Weihui Fang, Jianyu Wei, Hui Shen. Labile Ligands Protected Cu50 Nanoclusters with Tailorable Optical Limiting Effect. ACS Materials Letters 2024, 6 (1) , 281-289. https://doi.org/10.1021/acsmaterialslett.3c01305
    37. Papri Chakraborty, Sami Malola, Patrick Weis, Marco Neumaier, Erik Karsten Schneider, Hannu Häkkinen, Manfred M. Kappes. Tailoring Vacancy Defects in Isolated Atomically Precise Silver Clusters through Mercury-Doped Intermediates. The Journal of Physical Chemistry Letters 2023, 14 (51) , 11659-11664. https://doi.org/10.1021/acs.jpclett.3c02866
    38. Chang Liu, Yanshuang Li, Zongbing He, Ying Yang, Chao Wu, Weigang Fan, Wen Wu Xu, Man-Bo Li. Reduction–Oxidation Cascade Strategy for Reforming a Au13-Kerneled Gold Thiolate Nanocluster. The Journal of Physical Chemistry Letters 2023, 14 (51) , 11558-11564. https://doi.org/10.1021/acs.jpclett.3c03021
    39. Yun Hu, Qian Zhang, Jie Zhou, Shan Guo, Jia Xu, Hao Zheng, Yang Yang. Supramolecularly Dimeric Assemble of Planar Cu13 Clusters Controlled by the Length of Spacers of Diphosphine. Inorganic Chemistry 2023, 62 (51) , 21091-21100. https://doi.org/10.1021/acs.inorgchem.3c02992
    40. Xianwei Wang, Jiangtao Zhao, Henrik Eliasson, Rolf Erni, Abolfazl Ziarati, Siobhan Mckeown Walker, Thomas Bürgi. Very Low Temperature CO Oxidation over Atomically Precise Au25 Nanoclusters on MnO2. Journal of the American Chemical Society 2023, 145 (50) , 27273-27281. https://doi.org/10.1021/jacs.3c06372
    41. Hunter H. Ripberger, Kyle J. Schnitzenbaumer, Lily K. Nguyen, Dylan M. Ladd, Kelsey R. Levine, Damara G. Dayton, Michael F. Toney, Brandi M. Cossairt. Navigating the Potential Energy Surface of CdSe Magic-Sized Clusters: Synthesis and Interconversion of Atomically Precise Nanocrystal Polymorphs. Journal of the American Chemical Society 2023, 145 (50) , 27480-27492. https://doi.org/10.1021/jacs.3c08897
    42. Kouta Yoshida, Daichi Arima, Masaaki Mitsui. Dissecting the Triplet-State Properties and Intersystem Crossing Mechanism of the Ligand-Protected Au13 Superatom. The Journal of Physical Chemistry Letters 2023, 14 (49) , 10967-10973. https://doi.org/10.1021/acs.jpclett.3c02977
    43. Xueke Yu, Wei Pei, Wen-wu Xu, Yang Zhao, Yan Su, Jijun Zhao. Core-Packing-Related Vibrational Properties of Thiol-Protected Gold Nanoclusters and Their Excited-State Behavior. Inorganic Chemistry 2023, 62 (49) , 20450-20457. https://doi.org/10.1021/acs.inorgchem.3c03482
    44. Priyanka Chandrashekar, Milan Kumar Jena, Gokul Krishnan, Biswarup Pathak, Sukhendu Mandal. Photoluminescence Properties of a Chiral One-Dimensional Silver Chalcogenolate Chain. Inorganic Chemistry 2023, 62 (49) , 20288-20295. https://doi.org/10.1021/acs.inorgchem.3c03292
    45. Matthias Epple, Vincent M. Rotello, Kenneth Dawson. The Why and How of Ultrasmall Nanoparticles. Accounts of Chemical Research 2023, 56 (23) , 3369-3378. https://doi.org/10.1021/acs.accounts.3c00459
    46. Cheng Xu, Yuhao Jin, Hao Fang, Huijuan Zheng, Jesse C. Carozza, Yanxiong Pan, Ping-Jie Wei, Zhenyi Zhang, Zheng Wei, Zheng Zhou, Haixiang Han. A High-Nuclearity Copper Sulfide Nanocluster [S-Cu50] Featuring a Double-Shell Structure Configuration with Cu(II)/Cu(I) Valences. Journal of the American Chemical Society 2023, 145 (47) , 25673-25685. https://doi.org/10.1021/jacs.3c08549
    47. Vanesa Manzaneda-González, Kellie Jenkinson, Ovidio Peña-Rodríguez, Olivia Borrell-Grueiro, Sergio Triviño-Sánchez, Luis Bañares, Elena Junquera, Ana Espinosa, Guillermo González-Rubio, Sara Bals, Andrés Guerrero-Martínez. From Multi- to Single-Hollow Trimetallic Nanocrystals by Ultrafast Heating. Chemistry of Materials 2023, 35 (22) , 9603-9612. https://doi.org/10.1021/acs.chemmater.3c01698
    48. Rashi, Vishaldeep Kaur, Aarti Devi, Dipankar Bain, Tapasi Sen, Amitava Patra. Probing the Fluorescence Intermittency of Bimetallic Nanoclusters using Single-Molecule Fluorescence Spectroscopy. The Journal of Physical Chemistry Letters 2023, 14 (45) , 10166-10172. https://doi.org/10.1021/acs.jpclett.3c02823
    49. Russel Cruz Sevilla, Ruth Jeane Soebroto, Irwan Saleh Kurniawan, Po-Wen Chen, Sheng Hsiung Chang, Ji-Lin Shen, Wu-Ching Chou, Jui-Ming Yeh, Hsiu-Ying Huang, Chi-Tsu Yuan. Self-Trapped, Thermally Equilibrated Delayed Fluorescence Enables Low-Reabsorption Luminescent Solar Concentrators Based on Gold-Doped Silver Nanoclusters. ACS Applied Materials & Interfaces 2023, 15 (45) , 53136-53145. https://doi.org/10.1021/acsami.3c13710
    50. Vera Truttmann, Adea Loxha, Rareş Banu, Ernst Pittenauer, Sami Malola, María Francisca Matus, Yuchen Wang, Elizabeth A. Ploetz, Günther Rupprechter, Thomas Bürgi, Hannu Häkkinen, Christine Aikens, Noelia Barrabés. Directing Intrinsic Chirality in Gold Nanoclusters: Preferential Formation of Stable Enantiopure Clusters in High Yield and Experimentally Unveiling the “Super” Chirality of Au144. ACS Nano 2023, 17 (20) , 20376-20386. https://doi.org/10.1021/acsnano.3c06568
    51. Natalie Wolff, Kateryna Loza, Marc Heggen, Torsten Schaller, Felix Niemeyer, Peter Bayer, Christine Beuck, Cristiano L. P. Oliveira, Oleg Prymak, Claudia Weidenthaler, Matthias Epple. Ultrastructure and Surface Composition of Glutathione-Terminated Ultrasmall Silver, Gold, Platinum, and Alloyed Silver–Platinum Nanoparticles (2 nm). Inorganic Chemistry 2023, 62 (42) , 17470-17485. https://doi.org/10.1021/acs.inorgchem.3c02879
    52. Rong-Jia Wei, Mo Xie, Ri-Qin Xia, Jun Chen, Hua-Juan Hu, Guo-Hong Ning, Dan Li. Gold(I)-Organic Frameworks as Catalysts for Carboxylation of Alkynes with CO2. Journal of the American Chemical Society 2023, 145 (41) , 22720-22727. https://doi.org/10.1021/jacs.3c08262
    53. Anish Kumar Das, Sourav Biswas, Arijit Kayal, Arthur C. Reber, Subhrajyoti Bhandary, Deepak Chopra, Joy Mitra, Shiv N. Khanna, Sukhendu Mandal. Two-Dimensional Silver-Chalcogenolate-Based Cluster-Assembled Material: A p-type Semiconductor. Nano Letters 2023, 23 (19) , 8923-8931. https://doi.org/10.1021/acs.nanolett.3c02269
    54. Xiaoxuan Xu, Ying Liu, Fang Sun, Yanyuan Jia, Qinghua Xu, Jiaqi Tang, Zhenlang Xie, Jing Sun, Simin Li, Qing Tang, Shuo Guo, Hui Shen, Nanfeng Zheng. Array-Based Clusters of Copper with Largely Exposed Metal Sites for Promoting Catalysis. Chemistry of Materials 2023, 35 (18) , 7588-7596. https://doi.org/10.1021/acs.chemmater.3c01277
    55. Dipankar Bain, Aarti Devi, Rashi, Sikta Chakraborty, Sarita Kolay, Amitava Patra. Enhanced Luminescence in Zn+2-Induced Au14 Nanocluster Aggregates. The Journal of Physical Chemistry C 2023, 127 (36) , 18244-18251. https://doi.org/10.1021/acs.jpcc.3c05279
    56. Zhi Wang, Rakesh Kumar Gupta, Fahri Alkan, Bao-Liang Han, Lei Feng, Xian-Qiang Huang, Zhi-Yong Gao, Chen-Ho Tung, Di Sun. Dicarboxylic Acids Induced Tandem Transformation of Silver Nanocluster. Journal of the American Chemical Society 2023, 145 (36) , 19523-19532. https://doi.org/10.1021/jacs.3c01119
    57. Arijit Jana, Wakeel Ahmed Dar, Sourav Kanti Jana, Ajay Kumar Poonia, Vivek Yadav, Jayoti Roy, Sourov Chandra, Kumaran Nair Valsala Devi Adarsh, Robin H. A. Ras, Thalappil Pradeep. Photoconversion of Ag31 to Ag42 Initiated by Solvated Electrons. Chemistry of Materials 2023, 35 (17) , 7020-7031. https://doi.org/10.1021/acs.chemmater.3c01293
    58. Alberto Casu, Miquel Lopez, Claudio Melis, Davide Deiana, Hongbo Li, Luciano Colombo, Andrea Falqui. Thermally Promoted Cation Exchange at the Solid State in the Transmission Electron Microscope: How It Actually Works. ACS Nano 2023, 17 (17) , 17058-17069. https://doi.org/10.1021/acsnano.3c04516
    59. Chaoqiang Yan, Yanshuang Li, Endong Wang, Wen Wu Xu. Decoding Chemical Formula to Spatial Conformation: A Structural Study Targeting the [Au25(SR)19]0 Nanocluster. The Journal of Physical Chemistry Letters 2023, 14 (34) , 7632-7637. https://doi.org/10.1021/acs.jpclett.3c01731
    60. Lingyao Meng, Tuan V. Vu, Louise J. Criscenti, Tuan A. Ho, Yang Qin, Hongyou Fan. Theoretical and Experimental Advances in High-Pressure Behaviors of Nanoparticles. Chemical Reviews 2023, 123 (16) , 10206-10257. https://doi.org/10.1021/acs.chemrev.3c00169
    61. Debkumar Bera, Arun Mukhopadhyay, Nonappa, Nirmal Goswami. In Situ Depletion-Guided Engineering of Nanoshell-like Gold Nanocluster Assemblies with Enhanced Peroxidase-like Nanozyme Activity. The Journal of Physical Chemistry Letters 2023, 14 (32) , 7299-7305. https://doi.org/10.1021/acs.jpclett.3c01837
    62. Simin Li, Xiaodan Yan, Jiaqi Tang, Dongxu Cao, Xueli Sun, Guolong Tian, Xiongkai Tang, Huifang Guo, Qingyuan Wu, Jing Sun, Jinlu He, Hui Shen. Cu26 Nanoclusters with Quintuple Ligand Shells for CO2 Electrocatalytic Reduction. Chemistry of Materials 2023, 35 (15) , 6123-6132. https://doi.org/10.1021/acs.chemmater.3c01247
    63. Tzu-Hao Chiu, Jian-Hong Liao, Ying-Yann Wu, Jie-Ying Chen, Yuan Jang Chen, Xiaoping Wang, Samia Kahlal, Jean-Yves Saillard, C. W. Liu. Hydride Doping Effects on the Structure and Properties of Eight-Electron Rh/Ag Superatoms: The [RhHx@Ag21–x{S2P(OnPr)2}12] (x = 0–2) Series. Journal of the American Chemical Society 2023, 145 (30) , 16739-16747. https://doi.org/10.1021/jacs.3c04482
    64. William R. Jeffries, Sami Malola, Marcus A. Tofanelli, Christopher J. Ackerson, Hannu Häkkinen, Kenneth L. Knappenberger, Jr.. Coherent Vibrational Dynamics of Au144(SC8H9)60 Nanoclusters. The Journal of Physical Chemistry Letters 2023, 14 (29) , 6679-6685. https://doi.org/10.1021/acs.jpclett.3c01477
    65. Vikas Tiwari, Tarak Karmakar. Understanding Molecular Aggregation of Ligand-Protected Atomically-Precise Metal Nanoclusters. The Journal of Physical Chemistry Letters 2023, 14 (29) , 6686-6694. https://doi.org/10.1021/acs.jpclett.3c01770
    66. Kritiman Marjit, Goutam Ghosh, Srijon Ghosh, Debarati Ghosh, Anusri Medda, Amitava Patra. Electron Transfer Dynamics from CsPbBr3 Nanocrystals to Au144 Clusters. ACS Physical Chemistry Au 2023, 3 (4) , 348-357. https://doi.org/10.1021/acsphyschemau.2c00070
    67. Qinzhen Li, Yesen Tan, Baoyu Huang, Sha Yang, Jinsong Chai, Xiaoping Wang, Yong Pei, Manzhou Zhu. Mechanistic Study of the Hydride Migration-Induced Reversible Isomerization in Au22(SR)15H Isomers. Journal of the American Chemical Society 2023, 145 (29) , 15859-15868. https://doi.org/10.1021/jacs.3c02768
    68. Moushakhi Ghosh, Shabana Khan. N-Heterocyclic Carbenes Capped Metal Nanoparticles: An Overview of Their Catalytic Scope. ACS Catalysis 2023, 13 (14) , 9313-9325. https://doi.org/10.1021/acscatal.3c01824
    69. Ayaka Hatano, Tsuyoshi Sugawa, Rei Mimura, Shunichi Kataoka, Koji Yamamoto, Tsubasa Omoda, Bo Zhu, Yu Tian, Shigeyoshi Sakaki, Tetsuro Murahashi. Isolation and Structures of Polyarene Palladium Nanoclusters. Journal of the American Chemical Society 2023, 145 (28) , 15030-15035. https://doi.org/10.1021/jacs.3c02849
    70. Sourav Biswas, Anish Kumar Das, Sukhendu Mandal. Surface Engineering of Atomically Precise M(I) Nanoclusters: From Structural Control to Room Temperature Photoluminescence Enhancement. Accounts of Chemical Research 2023, 56 (13) , 1838-1849. https://doi.org/10.1021/acs.accounts.3c00176
    71. Jianyu Wei, Fahime Bigdeli, Ling-Xiao Wang, Lin-Lin Hou, Akram Panjehpour, Yue Ma, Kang-Zhou Wang, Ali Morsali, Kuan-Guan Liu. Template-Free Synthesis of Two New Luminescent One-Dimensional High-Nuclearity Silver Polyclusters. Inorganic Chemistry 2023, 62 (26) , 10185-10192. https://doi.org/10.1021/acs.inorgchem.3c00811
    72. Xiao Wei, Haoqi Li, Hao Li, Zewen Zuo, Fengqi Song, Xi Kang, Manzhou Zhu. Slice Visualization for Imaging Nanocluster Transformations. Journal of the American Chemical Society 2023, 145 (25) , 13750-13757. https://doi.org/10.1021/jacs.3c02165
    73. Satoru Muramatsu, Yuki Nakahigashi, Tsubasa Omoda, Shinjiro Takano, Tatsuya Tsukuda, Yoshiya Inokuchi. Collision-Induced Fission of Oblate Gold Superatom in [Au9(PPh3)8]3+: Deformation-Mediated Mechanism. The Journal of Physical Chemistry Letters 2023, 14 (24) , 5641-5647. https://doi.org/10.1021/acs.jpclett.3c01153
    74. Jing Sun, Xiaodan Yan, Lingzheng Wang, Zhenlang Xie, Guolong Tian, Lin Wang, Ayisha He, Simin Li, Qingxiang Guo, Chaolumen, Jinlu He, Hui Shen. Decorating an Anticuboctahedral Copper Kernel with Labile Surface Coatings for Controlling Optical and Catalytic Properties. Inorganic Chemistry 2023, 62 (23) , 9005-9013. https://doi.org/10.1021/acs.inorgchem.3c00710
    75. Along Ma, Wenjun Du, Jiawei Wang, Kefan Jiang, Cheng Zhang, Wenhan Sheng, Haiyan Zheng, Rongchao Jin, Shuxin Wang. Transforming Silver Nanoclusters from Racemic to Homochiral via Seeded Crystallization. The Journal of Physical Chemistry Letters 2023, 14 (22) , 5095-5101. https://doi.org/10.1021/acs.jpclett.3c00794
    76. Ying Zhang, Sheng-Rong He, Ying Yang, Tai-Song Zhang, Ze-Min Zhu, Wenwen Fei, Man-Bo Li. Preorganized Nitrogen Sites for Au11 Amidation: A Generalizable Strategy toward Precision Functionalization of Metal Nanoclusters. Journal of the American Chemical Society 2023, 145 (22) , 12164-12172. https://doi.org/10.1021/jacs.3c01961
    77. Ge Yang, Ziping Wang, Fanglin Du, Fuyi Jiang, Xun Yuan, Jackie Y. Ying. Ultrasmall Coinage Metal Nanoclusters as Promising Theranostic Probes for Biomedical Applications. Journal of the American Chemical Society 2023, 145 (22) , 11879-11898. https://doi.org/10.1021/jacs.3c02880
    78. Ye Tian, Weijia Zheng, Xiaoyu Zhang, Yinghui Wang, Yanwei Xiao, Dong Yao, Hao Zhang. Triple Ligand Engineered Gold Nanoclusters with Enhanced Fluorescence and Device Compatibility for Efficient Electroluminescence Light-Emitting Diodes. Nano Letters 2023, 23 (10) , 4423-4430. https://doi.org/10.1021/acs.nanolett.3c00725
    79. Wataru Ishii, Yoshinori Okayasu, Yoichi Kobayashi, Rika Tanaka, Shohei Katao, Yoshiko Nishikawa, Tsuyoshi Kawai, Takuya Nakashima. Excited State Engineering in Ag29 Nanocluster through Peripheral Modification with Silver(I) Complexes for Bright Near-Infrared Photoluminescence. Journal of the American Chemical Society 2023, 145 (20) , 11236-11244. https://doi.org/10.1021/jacs.3c01259
    80. Jiaojiao Han, Hao Li, Honglei Shen, Ying Xu, Xuejuan Zou, Xi Kang, Manzhou Zhu. (AuAg)44(SPhtBu)26 versus (AuAg)44(SPhF2)30: Tailoring the Geometric Structures and Optical Properties of Nanocluster Analogues. Precision Chemistry 2023, 1 (3) , 139-145. https://doi.org/10.1021/prechem.2c00007
    81. Kai Sheng, Zhi Wang, Li Li, Zhi-Yong Gao, Chen-Ho Tung, Di Sun. Solvent-Mediated Separation and Reversible Transformation of 1D Supramolecular Polymorphs Built from [W10O32]4– Templated 48-Nuclei Silver(I) Cluster. Journal of the American Chemical Society 2023, 145 (19) , 10595-10603. https://doi.org/10.1021/jacs.3c00321
    82. Anna Gonzàlez-Rosell, Sami Malola, Rweetuparna Guha, Nery R. Arevalos, María Francisca Matus, Meghen E. Goulet, Esa Haapaniemi, Benjamin B. Katz, Tom Vosch, Jiro Kondo, Hannu Häkkinen, Stacy M. Copp. Chloride Ligands on DNA-Stabilized Silver Nanoclusters. Journal of the American Chemical Society 2023, 145 (19) , 10721-10729. https://doi.org/10.1021/jacs.3c01366
    83. Tao Jia, Zong-Jie Guan, Chengkai Zhang, Xiao-Zhao Zhu, Yun-Xin Chen, Qian Zhang, Yang Yang, Di Sun. Eight-Electron Superatomic Cu31 Nanocluster with Chiral Kernel and NIR-II Emission. Journal of the American Chemical Society 2023, 145 (18) , 10355-10363. https://doi.org/10.1021/jacs.3c02215
    84. Zidong Lin, Ying Lv, Shan Jin, Haizhu Yu, Manzhou Zhu. Size Growth of Au4Cu4: From Increased Nucleation to Surface Capping. ACS Nano 2023, 17 (9) , 8613-8621. https://doi.org/10.1021/acsnano.3c01238
    85. Stefan Knoppe, Alvaro Muñoz-Castro. Intermediate Silver Doping of Au25(SR)18: Variation of Electronic, Optical, and Chiroptical Properties along Au25–xAgx(SH)18– (x = 0–12) Stoichiometry from DFT Calculations. Inorganic Chemistry 2023, 62 (18) , 7079-7086. https://doi.org/10.1021/acs.inorgchem.3c00485
    86. Junsheng Chen, Ajeet Kumar, Cecilia Cerretani, Tom Vosch, Donatas Zigmantas, Erling Thyrhaug. Excited-State Dynamics in a DNA-Stabilized Ag16 Cluster with Near-Infrared Emission. The Journal of Physical Chemistry Letters 2023, 14 (17) , 4078-4083. https://doi.org/10.1021/acs.jpclett.3c00764
    87. Rahul Ramachandran M, Sourav Biswas, Maurizio Polentarutti, Turbasu Sengupta, Shiv N. Khanna, Sukhendu Mandal. Role of Non-covalent Interaction toward Conductivity in a One-Dimensional Tube-like Silver-Thiolate Structure. Crystal Growth & Design 2023, 23 (5) , 3164-3170. https://doi.org/10.1021/acs.cgd.2c01340
    88. Priscila Seveur, Leïla Boubekeur-Lecaque, François Maurel, Éric Brémond. Modeling the Photo-Absorption Properties of Noble Metal Nanoclusters: A Challenge for Density-Functional Theory. The Journal of Physical Chemistry C 2023, 127 (16) , 7718-7729. https://doi.org/10.1021/acs.jpcc.2c08658
    89. Sangeeta Meena, Saptarshi G. Dastider, Chandra Shekhar Nishad, Dilip Kumar Jangid, Pankaj Kumar, Samreet Khirid, Shubhankar Kumar Bose, Krishnakanta Mondal, Biplab Banerjee, Rajendra S. Dhayal. Ag–S Type Quantum Dots versus Superatom Nanocatalyst: A Single Sulfur Atom Modulated Decarboxylative Radical Cascade Reaction. Inorganic Chemistry 2023, 62 (15) , 6092-6101. https://doi.org/10.1021/acs.inorgchem.3c00070
    90. Leonardo Scarabelli, Muhua Sun, Xiaolu Zhuo, Sungjae Yoo, Jill E. Millstone, Matthew R. Jones, Luis M. Liz-Marzán. Plate-Like Colloidal Metal Nanoparticles. Chemical Reviews 2023, 123 (7) , 3493-3542. https://doi.org/10.1021/acs.chemrev.3c00033
    91. Wentao Fan, Nan Yan, Jun Zha, Wanmiao Gu, Qing You, Ying Yang, Shengli Zhuang, Zhikun Wu. Regulating the Electronic Structure of Metal Nanoclusters by Longitudinal Single-Dithiolate Substitution. The Journal of Physical Chemistry Letters 2023, 14 (13) , 3216-3221. https://doi.org/10.1021/acs.jpclett.3c00238
    92. Zhao-Chen Shen, Yu-Ting Yang, Yu-Zhuo Guo, Ya-Qin Chai, Jia-Li Liu, Ruo Yuan. Zn2+-Induced Gold Cluster Aggregation Enhanced Electrochemiluminescence for Ultrasensitive Detection of MicroRNA-21. Analytical Chemistry 2023, 95 (13) , 5568-5574. https://doi.org/10.1021/acs.analchem.2c04714
    93. Jing Sun, Xiongkai Tang, Jiaqi Tang, Yuhao Zhang, Zilin Li, Chaolumen, Shuo Guo, Hui Shen. Simple Approach toward N-Heterocyclic Carbene-Protected Gold Nanoclusters. Inorganic Chemistry 2023, 62 (13) , 5088-5094. https://doi.org/10.1021/acs.inorgchem.2c04200
    94. Daichi Arima, Masaaki Mitsui. Structurally Flexible Au–Cu Alloy Nanoclusters Enabling Efficient Triplet Sensitization and Photon Upconversion. Journal of the American Chemical Society 2023, 145 (12) , 6994-7004. https://doi.org/10.1021/jacs.3c00870
    95. Yao Li, Xi-Ming Luo, Peng Luo, Qiu-Xu Zang, Zhao-Yang Wang, Shuang-Quan Zang. Cocrystallization of Two Negatively Charged Dimercaptomaleonitrile-Stabilized Silver Nanoclusters. ACS Nano 2023, 17 (6) , 5834-5841. https://doi.org/10.1021/acsnano.2c12473
    96. Site Li, Xiangsha Du, Zhongyu Liu, Yingwei Li, Yucai Shao, Rongchao Jin. Size Effects of Atomically Precise Gold Nanoclusters in Catalysis. Precision Chemistry 2023, 1 (1) , 14-28. https://doi.org/10.1021/prechem.3c00008
    97. Zhen Han, Yubing Si, Xi-Yan Dong, Jia-Hua Hu, Chong Zhang, Xuan-Hui Zhao, Jia-Wang Yuan, Yan Wang, Shuang-Quan Zang. Smart Reversible Transformations between Chiral Superstructures of Copper Clusters for Optical and Chiroptical Switching. Journal of the American Chemical Society 2023, 145 (11) , 6166-6176. https://doi.org/10.1021/jacs.2c12055
    98. Zhipeng Zhao, Huarui Chen, Kui He, Jincheng Lin, Wei Cai, Yidan Sun, Jinbin Liu. Glutathione-Activated Emission of Ultrasmall Gold Nanoparticles in the Second Near-Infrared Window for Imaging of Early Kidney Injury. Analytical Chemistry 2023, 95 (11) , 5061-5068. https://doi.org/10.1021/acs.analchem.2c05612
    99. Li Tang, Tengfei Duan, Yong Pei, Shuxin Wang. Synchronous Metal Rearrangement on Two-Dimensional Equatorial Surfaces of Au–Cu Alloy Nanoclusters. ACS Nano 2023, 17 (5) , 4279-4286. https://doi.org/10.1021/acsnano.2c07136
    100. Lipipuspa Sahoo, Aarti Devi, Amitava Patra. Atomically Precise Ni Nanoclusters for Improving Hydrogen Evolution Reaction Performance. ACS Sustainable Chemistry & Engineering 2023, 11 (10) , 4187-4196. https://doi.org/10.1021/acssuschemeng.2c06999
    Load more citations

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    MENDELEY PAIRING EXPIRED
    Your Mendeley pairing has expired. Please reconnect