ACS Publications. Most Trusted. Most Cited. Most Read
My Activity
CONTENT TYPES

Figure 1Loading Img
RETURN TO ISSUEPREVApplied ChemistryNEXT

V2O3@Amorphous Carbon as a Cathode of Zinc Ion Batteries with High Stability and Long Cycling Life

  • Hongzhe Chen
    Hongzhe Chen
    Hunan Province Key Laboratory of Chemical Power Source, College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China
    Innovation Base of Energy and Chemical Materials for Graduate Students Training, Central South University, Changsha 410083, China
    More by Hongzhe Chen
  • Yao Rong
    Yao Rong
    Hunan Province Key Laboratory of Chemical Power Source, College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China
    Innovation Base of Energy and Chemical Materials for Graduate Students Training, Central South University, Changsha 410083, China
    More by Yao Rong
  • Zhanhong Yang*
    Zhanhong Yang
    Hunan Province Key Laboratory of Chemical Power Source, College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China
    *Email: [email protected]
  • Lie Deng
    Lie Deng
    Hunan Province Key Laboratory of Chemical Power Source, College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China
    Innovation Base of Energy and Chemical Materials for Graduate Students Training, Central South University, Changsha 410083, China
    More by Lie Deng
  • , and 
  • Jian Wu
    Jian Wu
    Hunan Province Key Laboratory of Chemical Power Source, College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China
    Innovation Base of Energy and Chemical Materials for Graduate Students Training, Central South University, Changsha 410083, China
    More by Jian Wu
Cite this: Ind. Eng. Chem. Res. 2021, 60, 4, 1517–1525
Publication Date (Web):January 22, 2021
https://doi.org/10.1021/acs.iecr.0c05534
Copyright © 2021 American Chemical Society

    Article Views

    1752

    Altmetric

    -

    Citations

    LEARN ABOUT THESE METRICS
    Other access options
    Supporting Info (1)»

    Abstract

    Abstract Image

    Zinc ion batteries (ZIBs) have the advantages of environmental friendliness, safety, and simple assembly and have strong application potential in the field of energy storage. In this work, an amorphous carbon-loaded V2O3 (V2O3@AC) material is prepared by calcination and used as a cathode material for ZIBs. The V2O3@AC cathode has excellent stability and long life, which maintains 94.8 and 90.7% capacity retention after 180 cycles at 0.1 A g–1 and after 1600 cycles at 1 A g–1, respectively. By scanning electron microscopy (SEM) characterization, V2O3@AC is composed of small irregular nanoparticles, which have a lot of space for electrolyte penetration and ion transmission, and the kinetic studies also confirm this transport capability. The mechanism of zinc storage is studied by ex situ X-ray powder diffraction, X-ray photoelectron spectroscopy, and SEM technology, and they confirm that V2O3 will undergo phase transition and become V10O24·12H2O during the first charge process. Due to the high stability and cycle life of V2O3, we believe that it has competitive potential in zinc ion batteries and can play an important role in large-scale energy storage in the future.

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.

    Supporting Information

    ARTICLE SECTIONS
    Jump To

    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.iecr.0c05534.

    • Additional characterization of materials (TG analysis, SEM images, and XPS analysis) and performance including CV curves, galvanostatic charge–discharge profiles, and Nyquist plots (PDF)

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    This article is cited by 44 publications.

    1. Huifa Shi, Jiakai Cao, Weiyi Sun, Guixia Lu, Hongbo Lan, Lei Xu, Zahid Ali Ghazi, Dinghui Fan, Zongyu Mao, Daliang Han, Wenbao Liu, Shuzhang Niu. Ultrasmall, Amorphous V2O3 Intimately Anchored on a Carbon Nanofiber Aerogel Toward High-Rate Zinc-Ion Batteries. ACS Applied Materials & Interfaces 2024, 16 (15) , 18812-18823. https://doi.org/10.1021/acsami.3c19533
    2. Xiaofan Ma, Jiangling Luo, Rui Jiang, Wenhai Xiao, Xiaoyan Shi, Junling Xu, Jianchao Sun, Lianyi Shao, Zhipeng Sun. One-step Solid-State Synthesis of V1.13Se2/V2O3 Heterostructure as a High Pseudocapacitance Anode for Fast-Charging Sodium-Ion Batteries. ACS Applied Materials & Interfaces 2024, 16 (15) , 18833-18842. https://doi.org/10.1021/acsami.4c00278
    3. Tharani Selvam, Durgalakshmi Dhinasekaran, Balakumar Subramanian, Ajay Rakkesh Rajendran. Enhancing Interplanar Spacing in V2O3/V3O7 Heterostructures to Optimize Cathode Efficiency for Zn-Ion Batteries. The Journal of Physical Chemistry Letters 2024, 15 (5) , 1338-1346. https://doi.org/10.1021/acs.jpclett.3c03590
    4. Fengfeng Li, Hongwei Sheng, Hongyun Ma, Yifeng Qi, Mingjiao Shao, Jiao Yuan, Wenquan Li, Wei Lan. Structural Engineering of Vanadium Oxide Cathodes by Mn2+ Preintercalation for High-Performance Aqueous Zinc-Ion Batteries. ACS Applied Energy Materials 2023, 6 (11) , 6201-6213. https://doi.org/10.1021/acsaem.3c00710
    5. Yuxing Gao, Chunli Wang, Dongming Yin, Zhaomin Wang, Fan Wu, Yong Cheng, Limin Wang. Boosting the Rate Capability of Aqueous Zinc-Ion Batteries Using VNxOy/C Spheres Derived from a Self-Assembled V-polydopamine Complex. ACS Applied Energy Materials 2022, 5 (9) , 10776-10785. https://doi.org/10.1021/acsaem.2c01482
    6. Xue Xia, Juwei Yun, Cheng Huang, Deli Li, Zeheng Yang, Haijian Huang, Weixin Zhang. Ca/Ni Codoping Enables the Integration of High-Rate and High-Capacity Zn-Ion Storage Performances for Layered Hydrated Vanadate. Industrial & Engineering Chemistry Research 2022, 61 (12) , 4212-4221. https://doi.org/10.1021/acs.iecr.2c00220
    7. Hongzhe Chen, Zhanhong Yang, Jian Wu. Vanadium Nitride@nitrogen-Doped Graphene as Zinc Ion Battery Cathode with High Rate Capability and Long Cycle Stability. Industrial & Engineering Chemistry Research 2022, 61 (8) , 2955-2962. https://doi.org/10.1021/acs.iecr.1c04683
    8. Qingsong Su, Yao Rong, Hongzhe Chen, Jian Wu, Zhanhong Yang, Lie Deng, Zhimin Fu. Carbon-Doped Vanadium Nitride Used as a Cathode of High-Performance Aqueous Zinc Ion Batteries. Industrial & Engineering Chemistry Research 2021, 60 (33) , 12155-12165. https://doi.org/10.1021/acs.iecr.1c01915
    9. Lixin Zhang, Sicong Che, Hongfang Jiu, Congli Wang, Zhixin Guo, Yuxin Han, Jinfeng Ma, Hui Li, Luchao Yue, Xiaoqing Liu. Facile synthesis of V2O3/nitrogen-doped carbon shell nanoflower for boosted aqueous zinc ion storage performance. Colloids and Surfaces A: Physicochemical and Engineering Aspects 2024, 696 , 134307. https://doi.org/10.1016/j.colsurfa.2024.134307
    10. Jingjing Zhang, Dunpeng Bao, Biao Huang, Fengshi Xia, Dianmei Song, Libing Hu, Chunhui Shi, Jikui Zhu. Constructing 2D VO2 nanoplates embedded in a carbon matrix as high-performance cathode material for aqueous zinc ion batteries. Ceramics International 2024, 50 (9) , 15092-15099. https://doi.org/10.1016/j.ceramint.2024.01.428
    11. Tao Zhou, Guo Gao. Pre-intercalation strategy in vanadium oxides cathodes for aqueous zinc ion batteries: Review and prospects. Journal of Energy Storage 2024, 84 , 110808. https://doi.org/10.1016/j.est.2024.110808
    12. He Lin, Huanhuan Cheng, Yu Zhang. Improving Zinc-Ion Batteries’ Performance: The Role of Nitrogen Doping in V2O3/C Cathodes. Inorganics 2024, 12 (4) , 117. https://doi.org/10.3390/inorganics12040117
    13. Jingjing Zhang, Fengshi Xia, Dunpeng Bao, Yahui Chen, Libing Hu, Jikui Zhu. Two-dimensional V2O3 nanosheets embedded in a carbon matrix with enhanced performance for aqueous Zn-ion battery. Materials Letters 2024, 357 , 135706. https://doi.org/10.1016/j.matlet.2023.135706
    14. Jin Cao, Tianzhuo Ou, Sining Geng, Xueqing Zhang, Dongdong Zhang, Lulu Zhang, Ding Luo, Xinyu Zhang, Jiaqian Qin, Xuelin Yang. Constructing stable V2O5/V6O13 heterostructure interface with fast Zn2+ diffusion kinetics for ultralong lifespan zinc‐ion batteries. Journal of Colloid and Interface Science 2024, 656 , 495-503. https://doi.org/10.1016/j.jcis.2023.11.127
    15. Sophia Sahoo, Hemant Singh Kunwar, Satish Yadav, Rajeev Rawat, Vasant Sathe, Deodatta Moreswar Phase, Ram Janay Choudhary. Memristive thermal switching in epitaxial V2O3 thin film. Journal of Alloys and Compounds 2024, 970 , 172620. https://doi.org/10.1016/j.jallcom.2023.172620
    16. Guilin Zeng, Yuqiu Wang, Xiaoming Lou, Han Chen, Shaohua Jiang, Wei Zhou. Vanadium oxide/carbonized chestnut needle composites as cathode materials for advanced aqueous zinc-ion batteries. Journal of Energy Storage 2024, 77 , 109859. https://doi.org/10.1016/j.est.2023.109859
    17. Protity Saha, Ahmar Ali, S. M. Abu Nayem, Syed Shaheen Shah, Md. Abdul Aziz, A. J. Saleh Ahammad. Vanadium‐Based Cathodic Materials of Aqueous Zn‐Ion Battery for Superior‐Performance with Prolonged‐Life Cycle. The Chemical Record 2024, 24 (1) https://doi.org/10.1002/tcr.202200310
    18. Dong-Fei Sun, Zi-Juan Wang, Tian Tian, Xin Yu, Dan-Dan Yu, Xiao-Zhong Zhou, Guo-Fu Ma, Zi-Qiang Lei. Constructing oxygen deficiency-rich V2O3@PEDOT cathode for high-performance aqueous zinc-ion batteries. Rare Metals 2023, 22 https://doi.org/10.1007/s12598-023-02434-6
    19. Huibing Lu, Zhengchunyu Zhang, Xuguang An, Jinkui Feng, Shenglin Xiong, Baojuan Xi. In Situ Electrochemically Transforming VN/V 2 O 3 Heterostructure to Highly Reversible V 2 NO for Excellent Zinc Ion Storage. Small Structures 2023, 4 (11) https://doi.org/10.1002/sstr.202300191
    20. Meng Zhang, Peng-Fei Wang, Xiao-Nan Lv, Yubo Yang, Yu-Hang Zhang, Yu-Han Wu, Lina Zhao, Gang Yang, Fa-Nian Shi. Nitrogen-doped carbon/V2O3 nanorod composites as cathode material for high-performance aqueous Zn-ion battery. Journal of Alloys and Compounds 2023, 960 , 170790. https://doi.org/10.1016/j.jallcom.2023.170790
    21. Junzhi Hong, Ling Xie, Chenglong Shi, Xiaoyi Lu, Xiaoyan Shi, Junjie Cai, Yanxue Wu, Lianyi Shao, Zhipeng Sun. High‐Performance Aqueous Zinc‐Ion Batteries Based on Multidimensional V 2 O 3 Nanosheets@Single‐Walled Carbon Nanohorns@Reduced Graphene Oxide Composite and Optimized Electrolyte. Small Methods 2023, https://doi.org/10.1002/smtd.202300205
    22. Peng Cai, Kangli Wang, Xin He, Qixing Li, Zhuchan Zhang, Mengjun Li, Haomiao Li, Min Zhou, Wei Wang, Kai Jiang. Electric-field harmony in V2C/V2O5 heterointerfaces toward high-performance aqueous Zn-ion batteries. Energy Storage Materials 2023, 60 , 102835. https://doi.org/10.1016/j.ensm.2023.102835
    23. Jiaxin Wang, Guangshe Li, Xiaoqing Liu, Quan Ouyang, Mingwei Ma, Qiao Wang, Xin Zhang, Zhipeng Fan, Liping Li. In-situ electrochemical oxidization of V2O3-C cathode for boosted zinc-ion storage performance. Applied Surface Science 2023, 616 , 156481. https://doi.org/10.1016/j.apsusc.2023.156481
    24. Wei Zhou, Guilin Zeng, Haotian Jin, Shaohua Jiang, Minjie Huang, Chunmei Zhang, Han Chen. Bio-Template Synthesis of V2O3@Carbonized Dictyophora Composites for Advanced Aqueous Zinc-Ion Batteries. Molecules 2023, 28 (5) , 2147. https://doi.org/10.3390/molecules28052147
    25. Jian Zhi, Siwei Zhao, Min Zhou, Ruiqi Wang, Fuqiang Huang. A zinc-conducting chalcogenide electrolyte. Science Advances 2023, 9 (4) https://doi.org/10.1126/sciadv.ade2217
    26. Huaqing Chen, Yuyan Wang, Chanjuan Liu, Linrui Hou, Jinfeng Sun, Changzhou Yuan. Two‐dimensional V 2 CT x In‐situ Derived Porous V 2 O 3 @C Flakes Towards Zinc‐Ion Capacitors as a Competitive Cathode Material. ChemNanoMat 2023, 9 (1) https://doi.org/10.1002/cnma.202200394
    27. Xiangjie Chen, Qingquan Kong, Xiaoqiang Wu, Xuguang An, Jing Zhang, Qingyuan Wang, Weitang Yao. V2O3@C optimized by carbon regulation strategy for ultra long-life aqueous zinc-ion batteries. Chemical Engineering Journal 2023, 451 , 138765. https://doi.org/10.1016/j.cej.2022.138765
    28. Lu Zhang, Lihua Hou, Rui Sheng, Di Li, Yuanxiang Gu, Lei Wang. Constructing an Al 2 O 3 /(NH 4 ) 2 V 4 O 9 heterostructure as a cathode material for high performance aqueous rechargeable zinc ion batteries. CrystEngComm 2022, 24 (47) , 8248-8255. https://doi.org/10.1039/D2CE01178F
    29. Hongzhe Chen, Jingbo Cai, Xianqing Liu, Zhanhong Yang. Polyethylene (PE) reduction method towards V2O3@C-PE as cathode of zinc ion batteries with high stability and capacity. Journal of Electroanalytical Chemistry 2022, 924 , 116856. https://doi.org/10.1016/j.jelechem.2022.116856
    30. Ziyi Hao, Weikang Jiang, Kaiyue Zhu. Carbon-encapsulated V2O3 nanorods for high-performance aqueous Zn-ion batteries. Frontiers in Chemistry 2022, 10 https://doi.org/10.3389/fchem.2022.956610
    31. Sanna Gull, Han-Yi Chen. Recent advances in cathode materials for aqueous zinc-ion batteries: Mechanisms, materials, challenges, and opportunities. MRS Energy & Sustainability 2022, 9 (2) , 248-280. https://doi.org/10.1557/s43581-022-00044-w
    32. Man Qi, Fan Li, Zheng Zhang, Qiao Lai, Yuwen Liu, Jianmin Gu, Liqiu Wang. Three-dimensional interconnected ultrathin manganese dioxide nanosheets grown on carbon cloth combined with Ti3C2Tx MXene for high-capacity zinc-ion batteries. Journal of Colloid and Interface Science 2022, 615 , 151-162. https://doi.org/10.1016/j.jcis.2022.01.162
    33. Huai-Zheng Ren, Jian Zhang, Bo Wang, Hao Luo, Fan Jin, Tian-Ren Zhang, An Ding, Bo-Wen Cong, Dian-Long Wang. A V2O3@N–C cathode material for aqueous zinc-ion batteries with boosted zinc-ion storage performance. Rare Metals 2022, 41 (5) , 1605-1615. https://doi.org/10.1007/s12598-021-01892-0
    34. Jun Zheng, Chenyang Zhan, Kai Zhang, Wenwu Fu, Qiaojun Nie, Ming Zhang, Zhongrong Shen. Rapid Electrochemical Activation of V 2 O 3 @C Cathode for High‐Performance Zinc‐Ion Batteries in Water‐in‐Salt Electrolyte. ChemSusChem 2022, 15 (8) https://doi.org/10.1002/cssc.202200075
    35. Chang Lin Liu, Yang Liu, Xing Liu, Yun Gong. Coordination polymer-derived Al 3+ -doped V 2 O 3 /C with rich oxygen vacancies for an advanced aqueous zinc-ion battery with ultrahigh rate capability. Sustainable Energy & Fuels 2022, 6 (8) , 2020-2037. https://doi.org/10.1039/D2SE00049K
    36. Tao Zhou, Qing Han, Lingling Xie, Xinli Yang, Limin Zhu, Xiaoyu Cao. Recent Developments and Challenges of Vanadium Oxides (V x O y ) Cathodes for Aqueous Zinc‐Ion Batteries. The Chemical Record 2022, 22 (4) https://doi.org/10.1002/tcr.202100275
    37. Xianmin Huang, Ziwei Li, Hui Liu, Mengyuan Zhang, Xuena Du, Xiaoxiao Cui, Qingbo Wang, Hai Wang. Optimized cyclic and electrochemical performance by organic ion N(CH3)4+ pre-inserted into N(CH3)4V8O20 cathode and hierarchy distributive Zn anode in aqueous zinc ion batteries. Electrochimica Acta 2022, 412 , 140160. https://doi.org/10.1016/j.electacta.2022.140160
    38. Yue Niu, Denghui Wang, Yingjie Ma, Linjie Zhi. Cascading V2O3/N-doped carbon hybrid nanosheets as high-performance cathode materials for aqueous zinc-ion batteries. Chinese Chemical Letters 2022, 33 (3) , 1430-1434. https://doi.org/10.1016/j.cclet.2021.08.058
    39. Meng-Xin Bai, Zheng-Hua He, Jing-Feng Hou, Jian-Fei Gao, Ling-Bin Kong. Solvothermally Prepared Vo2(B) for Aqueous Zinc Ion Batteries with High Capacity and Excellent Rate Capability. SSRN Electronic Journal 2022, 50 https://doi.org/10.2139/ssrn.4167646
    40. Ping Luo, Wenwei Zhang, Shiyu Wang, Gangyuan Liu, Yao Xiao, Chunli Zuo, Wen Tang, Xudong Fu, Shijie Dong. Electroactivation-induced hydrated zinc vanadate as cathode for high-performance aqueous zinc-ion batteries. Journal of Alloys and Compounds 2021, 884 , 161147. https://doi.org/10.1016/j.jallcom.2021.161147
    41. Ting-Feng Yi, Liying Qiu, Jin-Peng Qu, Hongyan Liu, Jun-Hong Zhang, Yan-Rong Zhu. Towards high-performance cathodes: Design and energy storage mechanism of vanadium oxides-based materials for aqueous Zn-ion batteries. Coordination Chemistry Reviews 2021, 446 , 214124. https://doi.org/10.1016/j.ccr.2021.214124
    42. Jin‐Sung Park, Sungjin Yang, Yun Chan Kang. Boosting the Electrochemical Performance of V 2 O 3 by Anchoring on Carbon Nanotube Microspheres with Macrovoids for Ultrafast and Long‐Life Aqueous Zinc‐Ion Batteries. Small Methods 2021, 5 (9) https://doi.org/10.1002/smtd.202100578
    43. Hongzhe Chen, Zhanhong Yang, Jian Wu, Yao Rong, Lie Deng. Industrial VN@reduced graphene oxide cathode for aqueous zinc ion batteries with high rate capability and long cycle stability. Journal of Power Sources 2021, 507 , 230286. https://doi.org/10.1016/j.jpowsour.2021.230286
    44. Lie Deng, Hongzhe Chen, Jian Wu, Zhanhong Yang, Yao Rong, Zhimin Fu. V2O3 as cathode of zinc ion battery with high stability and long cycling life. Ionics 2021, 27 (8) , 3393-3402. https://doi.org/10.1007/s11581-021-04121-x

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    MENDELEY PAIRING EXPIRED
    Your Mendeley pairing has expired. Please reconnect