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Exploring Chemical, Mechanical, and Electrical Functionalities of Binders for Advanced Energy-Storage Devices

  • Hao Chen
    Hao Chen
    Centre for Clean Environment and Energy, School of Environment and Science, Griffith University, Gold Coast Campus, Gold Coast, Queensland 4222, Australia
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  • , 
  • Min Ling
    Min Ling
    Centre for Clean Environment and Energy, School of Environment and Science, Griffith University, Gold Coast Campus, Gold Coast, Queensland 4222, Australia
    Zhejiang Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China
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    Orcidhttp://orcid.org/0000-0001-6727-9585
  • , 
  • Luke Hencz
    Luke Hencz
    Centre for Clean Environment and Energy, School of Environment and Science, Griffith University, Gold Coast Campus, Gold Coast, Queensland 4222, Australia
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  • , 
  • Han Yeu Ling
    Han Yeu Ling
    Centre for Clean Environment and Energy, School of Environment and Science, Griffith University, Gold Coast Campus, Gold Coast, Queensland 4222, Australia
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  • , 
  • Gaoran Li
    Gaoran Li
    Zhejiang Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China
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  • , 
  • Zhan Lin*
    Zhan Lin
    Electrochemical NanoEnergy Group, School of Chemical Engineering and Light Industry at Guangdong University of Technology, Guangzhou, China
    *E-mail: [email protected]
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    Orcidhttp://orcid.org/0000-0001-5009-8198
  • , 
  • Gao Liu*
    Gao Liu
    Electrochemistry Division, Lawrence Berkeley National Lab, San Francisco, California 94720, United States
    *E-mail: [email protected]
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  • , and 
  • Shanqing Zhang*
    Shanqing Zhang
    Centre for Clean Environment and Energy, School of Environment and Science, Griffith University, Gold Coast Campus, Gold Coast, Queensland 4222, Australia
    *E-mail: [email protected]
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    Orcidhttp://orcid.org/0000-0001-5192-1844
Cite this: Chem. Rev. 2018, 118, 18, 8936–8982
Publication Date (Web):August 22, 2018
https://doi.org/10.1021/acs.chemrev.8b00241
Copyright © 2018 American Chemical Society
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    Abstract

    Abstract Image

    Tremendous efforts have been devoted to the development of electrode materials, electrolytes, and separators of energy-storage devices to address the fundamental needs of emerging technologies such as electric vehicles, artificial intelligence, and virtual reality. However, binders, as an important component of energy-storage devices, are yet to receive similar attention. Polyvinylidene fluoride (PVDF) has been the dominant binder in the battery industry for decades despite several well-recognized drawbacks, i.e., limited binding strength due to the lack of chemical bonds with electroactive materials, insufficient mechanical properties, and low electronic and lithium-ion conductivities. The limited binding function cannot meet inherent demands of emerging electrode materials with high capacities such as silicon anodes and sulfur cathodes. To address these concerns, in this review we divide the binding between active materials and binders into two major mechanisms: mechanical interlocking and interfacial binding forces. We review existing and emerging binders, binding technology used in energy-storage devices (including lithium-ion batteries, lithium–sulfur batteries, sodium-ion batteries, and supercapacitors), and state-of-the-art mechanical characterization and computational methods for binder research. Finally, we propose prospective next-generation binders for energy-storage devices from the molecular level to the macro level. Functional binders will play crucial roles in future high-performance energy-storage devices.

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