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Ultralong-Life Supercapacitors Using Pyridine-Derived Porous Carbon Materials

  • Shilian Lai
    Shilian Lai
    College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, Zhejiang 325035, P.R.China
    More by Shilian Lai
  • Jingyan Zhu
    Jingyan Zhu
    College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, Zhejiang 325035, P.R.China
    More by Jingyan Zhu
  • Weibing Zhang
    Weibing Zhang
    College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, Zhejiang 325035, P.R.China
  • Jun Jiang
    Jun Jiang
    College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, Zhejiang 325035, P.R.China
    More by Jun Jiang
  • , and 
  • Xinhua Li*
    Xinhua Li
    College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, Zhejiang 325035, P.R.China
    *Email: [email protected]
    More by Xinhua Li
Cite this: Energy Fuels 2021, 35, 4, 3407–3416
Publication Date (Web):January 29, 2021
https://doi.org/10.1021/acs.energyfuels.0c03286
Copyright © 2021 American Chemical Society

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    Abstract

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    Supercapacitors are widely used in power reserves and portable power devices because of their rapid charge and discharge rates and excellent cycle performance. Carbon materials have the characteristics of large specific surface areas, excellent electrical conductivity, good chemical stability, and low price, so they are very attractive as electrode materials for supercapacitors. In recent decades, the electrochemical properties of supercapacitors based on porous carbon have attracted much interest. Through the design of supercapacitors of reasonable appearance, pore shape, and surface characteristics, their electrochemical performance has been significantly improved. Herein, a simple and easy process is developed to synthesize a new kind of porous carbon materials with N,O-doping. The constructed supercapacitor with the as-prepared carbon material exhibits excellent capacitance performance and rapid charge and discharge rates (<1 s, 20 A/g, two-electrode cell), ultralong cycle life (>89,000 cycles, 10 A/g), large specific capacitance (276.5 F/g, 0.5 A/g), and excellent energy density (38.4 W/h/kg). Its superior properties make it one of the best candidate electrode materials for supercapacitors derived from ligands. Its excellent supercapacitor performance is probably related to its high ion-accessible specific surface area, hierarchical regular pore structure, and well N,O-doping on the surface of the carbon composite. This study provides a feasible strategy for the development of high-performance supercapacitors suitable for commercial applications.

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.energyfuels.0c03286.

    • Structure of BPTP, high-resolution XPS spectra, Nyquist plots, thermogravimetric analysis results, and CV curves (PDF)

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    This article is cited by 24 publications.

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