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Pyrolysis and Combustion Kinetic Study and Complementary Study of Ash Fusibility Behavior of Sugarcane Bagasse, Sugarcane Straw, and Their Pellets—Case Study of Agro-Industrial Residues
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    Article

    Pyrolysis and Combustion Kinetic Study and Complementary Study of Ash Fusibility Behavior of Sugarcane Bagasse, Sugarcane Straw, and Their Pellets—Case Study of Agro-Industrial Residues
    Click to copy article linkArticle link copied!

    • Kelly Roberta de Palma
      Kelly Roberta de Palma
      University of Campinas, School of Chemical Engineering, Avenida Albert Einstein 500, 13083-852 Campinas, São Paulo, Brazil
    • Nestor García-Hernando
      Nestor García-Hernando
      Carlos III University of Madrid, Energy Systems Engineering Group, Thermal and Fluids Engineering Department, Avenida de la Universidad 30, 28911 Madrid, Spain
    • Maria Aparecida Silva
      Maria Aparecida Silva
      University of Campinas, School of Chemical Engineering, Avenida Albert Einstein 500, 13083-852 Campinas, São Paulo, Brazil
    • Edson Tomaz
      Edson Tomaz
      University of Campinas, School of Chemical Engineering, Avenida Albert Einstein 500, 13083-852 Campinas, São Paulo, Brazil
      More by Edson Tomaz
    • Antonio Soria-Verdugo*
      Antonio Soria-Verdugo
      Carlos III University of Madrid, Energy Systems Engineering Group, Thermal and Fluids Engineering Department, Avenida de la Universidad 30, 28911 Madrid, Spain
      *E-mail: [email protected]. Tel: +34916248465.
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    Energy & Fuels

    Cite this: Energy Fuels 2019, 33, 4, 3227–3238
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    https://doi.org/10.1021/acs.energyfuels.8b04288
    Published March 22, 2019
    Copyright © 2019 American Chemical Society

    Abstract

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    Pyrolysis and combustion kinetics of sugarcane bagasse and straw was analyzed using thermogravimetric measurements and applying the DAEM. The kinetic parameters of pyrolysis and combustion reactions were determined, obtaining pyrolysis activation energies of approximately 175 kJ/mol for bagasse and 200 kJ/mol for straw. The combustion activation energies ranged from 162.3 to 282.7 kJ/mol for bagasse and from 130.7 to 292.0 kJ/mol for the straw. The ash melting temperature of both sugarcane residues was also measured. The fluid temperature values found were 1396 and 1352 °C for bagasse and straw, respectively. The analyses were performed for raw material and milled pellets of sugarcane bagasse and straw, obtaining slightly lower values of the kinetic parameters for the milled pellets and negligible differences for the ash melting temperatures.

    Copyright © 2019 American Chemical Society

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    Cited By

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    This article is cited by 23 publications.

    1. Hamidreza Najafi, Ahmad Golrokh Sani, Mohammad Amin Sobati. Thermogravimetric and thermo-kinetic analysis of sugarcane bagasse pith: a comparative evaluation with other sugarcane residues. Scientific Reports 2024, 14 (1) https://doi.org/10.1038/s41598-024-52500-x
    2. Tarcísio Martins, Mirele Santana de Sá, Wenes Ramos Silva, Caroline Carriel Schmitt, Renata Moreira, Klaus Raffelt, Nicolaus Dahmen, Alberto Wisniewski. Sugarcane biorefinery: Unlocking the potential of the pyrolytic process to convert waste biomasses into value-added products. Energy Conversion and Management 2024, 318 , 118913. https://doi.org/10.1016/j.enconman.2024.118913
    3. Zhen Huang, Yu-si Li, Chen-xu Zhao, Yu-jiang Liu. Co-pyrolysis of poly (lactic acid) and sugar cane bagasse: Kinetic and thermodynamic studies. Fuel 2024, 372 , 132228. https://doi.org/10.1016/j.fuel.2024.132228
    4. Huili Zhang, Zhen Huang, Ting-ting Liu, Siqi Zheng. Co-pyrolysis of poly (methyl methacrylate) and sugarcane bagasse evaluated through multiple kinetic analysis methods. Journal of Thermal Analysis and Calorimetry 2024, 149 (17) , 9353-9365. https://doi.org/10.1007/s10973-024-13396-x
    5. Carlos T. Hiranobe, Andressa S. Gomes, Fábio F. G. Paiva, Gabrieli R. Tolosa, Leonardo L. Paim, Guilherme Dognani, Guilherme P. Cardim, Henrique P. Cardim, Renivaldo J. dos Santos, Flávio C. Cabrera. Sugarcane Bagasse: Challenges and Opportunities for Waste Recycling. Clean Technologies 2024, 6 (2) , 662-699. https://doi.org/10.3390/cleantechnol6020035
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    9. Bhautik Gajera, Anil Kumar Sarma, Mithilesh Kumar Jha. Assessment of Thermal Behavior and Pyrolytic Kinetics of Selected Agro-residues through Thermogravimetric Analysis. 2023, 185-198. https://doi.org/10.1007/978-981-99-5758-3_15
    10. Joyner Caicedo-Zuñiga, Fernando Casanova, Jhonathan Duque, José Jaime García. Laboratory and field testing to characterize the compaction of sugarcane agricultural residue bales. Energy Conversion and Management: X 2022, 16 , 100326. https://doi.org/10.1016/j.ecmx.2022.100326
    11. Antonio Soria-Verdugo, Eduardo Cano-Pleite, Aidin Panahi, Ahmed F. Ghoniem. Kinetics mechanism of inert and oxidative torrefaction of biomass. Energy Conversion and Management 2022, 267 , 115892. https://doi.org/10.1016/j.enconman.2022.115892
    12. Isabel M. Lima, Jean A. Beacorn. Targeting a Sustainable Sugar Crops Processing Industry: A Review (Part I)—By-Product Applications. Sugar Tech 2022, 24 (4) , 970-991. https://doi.org/10.1007/s12355-022-01169-5
    13. Thomas Rafael de Oliveira, Katia Tannous, Elisangela Cristina Trevisan de Lima. Pyrolysis of the hybrid energy cane: thermal decomposition and kinetic modeling using non-isothermal thermogravimetric analysis. Journal of Thermal Analysis and Calorimetry 2022, 147 (13) , 7431-7448. https://doi.org/10.1007/s10973-021-11028-2
    14. A. Ramírez-Estrada, V. Y. Mena-Cervantes, F. S. Mederos-Nieto, G. Pineda-Flores, R. Hernández-Altamirano. Assessment and classification of lignocellulosic biomass recalcitrance by principal components analysis based on thermogravimetry and infrared spectroscopy. International Journal of Environmental Science and Technology 2022, 19 (4) , 2529-2544. https://doi.org/10.1007/s13762-021-03309-y
    15. María Victoria Alvarez-Henao, Liliana Cardona, Sara Hincapié, Julián Londoño-Londoño, Claudio Jimenez-Cartagena. Supercritical fluid extraction of phytosterols from sugarcane bagasse: Evaluation of extraction parameters. The Journal of Supercritical Fluids 2022, 179 , 105427. https://doi.org/10.1016/j.supflu.2021.105427
    16. Kelly Roberta de Palma, Edson Tomaz, Antonio Soria-Verdugo, Maria Aparecida Silva. The influence of the elemental and structural chemical composition on the ash fusibility of sugarcane bagasse and sugarcane straw. Fuel 2021, 304 , 121404. https://doi.org/10.1016/j.fuel.2021.121404
    17. Bruno Rafael de Almeida Moreira, Victor Hugo Cruz, Edivaldo Wilson de Lima, Lucas da Silva Alves, Paulo Renato Matos Lopes, Ronaldo da Silva Viana. Fuel pellets with antioxidant of illicit cigarette's tobacco auto-generate less CO2, produce adequate flame and are toxicologically reliable. Biomass and Bioenergy 2021, 153 , 106205. https://doi.org/10.1016/j.biombioe.2021.106205
    18. Lucas da Silva Alves, Bruno Rafael de Almeida Moreira, Ronaldo da Silva Viana, Arturo Pardo-Gimenez, Eustáquio Souza Dias, Ralph Noble, Diego Cunha Zied. Recycling spent mushroom substrate into fuel pellets for low-emission bioenergy producing systems. Journal of Cleaner Production 2021, 313 , 127875. https://doi.org/10.1016/j.jclepro.2021.127875
    19. Eduardo Cano-Pleite, Mariano Rubio-Rubio, Uwe Riedel, Antonio Soria-Verdugo. Evaluation of the number of first-order reactions required to accurately model biomass pyrolysis. Chemical Engineering Journal 2021, 408 , 127291. https://doi.org/10.1016/j.cej.2020.127291
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    21. Antonio Soria-Verdugo, Mariano Rubio-Rubio, Elke Goos, Uwe Riedel. On the characteristic heating and pyrolysis time of thermally small biomass particles in a bubbling fluidized bed reactor. Renewable Energy 2020, 160 , 312-322. https://doi.org/10.1016/j.renene.2020.07.008
    22. Eduardo Cano-Pleite, Mariano Rubio-Rubio, Néstor García-Hernando, Antonio Soria-Verdugo. Microalgae pyrolysis under isothermal and non-isothermal conditions. Algal Research 2020, 51 , 102031. https://doi.org/10.1016/j.algal.2020.102031
    23. Antonio Soria-Verdugo, Juho Kauppinen, Teemu Soini, Luis Miguel García-Gutiérrez, Toni Pikkarainen. Pollutant emissions released during sewage sludge combustion in a bubbling fluidized bed reactor. Waste Management 2020, 105 , 27-38. https://doi.org/10.1016/j.wasman.2020.01.036

    Energy & Fuels

    Cite this: Energy Fuels 2019, 33, 4, 3227–3238
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.energyfuels.8b04288
    Published March 22, 2019
    Copyright © 2019 American Chemical Society

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