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Utilization or Sequestration for Captured CO2 from Cement Plants?
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    Process Systems Engineering

    Utilization or Sequestration for Captured CO2 from Cement Plants?
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    • Syed Ali Zaryab
      Syed Ali Zaryab
      Group of Energy Conversion Systems (GECOS), Department of Energy, Politecnico di Milano, Via Lambruschini 4A, 20156 Milano, Italy
    • Federico d’Amore
      Federico d’Amore
      Computer-Aided Process Engineering Laboratory (CAPE-Lab), Department of Industrial Engineering, University of Padova, Via Marzolo 9, 35131 Padova, Italy
    • Paolo Colbertaldo
      Paolo Colbertaldo
      Group of Energy Conversion Systems (GECOS), Department of Energy, Politecnico di Milano, Via Lambruschini 4A, 20156 Milano, Italy
    • Matteo C. Romano*
      Matteo C. Romano
      Group of Energy Conversion Systems (GECOS), Department of Energy, Politecnico di Milano, Via Lambruschini 4A, 20156 Milano, Italy
      *Email: [email protected]
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    Industrial & Engineering Chemistry Research

    Cite this: Ind. Eng. Chem. Res. 2024, 63, 46, 20287–20303
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    https://doi.org/10.1021/acs.iecr.4c02268
    Published November 11, 2024
    Copyright © 2024 American Chemical Society

    Abstract

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    The scope of this work is to assess the economic competitivity of optimized CO2 capture and utilization process (CCU) for e-methanol production with respect to CO2 capture and sequestration (CCS) in three locations (southern Italy, northern Germany, northeastern Egypt) and two economic scenarios (short- and long-term) for the cost of renewable energy technologies. The final aim is to determine the optimal sizing and operation of the process units of the system by minimizing the total costs to be sustained by a cement producer. At a methanol selling price of 550 €/t, which is consistent with the current market price, CCS is economically more competitive than CCU in the short-term scenario in all locations. In the long-term scenario, due to the reduced costs of renewable energy technologies, CCU becomes the preferable option in a large majority of the assessed cases. In the long-term scenario, the breakeven methanol selling price in Italy with respect to CCS was found to increase from 384 €/t to 570 €/t if low-cost hydrogen storage is not available and H2 is stored in pressurized vessels (as alternative to caverns). In Germany, from 542 €/t to 778 €/t. In Egypt, from 402 to 501 €/t. Overall, this study shows that e-methanol production from captured CO2 in European countries may be competitive with e-methanol produced in more favorable locations, such as Egypt, only in the long-term, at the condition of a substantial cost reduction of renewable energy technologies, and of the persistency of a differential cost of capital with respect to renewables-rich emerging countries.

    Copyright © 2024 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.iecr.4c02268.

    • Mathematical model description, key results, profiles (wind, PV, grid price, indirect grid emissions) (PDF)

    • Hourly profiles for PV and WT, hourly cement operation, CO2, H2, and electricity hourly balance for long-term cases (XLSX)

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    This article is cited by 1 publications.

    1. Jing Wei, Min Deng, Dengguo Yin, Zikang Qin, Lin Yang, Lu Yao, Wenju Jiang, Junfeng Zheng, Zhongde Dai. Enhancing the CO2 Separation Performance of Mixed Matrix Membranes Based on Block Copolymer via Nonsolvent-Induced Microstructure Rearrangement. Industrial & Engineering Chemistry Research 2025, 64 (6) , 3499-3510. https://doi.org/10.1021/acs.iecr.4c04366

    Industrial & Engineering Chemistry Research

    Cite this: Ind. Eng. Chem. Res. 2024, 63, 46, 20287–20303
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.iecr.4c02268
    Published November 11, 2024
    Copyright © 2024 American Chemical Society

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