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Density Measurements of Various Molten Sodium, Magnesium, Potassium, and Uranium Chloride Salt Compositions Using Neutron Imaging

  • Jisue Moon
    Jisue Moon
    Oak Ridge National Laboratory, One Bethel Valley Road, Oak Ridge, Tennessee37830, United States
    More by Jisue Moon
  • Hunter Andrews*
    Hunter Andrews
    Oak Ridge National Laboratory, One Bethel Valley Road, Oak Ridge, Tennessee37830, United States
    *Email: [email protected]
  • Can Agca
    Can Agca
    Oak Ridge National Laboratory, One Bethel Valley Road, Oak Ridge, Tennessee37830, United States
    More by Can Agca
  • Jean-Christophe Bilheux
    Jean-Christophe Bilheux
    Oak Ridge National Laboratory, One Bethel Valley Road, Oak Ridge, Tennessee37830, United States
  • Alexander Braatz
    Alexander Braatz
    Oak Ridge National Laboratory, One Bethel Valley Road, Oak Ridge, Tennessee37830, United States
  • Abbey McAlister
    Abbey McAlister
    Oak Ridge National Laboratory, One Bethel Valley Road, Oak Ridge, Tennessee37830, United States
  • Joanna McFarlane
    Joanna McFarlane
    Oak Ridge National Laboratory, One Bethel Valley Road, Oak Ridge, Tennessee37830, United States
  • Jake McMurray
    Jake McMurray
    Oak Ridge National Laboratory, One Bethel Valley Road, Oak Ridge, Tennessee37830, United States
  • Kevin Robb
    Kevin Robb
    Oak Ridge National Laboratory, One Bethel Valley Road, Oak Ridge, Tennessee37830, United States
    More by Kevin Robb
  • , and 
  • Yuxuan Zhang
    Yuxuan Zhang
    Oak Ridge National Laboratory, One Bethel Valley Road, Oak Ridge, Tennessee37830, United States
    More by Yuxuan Zhang
Cite this: Ind. Eng. Chem. Res. 2022, 61, 48, 17665–17673
Publication Date (Web):November 18, 2022
https://doi.org/10.1021/acs.iecr.2c02967
Copyright © 2022 American Chemical Society

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    Abstract

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    With an increased interest in the use of molten salts for energy generation, obtaining thermophysical properties of salt mixtures becomes critical for the understanding of salt performance and behavior. Density is one of the significant thermophysical properties of salt systems. This work presents the density measurement of molten chloride salt mixtures using neutron imaging. This work was performed at the Oak Ridge National Laboratory High-Flux Isotope Reactor. Resulting densities as a function of temperature for different molten chloride salts from this work were compared with calculated values using Redlich–Kister modeling. Agreement between the calculated and measured values was within 1–10%, with the exception of the ternary UCl3–NaCl–KCl salt that showed a 32% discrepancy between several literature reports; however, the results did align well with another neutron radiography article. Analysis of the radiographs suggests that microbubbles in the ternary mixture might have biased the density measurements.

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.iecr.2c02967.

    • Two heights used for calculation of the salt volume from the neutron images; ideal and RK-estimated densities plotted against temperature; contact angle data; averaged contact angles for NaCl–KCl (50:50 mol%) as a function of temperature; data for averaged contact angles for the UCl3–KCl and UCl3–KCl–NaCl mixtures as a function of temperature; and average contact angle data for the KCl–MgCl2 mixtures as a function of temperature (PDF)

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    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    This article is cited by 1 publications.

    1. Joanna McFarlane, Hunter B. Andrews, Abbey L. McAlister, Jisue Moon, Kevin R. Robb, Charles F. Weber, Andrew Ballard. The effect of interfacial phenomena on gas solubility measurements in molten salts. Frontiers in Energy Research 2023, 10 https://doi.org/10.3389/fenrg.2022.1102466

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