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Facile Fabrication of Fe2O3-Decorated Carbon Matrixes with a Multidimensional Structure as Anodes for Lithium-Ion Batteries

  • Jitong Wang*
    Jitong Wang
    State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China
    Key Laboratory of Specially Functional Polymeric Materials and Related Technology, East China University of Science and Technology, Shanghai 200237, China
    *Email: [email protected]
    More by Jitong Wang
  • Cheng Ma*
    Cheng Ma
    State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China
    Key Laboratory of Specially Functional Polymeric Materials and Related Technology, East China University of Science and Technology, Shanghai 200237, China
    CAS Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
    *Email: [email protected]
    More by Cheng Ma
  • Jiawei Tang
    Jiawei Tang
    State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China
    More by Jiawei Tang
  • Xiaojuan Yang
    Xiaojuan Yang
    State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China
  • Yongbang Wang
    Yongbang Wang
    State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China
  • Xianfeng Jia
    Xianfeng Jia
    State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China
    Department of Chemistry, Tangshan Normal University, Tangshan 063000, China
    More by Xianfeng Jia
  • Wendi Cai
    Wendi Cai
    State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China
    More by Wendi Cai
  • Wenming Qiao
    Wenming Qiao
    State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China
    Key Laboratory of Specially Functional Polymeric Materials and Related Technology, East China University of Science and Technology, Shanghai 200237, China
    More by Wenming Qiao
  • , and 
  • Licheng Ling
    Licheng Ling
    State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China
    Key Laboratory of Specially Functional Polymeric Materials and Related Technology, East China University of Science and Technology, Shanghai 200237, China
    More by Licheng Ling
Cite this: Energy Fuels 2021, 35, 1, 816–826
Publication Date (Web):December 11, 2020
https://doi.org/10.1021/acs.energyfuels.0c02947
Copyright © 2020 American Chemical Society

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    Abstract

    Abstract Image

    Rational design of the dimension and structure for electrode materials is an efficient strategy to boost the electrochemical properties. Herein, Fe2O3 nanoparticles are integrated with carbon substrates of different dimensions including a one-dimensional carbon nanotube (CNT), two-dimensional reduced graphene oxide (rGO), and a three-dimensional carbon framework composed of CNT and rGO via facile heterogeneous nucleation under hydrothermal conditions. These materials demonstrate a strong structure-dependent electrochemical performance. Among the three composites constructed, the rGO/CNT–Fe2O3 composite possesses an interconnected network with Fe2O3 uniformly distributed in the three-dimensional carbon skeleton composed of CNT and rGO. The two-dimensional conductive rGO could not only confine the Fe2O3 nanoparticles within the graphene layers to prevent the pulverization and agglomeration of Fe2O3 but also offer accessible active sites for the electrochemical reaction. The one-dimensional CNT interspersed within the interlayer space between the rGO nanosheet could impede the folding of the rGO sheet to enhance the ion/electron transport as well as maintain the multistructure of the composite during the charge and discharge process. Therefore, rGO/CNT–Fe2O3 can achieve a superior initial reversible capacity of 1306.9 mAh g–1 at 500 mA g–1 with a high capacity retention of 760.3 mAh g–1 after 400 cycles and a remarkable rate performance of 424.2 mAh g–1 at 5 A g–1. This work provides insight into the effect of carbon dimension on the energy storage capacity and develops an efficient strategy to construct multidimensional transition-metal oxide-based composites as anode materials for lithium-ion batteries.

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    Cited By

    This article is cited by 14 publications.

    1. Qizhi Liu, Cheng Ma, Wenming Qiao, Licheng Ling, Jitong Wang. Nanoarchitectured MnO2 Confined to Mesoporous Carbon Microspheres as Bifunctional Electrodes for High-Performance Supercapacitors and Lithium-Ion Capacitors. Industrial & Engineering Chemistry Research 2022, 61 (4) , 1748-1760. https://doi.org/10.1021/acs.iecr.1c04475
    2. Sandeep Kumar Sundriyal, Yogesh Sharma. Morphology and Oxygen Defects Mediated Improved Pseudocapacitive Li+ Storage of Conversion-Based Lithium Iron Oxide. Energy & Fuels 2021, 35 (15) , 12637-12652. https://doi.org/10.1021/acs.energyfuels.1c01434
    3. Yao Chen, Xueye Chen, Yaolong Zhang. A Comprehensive Review on Metal-Oxide Nanocomposites for High-Performance Lithium-Ion Battery Anodes. Energy & Fuels 2021, 35 (8) , 6420-6442. https://doi.org/10.1021/acs.energyfuels.1c00315
    4. Kongyao Chen, Gaojie Li, Zhihan Hu, Yanjie Wang, Zhuo Wang, Na Qin, Xueli Chen, Weihua Chen, Zijie Wu, Constantinos Soutis, Liwei Mi. Simple Preparation of Baroque Mn-Based Chalcogenide/Honeycomb-like Carbon Composites for Sodium-Ion Batteries from Renewable Pleurotus Eryngii. Energy & Fuels 2021, 35 (7) , 6265-6271. https://doi.org/10.1021/acs.energyfuels.1c00338
    5. Sayed R.E. Mohamed, Ahmed S.A. Mohammed, Ossama I. Metwalli, S. El-Sayed, Gomaa Khabiri, Abdelwahab Hassan, Kai Yin, Sameh O. Abdellatif, Nieves López-Salas, Ahmed S.G. Khalil. Synergistic design of high-performance symmetric supercapacitor based on iron oxide nanoplatelets/COOH-MWCNTs heterostructures: DFT computation and experimental analysis. Journal of Alloys and Compounds 2024, 987 , 174118. https://doi.org/10.1016/j.jallcom.2024.174118
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    7. Quang Nhat Tran, Chan Ho Park, Thi Hoa Le. Nanocrystalline Cellulose-Supported Iron Oxide Composite Materials for High-Performance Lithium-Ion Batteries. Polymers 2024, 16 (5) , 691. https://doi.org/10.3390/polym16050691
    8. Yanzhi Cai, Zhongyi Hu, Laifei Cheng, Siyu Guo, Tingting Liu, Shaohua Huang, Dengpeng Chen, Yuhan Wang, Haiming Yu, Yuan Zhou. Application and structure of carbon nanotube and graphene-based flexible electrode materials and assembly modes of flexible lithium-ion batteries toward different functions. Frontiers in Energy 2024, 32 https://doi.org/10.1007/s11708-024-0911-2
    9. Ying Zeng, Dong Xie, Shuzhao Ai, Han Huang, Zeqiang Zheng, Shilei Xie, Peng Liu, Shoushan Wang, Min Zhang, Faliang Cheng. Facile fabrication of core-shell α-Fe2O3@PPy imbedded into porous biomass-derived carbon for enhanced lithium storage. Journal of Energy Storage 2023, 67 , 107625. https://doi.org/10.1016/j.est.2023.107625
    10. Zhiping Xue, Jing Lu. Fabrication and application of Fe 2 O 3 -decorated carbon nanotube fibers via instantaneous Joule-heating method. Nanotechnology 2022, 33 (45) , 455601. https://doi.org/10.1088/1361-6528/ac8486
    11. Lin Hu, Jian Huang, Zhong Yang, Jianping Li, Ping Wang, Liangliang Wang, Pengfei Sun. Microstructure and lithium storage properties of Fe2O3 in N-doped carbon nanosheets. Solid State Ionics 2022, 383 , 115981. https://doi.org/10.1016/j.ssi.2022.115981
    12. Qingfu Ban, Yuanyuan Liu, Peiyan Liu, Yan Li, Yusheng Qin, Yaochen Zheng. Hierarchically nanostructured carbon nanotube/polyimide/mesoporous Fe2O3 nanocomposite for organic-inorganic lithium-ion battery anode. Microporous and Mesoporous Materials 2022, 335 , 111803. https://doi.org/10.1016/j.micromeso.2022.111803
    13. Xiuying Jin, Yanwei Li, Tengfei Jin, Jiqiong Jiang, Qing Zhu, Jinhuan Yao. Facile and efficient synthesis of binary FeOOH/Fe2O3 composite as a high-performance anode material for lithium-ion batteries. Journal of Alloys and Compounds 2022, 896 , 163026. https://doi.org/10.1016/j.jallcom.2021.163026
    14. Han Ye, Guoxu Zheng, Xu Yang, Daqing Zhang, Yichi Zhang, Shoucong Yan, Ling You, Shan Hou, ZeLin Huang. Application of different carbon-based transition metal oxide composite materials in lithium-ion batteries. Journal of Electroanalytical Chemistry 2021, 898 , 115652. https://doi.org/10.1016/j.jelechem.2021.115652

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