Pyrolysis and Combustion Kinetic Study and Complementary Study of Ash Fusibility Behavior of Sugarcane Bagasse, Sugarcane Straw, and Their Pellets—Case Study of Agro-Industrial ResiduesClick to copy article linkArticle link copied!
- Kelly Roberta de PalmaKelly Roberta de PalmaUniversity of Campinas, School of Chemical Engineering, Avenida Albert Einstein 500, 13083-852 Campinas, São Paulo, BrazilMore by Kelly Roberta de Palma
- Nestor García-HernandoNestor García-HernandoCarlos III University of Madrid, Energy Systems Engineering Group, Thermal and Fluids Engineering Department, Avenida de la Universidad 30, 28911 Madrid, SpainMore by Nestor García-Hernando
- Maria Aparecida SilvaMaria Aparecida SilvaUniversity of Campinas, School of Chemical Engineering, Avenida Albert Einstein 500, 13083-852 Campinas, São Paulo, BrazilMore by Maria Aparecida Silva
- Edson TomazEdson TomazUniversity of Campinas, School of Chemical Engineering, Avenida Albert Einstein 500, 13083-852 Campinas, São Paulo, BrazilMore by Edson Tomaz
- Antonio Soria-Verdugo*Antonio Soria-Verdugo*E-mail: [email protected]. Tel: +34916248465.Carlos III University of Madrid, Energy Systems Engineering Group, Thermal and Fluids Engineering Department, Avenida de la Universidad 30, 28911 Madrid, SpainMore by Antonio Soria-Verdugo
Abstract
Pyrolysis and combustion kinetics of sugarcane bagasse and straw was analyzed using thermogravimetric measurements and applying the DAEM. The kinetic parameters of pyrolysis and combustion reactions were determined, obtaining pyrolysis activation energies of approximately 175 kJ/mol for bagasse and 200 kJ/mol for straw. The combustion activation energies ranged from 162.3 to 282.7 kJ/mol for bagasse and from 130.7 to 292.0 kJ/mol for the straw. The ash melting temperature of both sugarcane residues was also measured. The fluid temperature values found were 1396 and 1352 °C for bagasse and straw, respectively. The analyses were performed for raw material and milled pellets of sugarcane bagasse and straw, obtaining slightly lower values of the kinetic parameters for the milled pellets and negligible differences for the ash melting temperatures.
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