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Fast Pyrolysis of Wheat Straw—Improvements of Operational Stability in 10 Years of Bioliq Pilot Plant Operation

  • Andreas Niebel*
    Andreas Niebel
    Institute of Catalysis Research and Technology (IKFT), Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
    *E-mail: [email protected]
  • Axel Funke
    Axel Funke
    Institute of Catalysis Research and Technology (IKFT), Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
    More by Axel Funke
  • Cornelius Pfitzer
    Cornelius Pfitzer
    Institute of Catalysis Research and Technology (IKFT), Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
  • Nicolaus Dahmen
    Nicolaus Dahmen
    Institute of Catalysis Research and Technology (IKFT), Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
  • Nicole Weih
    Nicole Weih
    Institute of Catalysis Research and Technology (IKFT), Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
    More by Nicole Weih
  • Daniel Richter
    Daniel Richter
    Institute of Catalysis Research and Technology (IKFT), Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
  • , and 
  • Bernd Zimmerlin
    Bernd Zimmerlin
    Institute for Technical Chemistry (ITC), Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
Cite this: Energy Fuels 2021, 35, 14, 11333–11345
Publication Date (Web):June 30, 2021
https://doi.org/10.1021/acs.energyfuels.1c00851
Copyright © 2021 The Authors. Published by American Chemical Society

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    Abstract

    Abstract Image

    The bioliq process developed at the Karlsruhe Institute of Technology (KIT) aims at the conversion of lignocellulosic biomass into synthetic biofuels and chemicals. The process follows a two-stage concept combining decentralized pretreatment of biomass via fast pyrolysis and centralized large-scale gasification and synthesis. The process was specifically designed to convert ash-rich biomass residues, such as wheat straw, requiring special design features at least in the upstream processes. The 2 MW fast pyrolysis pilot plant at KIT was operated with wheat straw from 2009 to 2018 and since then with miscanthus. A substantial increase from less than 5 tons of wheat straw converted per test run in 2012 to more than 50 tons in 2018 was achieved. In total, up to 2018, more than 260 tons of wheat straw were converted to pyrolysis products within a total of 500 h of steady operation. Representative results of the product yields and properties were presented for test campaigns from 2015 to 2018 and compared to a process demonstration unit of the same design but with a downscale factor of 50 (10 kg/h). Mass yields from both plants are in good agreement and consistent with literature data. Experience from longer-term operation and major technical modifications made to improve the operational stability of the plant are described.

    Cited By

    This article is cited by 4 publications.

    1. Katharina Kohse-Höinghaus. Combustion, Chemistry, and Carbon Neutrality. Chemical Reviews 2023, 123 (8) , 5139-5219. https://doi.org/10.1021/acs.chemrev.2c00828
    2. George Kofi Parku, Anke Krutof, Axel Funke, Daniel Richter, Nicolaus Dahmen. Using Fractional Condensation to Optimize Aqueous Pyrolysis Condensates for Downstream Microbial Conversion. Industrial & Engineering Chemistry Research 2023, 62 (6) , 2792-2803. https://doi.org/10.1021/acs.iecr.2c03598
    3. Amgad Moussa . Scale-Up to Pilot and Demonstration Plants (TRL 6 and TRL 7). , 169-181. https://doi.org/10.1021/bk-2022-1426.ch009
    4. Manuel Garcia-Perez, (Guest Editor)Karthikeyan K. Ramasamy (Guess Editor). Virtual Special Issue of Recent Advances in Biomass and Wastes Thermochemical Processing. Energy & Fuels 2022, 36 (6) , 2919-2922. https://doi.org/10.1021/acs.energyfuels.2c00447

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