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Enhancing Corrosion Inhibition Performance of ZnO Solid Solution by Doping Variable-Valence Rare-Earth Element Cerium

  • Si-Rui Zhao
    Si-Rui Zhao
    School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, P. R. China
    More by Si-Rui Zhao
  • Xiao-Yu Yuan
    Xiao-Yu Yuan
    School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, P. R. China
    More by Xiao-Yu Yuan
  • Yi-Xiang Chen
    Yi-Xiang Chen
    School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, P. R. China
  • Yi Lu
    Yi Lu
    School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, P. R. China
    Material Corrosion and Protection Key Laboratory of Sichuan Province, Sichuan University of Science and Engineering, Zigong, Sichuan 643000, P. R. China
    More by Yi Lu
  • Min Zhang
    Min Zhang
    School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, P. R. China
    More by Min Zhang
  • , and 
  • Jin-Ku Liu*
    Jin-Ku Liu
    School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, P. R. China
    Material Corrosion and Protection Key Laboratory of Sichuan Province, Sichuan University of Science and Engineering, Zigong, Sichuan 643000, P. R. China
    *Email: [email protected]
    More by Jin-Ku Liu
Cite this: Ind. Eng. Chem. Res. 2022, 61, 1, 421–432
Publication Date (Web):December 27, 2021
https://doi.org/10.1021/acs.iecr.1c04162
Copyright © 2021 American Chemical Society

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    Abstract

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    Mixed-valence element-doped compounds have attracted great interest due to their unique chemical properties. Here, mixed-valence cerium-doped zinc-oxide solid solution (ZCOSS) material with a single-port hollow columnar structure was prepared under inorganic aqueous conditions, which could effectively inhibit the oxygen-absorbing corrosion of the metal. As a result of the synergistic valence cycling effect of variable-valence cerium and the molecule of zinc oxide and the adsorption effect of the hollow columnar structure, the corrosive environment was hypoxic, the charge transfer was hindered, and the generation of corrosion product was limited. In addition, the doping of cerium changed the energy band structure of the zinc oxide material, making it possible for photoelectrochemical cathodic protection of steels. Thus, the corrosion inhibition efficiency of the ZCOSS composite system is approximately 14 times that of epoxy resin and 5.5 times that of the ZnO composite system.

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.iecr.1c04162.

    • Diagrammatic crystal structure, Raman test results, electrochemical parameters extracted from impedance data, Tafel polarization curves (ΔEI) and (E–log I), experimental details of the BET measurement, and calcination conditions of ZCOSS materials (PDF)

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    Cited By

    This article is cited by 7 publications.

    1. Abinash Das, Dongyu Liu, Riu Riu Wary, Andrey S. Vasenko, Oleg V. Prezhdo, Ranjith G. Nair. Mn-Modified ZnO Nanoflakes for Optimal Photoelectrochemical Performance Under Visible Light: Experimental Design and Theoretical Rationalization. The Journal of Physical Chemistry Letters 2023, 14 (43) , 9604-9611. https://doi.org/10.1021/acs.jpclett.3c02730
    2. Jing-Jing Tian, Yi-Xiang Chen, Zi-Xiang Liu, Jin-Ku Liu. Enhanced Anticorrosion Properties and Mechanism of Co/N Codoped Modified ZnO Dilute Magnetic Solid Solutions. ACS Applied Engineering Materials 2023, 1 (8) , 2255-2268. https://doi.org/10.1021/acsaenm.3c00305
    3. Si-Rui Zhao, Wen-Qiang Huang, Jin-Ku Liu, ZhenXue Liu, JiChang Liu, Yun-Sheng Ma, Peng-Peng Liu. Enhanced Durable Corrosion Resistance of Samarium-Doped ZnO Solid Solution Materials by 4f Electrons of Samarium Atoms. Industrial & Engineering Chemistry Research 2023, 62 (32) , 12549-12558. https://doi.org/10.1021/acs.iecr.3c01893
    4. Wei Tong, Kai An, Jiasheng Zhang, Ning Du, Chen Ma, Dangsheng Xiong. Improved Interfacial Interactions of Dip Coatings by In Situ Introducing Silica to Enhance Corrosion Resistance and Metal Bonding Strength. Langmuir 2023, 39 (5) , 1775-1785. https://doi.org/10.1021/acs.langmuir.2c02510
    5. Lidong Wang, Xiaohan Guo, Qingying Ye, Juanjuan Qi, Ping Li, Fei Yan. Boosting H2O2 Activation for the Efficient Degradation of Dimethyl Sulfoxide-Containing Wastewater over Supported Niobia Catalysts. Industrial & Engineering Chemistry Research 2022, 61 (40) , 14772-14782. https://doi.org/10.1021/acs.iecr.2c02196
    6. Xi Chen, Guangzhu Zhou, Xiutong Wang, Hui Xu, Cuizhen Wang, Qiuhui Yao, Jingyi Chi, Xiaoning Fu, Yuanhao Wang, Xueying Yin, Zijin Zhang. Progress in semiconductor materials for photocathodic protection: Design strategies and applications in marine corrosion protection. Chemosphere 2023, 323 , 138194. https://doi.org/10.1016/j.chemosphere.2023.138194
    7. Feng-Rui Wang, Xiao-Xiao Sheng, Min Zhang, Min Miao, Jin-Ku Liu, Ji-Chang Liu, Yun-Sheng Ma, Peng-Peng Liu. Design and enhanced anticorrosion performance of a Zn 5 Mo 2 O 11 ·5H 2 O/ h -BN nanocomposite with labyrinth of nanopores. Nanoscale 2023, 15 (7) , 3199-3211. https://doi.org/10.1039/D2NR06846J

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